• Title/Summary/Keyword: Santa Barbara

Search Result 45, Processing Time 0.026 seconds

Electrochemical Characteristics of Silicon/Carbon Composites for Anode Materials of Lithium Ion Batteries (리튬이온배터리 음극활물질 Silicon/Carbon 복합소재의 전기화학적 특성)

  • Park, Ji Yong;Jung, Min Zy;Lee, Jong Dae
    • Applied Chemistry for Engineering
    • /
    • v.26 no.1
    • /
    • pp.80-85
    • /
    • 2015
  • Silicon/carbon composites as anode materials for lithium-ion batteries were examined to find the cycle performance and capacity. Silicon/carbon composites were prepared by a two-step method, including the magnesiothermic reduction of SBA-15 (Santa Barbara Amorphous material No. 15) and carbonization of phenol resin. The electrochemical behaviors of lithium ion batteries were characterized by charge/discharge, cycle, cyclic voltammetry and impedance tests. The improved electrochemical performance attributed to the fact that silicon/carbon composites suppress the volume expansion of the silicon particles and enhance the conductivity of silicon/carbon composites (30 ohm) compared to that of using the pure silicon (235 ohm). The anode electrode of silicon/carbon composites showed the high capacity approaching 1,348 mAh/g and the capacity retention ratio of 76% after 50 cycles.

Synthesis and Electrochemical Characteristics of Silicon/Carbon Anode Composite with Binders and Additives (Silicon/Carbon 음극소재 제조 및 바인더와 첨가제에 따른 전기화학적 특성)

  • Park, Ji Yong;Lee, Jong Dae
    • Korean Chemical Engineering Research
    • /
    • v.56 no.3
    • /
    • pp.303-308
    • /
    • 2018
  • Silicon/Carbon (Si/C) composite as anode materials for lithium-ion batteries was synthesized to find the effect of binders and an electrolyte additive. Si/C composites were prepared by two step method, including magnesiothermic reduction of SBA-15 (Santa Barbara Amorphous material No. 15) and carbonization of phenol resin. The electrochemical performances of Si/C composites were investigated by charge/discharge, cyclic voltammetry and impedance tests. The anode electrode of Si/C composite with PAA binder appeared better capacity (1,899 mAh/g) and the capacity retention ratio (92%) than that of other composition coin cells during 40 cycles. Then, Vinylene carbonate (VC) was tested as an electrolyte additive. The influence of this additive on the behavior of Si/C anodes was very positive (3,049 mAh/g), since the VC additive is formed passivation films on Si/C surfaces and suppresses irreversible changes.

Adsorption of methylene blue from an aqueous dyeing solution by use of santa barbara amorphous-15 nanostructure: Kinetic and isotherm studies

  • Alizadeh, Reza;Zeidi, Amir
    • Advances in environmental research
    • /
    • v.6 no.2
    • /
    • pp.113-125
    • /
    • 2017
  • Santa Barbara Amorphous-15(SBA-15) nanoparticles were utilized as the inexpensive and effective adsorbents to remove methylene blue dye from the aqueous solution.SBA-15 was created by Zhao et al method. Infrared spectroscopy, X-ray diffraction and scanning electron microscopy (SEM) were used for the evaluated physical properties of SBA-15. The results of diffraction X-ray indicated that was the crystalline structure for it. Also IR spectroscopy indicated was a silica the whole structure of the groups and SEM image verify the structure of relatively identical particles size of SBA-15. Factors affecting adsorption including the amounts of adsorbent, pH and contact time were investigated by a SBA-15 nanomaterial design. The extent of dye removal enhanced with increasing initial dye concentration and pH from 4 to 10. The higher percentage adsorption were obtained under optimum conditions of variables (sorbent dose of 200 mg/liter, initial MB concentration 10 mg/liter, initial pH of 10 and temperature of $25^{\circ}C$). Maximum adsorption happened after the 2 hour and the kinetic processes of the dyes adsorption were described by applying the pseudo-first-order and the pseudo-second-order and the relatively High correlation with the kinetic Ellovich models. It was found that the pseudo-second-order models kinetic equation described the data of dye adsorption with a good correlation (R2>0.999) which indicated chemisorption mechanism. Freundlich and Langmuir adsorption models were investigated in conditions of variables (adsorbent dose 0.01 gr/liter, MB concentration 10, 20, 30 mg/liter, pH of 4, 7, 10, contact time 90 min and temperature of $27^{\circ}C$). The adsorption data were represented by Langmuir isotherm model. These values are higher than the adsorption capacities of some other adsorbents that have recently been published in the literature.

