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Application of Manganese Oxide for the Oxidative Degradation of Bisphenol-A in Aqueous Phase  

Jee, Sang-Hyun (Department of Civil Engineering, Industrial Liaison Research Institute, Kyunghee University)
Ko, Seok-Oh (Department of Civil Engineering, Industrial Liaison Research Institute, Kyunghee University)
Publication Information
Journal of Korean Society on Water Environment / v.23, no.5, 2007 , pp. 659-664 More about this Journal
Abstract
The objective of this study is to evaluate the detoxification method for the endocrine disrupting chemicals by manganese oxide. Manganese coated sand and bisphenol-A (BPA) was used as the reactive medium and the contaminant. Results showed that manganese oxide effectively degrades BPA by oxidative coupling reaction. The nonlinear oxidative coupling reaction orders were obtained for BPA and oxide, respectively. The reaction rate of BPA decreased as initial BPA concentration increased, as oxide loading decreased and as pH increased. The higher ionic strength, the higher reaction rate was observed. Divalent cations were adsorbed on the oxide surfaces, resulting in the decreased degradation rate of BPA.
Keywords
Bisphenol-A; Endocrine disrupting chemicals; Intoxification; Manganese oxide; Oxidative coupling reaction;
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