• Journal of Periodontal and Implant Science
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• 제49권3호
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• pp.193-204
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• 2019

Purpose: The reaction of cells to a titanium implant depends on the surface characteristics of the implant which are affected by decontamination. The aim of this study was to evaluate the cytocompatibility of titanium disks treated with various decontamination methods, using salivary bacterial contamination with dental pellicle formation as an in vitro model. Methods: Sand-blasted and acid-etched (SA) titanium disks were used. Three control groups (pristine SA disks [SA group]; salivary pellicle-coated SA disks [pellicle group]; and biofilm-coated, untreated SA disks [NT group]) were not subjected to any decontamination treatments. Decontamination of the biofilm-coated disks was performed by 14 methods, including ultrasonic instruments, rotating instruments, an air-powder abrasive system, a laser, and chemical agents. MG63 cells were cultured in the presence of the treated disks. Cell proliferation assays were performed on days 2 and 5 of cell culture, and cell morphology was analyzed by immunofluorescence and scanning electron microscopy (SEM). A vascular endothelial growth factor (VEGF) assay was performed on day 5 of culture. Results: The cell proliferation assay revealed that all decontaminated disks, except for the 2 groups treated using a plastic tip, showed significantly less cell proliferation than the SA group. The immunofluorescence and SEM analyses revealed that most groups showed comparable cell density, with the exception of the NT group, in which the cell density was lower and bacterial residue was observed. Furthermore, the cells grown with tetracycline-treated titanium disks showed significantly lower VEGF production than those in the SA group. Conclusions: None of the decontamination methods resulted in cytocompatibility similar to that of pristine SA titanium. However, many methods caused improvement in the biocompatibility of the titanium disks in comparison with the biofilm-coated, untreated titanium disks. This suggests that decontamination is indispensable for the treatment of peri-implantitis, even if the original biocompatibility cannot be restored.

• 대한지리학회지
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• 제41권3호
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• pp.331-345
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• 2006

본 연구는 두만강 하류 지역에 대규모로 발달한 사구 지형의 분포 및 지표 환경, 퇴적물의 특성, 기원 및 형성과정을 밝히고, 두만강 하류 일대의 하천 및 해안 환경변화를 고찰하고자 한다. 이를 위해, Landsat, Spot 영상을 이용하여 지표피복을 분석하고, 2회의 현지 야외조사를 실시하였으며, 입도분석 및 현미경 관찰을 통해 사구 퇴적물 시료를 분석하였다. 위성영상에서 파악된 사질퇴적지형 요소들은 삼각주, 사취, 이동사구, 정착사구, 사주, 사주피복 수변식생으로 구분되었다. 사구 퇴적물에 대한 입도 분석 결과, 조사 지역 중 가장 상류 쪽에 해당하는 DM3과 DM4에서 하성보다는 해성 모래와의 상관성이 높게 나타났다. 이는 현재 사구를 이루는 모래의 입도 특성이 두만강 하류 지역의 현재 자연환경을 반영하고 있지 않음을 의미하는 것이다. 현미경 분석 결과, 모든 시료에서 풍화에 가장 강한 석영의 비율이 $65{\sim}83%$로 가장 높았다. 그러나 $30{\sim}40%$를 차지하는 광물 입자의 표면은 화학적 풍화를 받아 황색의 물질로 표면이 코팅되어 있으며, 물리 화학적 풍화에 의한 바늘 및 그물 모양의 거친 표면 형태와 에칭 피트가 나타난다.

• 한국지반공학회논문집
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• 제16권4호
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• pp.17-30
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• 2000