Autophagy-related protein LC3 and Beclin-1 in the first trimester of pregnancy

  • Chifenti, Barbara;Locci, Maria Teresa;Lazzeri, Gloria;Guagnozzi, Mariangela;Dinucci, Dino;Chiellini, Federica;Filice, Maria Elena;Salerno, Maria Giovanna;Battini, Lorella
    • Clinical and Experimental Reproductive Medicine
    • /
    • v.40 no.1
    • /
    • pp.33-37
    • /
    • 2013
  • Autophagy is a degradation process that acts in response to environmental stressors. Recently, autophagy has been detected in normal term, preeclamptic and intrauterine growth-restricted placentas. The object of this work was to investigate the presence of autophagy in first trimester voluntary interruption of pregnancy placental villi by the expression of autophagy-related proteins, light chain 3 (LC3), and Beclin-1. In first trimester placental villi laser scanning confocal microscopy (LSCM) analysis revealed LC3 and Beclin-1 immunoreactivity prevalently located in villous cytotrophoblasts. Using LSCM, LC3, and Beclin-1 were localized to the cytoplasm of the trophoblast layer in human full-term placentas. Beclin-1 expression and LC3 activation were confirmed by western blotting. These data emphasize that autophagy activation is different among cytotrophoblasts and syncytiotrophoblasts depending on the gestational age and thus we speculate that autophagy might play a prosurvival role throughout human pregnancy.

Comparison of Muscle Activity with Lower Extremity during Stairs and Ramp Climbing of Old Adults by EMG (근전도를 이용한 노인의 계단과 경사로 오르기 시하지 근활성도 비교)

  • Han, Jin-Tae;Gong, Won-Tae;Lee, Yun-Seob
    • The Journal of Korean Physical Therapy
    • /
    • v.21 no.1
    • /
    • pp.35-40
    • /
    • 2009
  • Purpose: The purpose of this study was to investigate change of muscle activities during level walking, stairs and ramp climbing in old adults. Methods: Twelve old adults were recruited and agreed this study. Muscle activity was measured by MP150 system (BIOPAC System Inc., Santa Barbara, USA). Statistical analysis was used one-way ANOVA to know the difference according to gait conditions (level walking, stairs and ramp ascending) Results: In stance phase, muscle activities of low extremities with old adults were generally significant difference in ramp ascending. In swing phase, rectus femoris and biceps femoris activity in old adults generally more increased during stairs ascending and tibialis anterior and gastrocnemius activity in old adults generally increased during ramp ascending. Conclusion: These results indicate that stair and ramp climbing is different muscle recruit pattern to level walking.

  • PDF

THE EFFECTS OF UNCERTAIN TOPOGRAPHIC DATA ON SPATIAL PREDICTION OF LANDSLIDE HAZARD

  • Park, No-Wook;Kyriakidis, Phaedon C.
    • Proceedings of the KSRS Conference
    • /
    • 2008.10a
    • /
    • pp.259-261
    • /
    • 2008
  • GIS-based spatial data integration tasks have used exhaustive thematic maps generated from sparsely sampled data or satellite-based exhaustive data. Due to a simplification of reality and error in mapping procedures, such spatial data are usually imperfect and of different accuracy. The objective of this study is to carry out a sensitivity analysis in connection with input topographic data for landslide hazard mapping. Two different types of elevation estimates, elevation spot heights and a DEM from ASTER stereo images are considered. The geostatistical framework of kriging is applied for generating more reliable elevation estimates from both sparse elevation spot heights and exhaustive ASTER-based elevation values. The effects of different accuracy arising from different terrain-related maps on the prediction performance of landslide hazard are illustrated from a case study of Boeun, Korea.

  • PDF

Narrow-line region of two radio-quiet quasars

  • Oh, Se-MYeong;Woo, Jong-Hak;Bennert, Vardha
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.36 no.1
    • /
    • pp.53.1-53.1
    • /
    • 2011
  • We investigate the radial properties of the narrow-line region (NLR) in two radio-quiet quasars, PG1012+008 and PG1307+085, using the spectra obtained with the FORS1 at the Very Large Telescope. These high quality spectra with seeing < 0.6" enable us to extract seven two-pixel (0.4") spectra as a function of the radial distance from the accretion disk. In contrast to [OIII] narrow-band imaging, which can be contaminated by starbursts, shock-ionized gas, and tidal tails, we use emission-line diagnostic to determine the true size of the AGN-excited NLR. In this poster, we present the results based on the radial variance of $H{\beta}$ to [OIII] ${\lambda}5007$ ratio. For both targets, the [OIII] emission line exhibits a blue wing, suggesting an outflow of gas. In the case of PG1307+085, the blue wing disappears at the distance of 1". We will discuss the properties of the NLR in detail.