본 연구의 목적은 폐주물사-플라이애쉬 혼합재료의 옹벽 뒷채움재 이용시 옹벽에 작용하는 토압과 안정성에 대한 특성을 평가하는 것이다. 세종류의 폐주물사(생형사, 후란사, 코티드사)와 ASTM 분류 기준 F 등급의 플라이애쉬를 이용한 유동성 뒷채움재의 옹벽 적용성평가를 위해 인위적 변위제어 실험 및 자유변위제어실험을 이용하여 모형옹벽실험을 수행하였다. 인위적 변위제어실험의 경우 유동성 뒤채움의 타설 직후 토압계수의 크기는 0.8~1 사이의 값으로 나타났고, 약 12시간이 경과하면 옹벽에 작용하는 토압이 상당부분 저감되었다. 2단계 타설 방법을 적용한 자유변위실험의 경우, 슬러리 형태의 유동성 뒤채움재의 타설초기에 후란사와 코티드사 혼합재는 빠른 배수효과에 의해 토압 경감 효과가 빨리 나타났지만, 1일 후의 토압은 같은 양생시간의 생형사에 비해 크게 유지되었다. 모형실험의 자유변위제어 실험결과를 이용한 안정성 해석으로부터 6m 옹벽에 타설할 수 있는 뒤채움재의 시공단계별 1차타설 높이 및 2차타설 높이는 생형사의 경우 3.9m 및 3.57m, 후란사의 경우 4.07m 및 3.64m, 코티드사의 경우 3.86m 및 3.54m, 혼합사의 경우 3.9m 및 3.44m로 결정되었고, 실제 옹벽의 뒤채움 높이 5.4m보다 크므로 2단계 시공으로 옹벽의 뒤채움을 완공할 수 있는 것으로 판정되었다. 또한 재료의 양생특성에 따른 옹벽의 안정성은 양생기간이 경과함에 따라 더욱 증가되는 결과를 나타내었다.

• Corrosion Science and Technology
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• 제4권2호
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• pp.56-59
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• 2005

In rebar concrete structure, the corrosion of rebar can arise the deterioration of concrete structure and may affect the safety of the whole system. Recently, several methods for corrosion protection have been used and are more important for concrete structure using the sand including chloride ion. Among several protections, electrical cathodic protection has been expected to be one of the most useful methods in corrosion protection for reinforcement of concrete structures. The anode for cathodic protection needs high current density, high corrosion resistance and low overvoltage. To fill up the special qualities, the insoluble anodes were developed and these anodes were coated with metal oxide of $TiO_2$, $ZrO_2$, $RuO_2$, and $IrO_2$. Lifetime of these anodes can be one of the important factors affecting the lifetime of concrete structure in cathodic protection. In this work, several anodes were made by sol-gel method and thermal decomposition method and the lifetime of these anodes was evaluated by NACE international standard test method, TM 0294-94. Also, we did analyze the properties of coated metal oxides.

• 한국물환경학회지
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• 제31권2호
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• pp.209-215
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• 2015

The purpose of this study is to evaluate the characteristic of the iron oxide carrier for removing arsenic contained in the groundwater. 4 types of iron oxide carrier used in the study is iron oxide coated sand carrier (IOCSC), iron oxide coated zeolite carrier (IOCZC), iron oxide plasticity carrier (IOPC) and platinum iron oxide plasticity carrier (PIOPC). The results of this study, IOPC is showed high arsenic adsorption strength and the maximum amount of adsorption than the IOCC. Based on the results of the arsenic adsorption characteristic, by using IOCC was conducted to column test. As a result, PIOPC is showed a high arsenic adsorption amount than IOPC, it was found that the time required to reach the breakthrough point is also extended. Therefore it is determined that stably compliance with water quality standards enhanced drinking water when using the PIOPC.

• 한국지하수토양환경학회지:지하수토양환경
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• 제13권2호
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• pp.62-69
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• 2008

본 연구에서는 제조방법이 다른 여러 종류의 망간코팅사(MCS)들의 물리화학적 특성과 내산성을 비교하고 이들에 의한 독성 3가 비소의 산화특성을 평가하였다. 실험에 사용된 MCS는 4종류로서 실험실에서 고온가열처리에 의하여 제조한 B-MCS, 접촉/건조(wetting and dry) 방법으로 제조한 W&D-MCS, 정수처리장 수 처리 과정에서 자연발생적으로 생성된 N-MCS, 그리고 철 및 망간제거용으로 시판되는 Birm을 사용하였다. 각 망간사내의 망간함유량은 Birm (63,120 mg/kg) > N-MCS(10,400 mg/kg) > W&D-MCS(5,080 mg/kg) > B-MCS(2,220 mg/kg) 순으로 나타났다. 내산성 실험결과 Birm에 함유된 망간이 산성조건에서 가장 적은 용출분율(% 기준)을 보였다. 3가 비소산화 결과, B-MCS의 경우 반응용액의 pH가 낮을수록 산화율이 지속적으로 증가하였지만, N-MCS와 Birm의 경우는 이와는 달리 pH 6 부근에서 산화율이 최소가 되며 강산성 및 강알카리 영역에서는 산화율이 증가하는 것으로 나타났다. N-MCS와 Birm의 경우에는 산화망간 외에 상당량의 산화알루미늄을 함유하고 있어서 As(III) 산화와 동시에 망간산화물의 환원에 의해서 생성되는 $Mn^{2+}$가 산화망간 및 산화알루미늄 두 반응점으로 경쟁흡착이 되기 때문에 기인한 것으로 여겨진다.

• 한국재료학회지
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• 제16권4호
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• pp.248-252
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• 2006

An investigation is reported on the coating of ZnS:Cu,Cl phosphors by $HfO_2$ using atomic layer deposition method. Hafnium oxide films were prepared at the chamber temperature of $280^{\circ}C$ using $Hf[N(CH_3)_2]_4\;and\;O_2$ as precursors and reactant gas, respectively. XPS and ICP-MS analysis showed the surface composition of coated phosphor powder was hafnium oxide. In FE-SEM analysis, the surface morphology of uncoated phosphors became smoother and clearer as the number of ALD cycle increased from 900 to 1800. The photoluminescence intensity for coated phosphors showed $7.3{\sim}13.4%$ higher than that of uncoated. The effect means that the reactive surface is uniformly coated with stable hafnium oxide to reduce the dead surface layer without change of bulk properties and also its absorptance is almost negligible due to ultrathin(nano-scaled) films. The growth rate is about $1.1{\AA}/cycle$.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.172-175
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• 2004

This study is to investigate the tensile properties of glass fiber reinforced polymer(GFRP) reinforcing bars with various kinds of anchor systems experimentally. Three types of anchor systems were examined: resin sleeve anchor adopted by CSA Standard, metal overlay anchor by ASTM Standards and wedge anchor normally used in prestressing tendons. Also, three different types of GFRP bars with different surface deformations were tested in this study. All test procedures including specimens preparation, test apparatus and measuring devices were made according to the recommendations of CSA Standard S806-02. From the test results, it was found that the highest tensile strength of GFRP bar was developed by resin sleeve anchor, and tensile strength of GFRP bar with CSA anchor system is $10\%$ higher than that with ASTM anchor system in the case of sand-coated GFRP bar.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2004년도 춘계 학술발표회 제16권1호
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• pp.124-127
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• 2004

This study is to investigate the bond characteristics of glass fiber reinforced polymer(GFRP) reinforcing bars in concrete by pullout test experimentally. Three different types of GFRP bars with different surface deformations were considered in this study. Also, standard deformed steel reinforcing bar with or without epoxy-coating were included for the comparisons of bond strength. All test procedures including specimens preparation, test apparatus and measuring devices were made according to the recommendation of CSA(Canadian Standards Association) Standard S806-02. From the test results, it was found that small surface indentations contributed to increase the bond strength of GFRP bar significantly. Based on the limited test results till now, the bond strength of GFRP bar with sand-coated deformation commercially available in foreign market is around $80\%$ of that of steel deformed bars.

• 한국물환경학회지
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• 제23권5호
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• pp.659-664
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• 2007

The objective of this study is to evaluate the detoxification method for the endocrine disrupting chemicals by manganese oxide. Manganese coated sand and bisphenol-A (BPA) was used as the reactive medium and the contaminant. Results showed that manganese oxide effectively degrades BPA by oxidative coupling reaction. The nonlinear oxidative coupling reaction orders were obtained for BPA and oxide, respectively. The reaction rate of BPA decreased as initial BPA concentration increased, as oxide loading decreased and as pH increased. The higher ionic strength, the higher reaction rate was observed. Divalent cations were adsorbed on the oxide surfaces, resulting in the decreased degradation rate of BPA.