  • PDF

Geostatistical Integration of Different Sources of Elevation and its Effect on Landslide Hazard Mapping

  • Park, No-Wook;Kyriakidis, Phaedon C.
    • Korean Journal of Remote Sensing
    • /
    • v.24 no.5
    • /
    • pp.453-462
    • /
    • 2008
  • The objective of this paper is to compare the prediction performances of different landslide hazard maps based on topographic data stemming from different sources of elevation. The geostatistical framework of kriging, which can properly integrate spatial data with different accuracy, is applied for generating more reliable elevation estimates from both sparse elevation spot heights and exhaustive ASTER-based elevation values. A case study from Boeun, Korea illustrates that the integration of elevation and slope maps derived from different data yielded different prediction performances for landslide hazard mapping. The landslide hazard map constructed by using the elevation and the associated slope maps based on geostatistical integration of spot heights and ASTER-based elevation resulted in the best prediction performance. Landslide hazard mapping using elevation and slope maps derived from the interpolation of only sparse spot heights showed the worst prediction performance.

Photocatalytic Degradation and Adsorptive Removal of Tetracycline on Amine-Functionalized Graphene Oxide/ZnO Nanocomposites

  • Thanh Truong Dang;Hoai-Thanh Vuong;Sung Gu Kang;Jin Suk Chung
    • Korean Chemical Engineering Research
    • /
    • v.61 no.4
    • /
    • pp.635-644
    • /
    • 2023
  • Due to the rapid development of the livestock industry, particularly due to residual pharmaceutical antibiotics, environmental populations have been negatively affected. Herein, we report a ZnO/melamine-functionalized carboxylic-rich graphene oxide (ZFG) photocatalyst for visible light-driven photocatalytic degradation of tetracycline hydrochloride in aqueous solutions. The properties of the photocatalysts were evaluated by XRD, FTIR, XPS, Fe-SEM, HR-TEM, TGA, Raman spectroscopy, UV-Vis spectroscopy, zeta potential, and electrochemical measurements. The photocatalytic activity was measured using high-performance liquid chromatography. The photocatalytic properties of the ZFG photocatalyst evaluated against the tetracycline hydrochloride (TCH) antibiotic under visible light irradiation showed superior photodegradation of 96.27% within 60 min at an initial pH of 11. The enhancement of photocatalytic degradation was due to the introduction of functionalized graphene, which increases the light-harvesting capability and molecular adsorption capability in addition to minimizing the recombination rate of photogenerated charge carriers due to its role as an electron acceptor and mediator.

Towards 3D Modeling of Buildings using Mobile Augmented Reality and Aerial Photographs (모바일 증강 현실 및 항공사진을 이용한 건물의 3차원 모델링)

  • Kim, Se-Hwan;Ventura, Jonathan;Chang, Jae-Sik;Lee, Tae-Hee;Hollerer, Tobias
    • Journal of the Institute of Electronics Engineers of Korea CI
    • /
    • v.46 no.2
    • /
    • pp.84-91
    • /
    • 2009
  • This paper presents an online partial 3D modeling methodology that uses a mobile augmented reality system and aerial photographs, and a tracking methodology that compares the 3D model with a video image. Instead of relying on models which are created in advance, the system generates a 3D model for a real building on the fly by combining frontal and aerial views. A user's initial pose is estimated using an aerial photograph, which is retrieved from a database according to the user's GPS coordinates, and an inertial sensor which measures pitch. We detect edges of the rooftop based on Graph cut, and find edges and a corner of the bottom by minimizing the proposed cost function. To track the user's position and orientation in real-time, feature-based tracking is carried out based on salient points on the edges and the sides of a building the user is keeping in view. We implemented camera pose estimators using both a least squares estimator and an unscented Kalman filter (UKF). We evaluated the speed and accuracy of both approaches, and we demonstrated the usefulness of our computations as important building blocks for an Anywhere Augmentation scenario.