Journal of Korean Society on Water Environment (한국물환경학회지)

Korean Society on Water Environment (한국물환경학회)
권호 표지

Application of Manganese Oxide for the Oxidative Degradation of Bisphenol-A in Aqueous Phase

망간산화물을 이용한 수용액내 Bisphenol-A의 산화 반응성 평가

  • Jee, Sang-Hyun (Department of Civil Engineering, Industrial Liaison Research Institute, Kyunghee University) ;
  • Ko, Seok-Oh (Department of Civil Engineering, Industrial Liaison Research Institute, Kyunghee University)
  • 지상현 (경희대학교 토목공학과, 산학협력기술연구원) ;
  • 고석오 (경희대학교 토목공학과, 산학협력기술연구원)
  • Received : 2007.06.26
  • Accepted : 2007.09.11
  • Published : 2007.09.30
Download PDF
⟨ Previous Next ⟩

Abstract

The objective of this study is to evaluate the detoxification method for the endocrine disrupting chemicals by manganese oxide. Manganese coated sand and bisphenol-A (BPA) was used as the reactive medium and the contaminant. Results showed that manganese oxide effectively degrades BPA by oxidative coupling reaction. The nonlinear oxidative coupling reaction orders were obtained for BPA and oxide, respectively. The reaction rate of BPA decreased as initial BPA concentration increased, as oxide loading decreased and as pH increased. The higher ionic strength, the higher reaction rate was observed. Divalent cations were adsorbed on the oxide surfaces, resulting in the decreased degradation rate of BPA.

Keywords

Acknowledgement

Supported by : 한국학술진흥재단

References

  1. 국립환경연구원, 1999년 내분비계장애물질 조사. 연구사업 결과보고서 (2000)
  2. 전선영, 독성 유기물로 오염된 퇴적토의 현장처리를 위한 Reactive Capping 재료의 반응성 평가, 석사학위논문, 경희대학교 (2005)
  3. 전선영, 고석오, 천연망간산화물을 이용한 클로로페놀류의 산화중합반응, 한국지하수토양환경학회지, 10(4), pp. 62-69 (2005)
  4. 환경부, 내분비계 장애물질 중장기사업계획 (1999)
  5. 환경부, 정수처리기울연구대상 유해물질 선정 보고 (2004)
  6. Bollag, J. M., Decontaminating soil with enzymes, Environ. Sci. Technol., 26(10), pp. 1876-1881 (1992) https://doi.org/10.1021/es00034a002
  7. Chen, J. A., Li, X., Li, J., Cao, J., Qiu, Z., Zhao, Q., Xu, C. and Shu, W., Degradation of environmental endocrine disruptor di-2-ethylhexyl phthalate by a newly discovered bacterium, Microbacterium sp strain CQ0110Y, Applied Microbiology and Biotechnology, 74(3), pp. 676-682 (2007) https://doi.org/10.1007/s00253-006-0700-3
  8. Ferrara, F., Fabietti, F., Delise, M., Bocca, A. P. and Funari, E., Alkylphenolic compounds in edible molluscs of the Adriatic sea(Italy), Environ. Sci. Technol., 35, pp. 3109-3112 (2001) https://doi.org/10.1021/es010508h
  9. Harries, J. E., Sheahan, D. A., Jobling, S., Matthiessen, P., Neall, P., Sumpter, J. P., Tylor, T. and Zaman, N., Estrogenic activity in five United Kingdom rivers detected by measurement of vitellogenesis in caged male trout, Environ. Toxicol. Chem., 16, pp. 534-542 (1997) https://doi.org/10.1897/1551-5028(1997)016<0534:EAIFUK>2.3.CO;2
  10. Isobe, T., Nishiyama, H., Nakashima, A. and Takada, H., Distribution and behavior of nonylphenol, octylphenol, and nonylphenol monoethoxylate in Tokyo metropolitan area: their association with aquatic particles and sedimentary distribution, Environ. Sci. Technol., 35, pp. 1041-1049 (2001) https://doi.org/10.1021/es001250i
  11. Li, J., Chen, J. A., Zhao, Q., Li, X. and Shu, W., Bioremediation of environmental endocrine disruptor di-n-butyl phthalate ester by Rhodococcus ruber, Chemosphere, 65(9), pp. 1627-1633 (2006) https://doi.org/10.1016/j.chemosphere.2006.03.005
  12. Nico, P. S. and Zasoski, R. J., Importance of Mn(III) availability on the rate of Cr(III) oxidation on delta-$MnO_2$, Environ. Sci. Technol., 34(16), pp. 3363-3367 (2000) https://doi.org/10.1021/es991462j
  13. Petrie, R. A., Grossl, P. R. and Sims, R. C., Oxidation of pentachlorophenol in manganese oxide suspensions under controlled eh and pH environments, Environ. Sci. Technol., 36(17), pp. 3744-3748 (2002) https://doi.org/10.1021/es0109491
  14. Renner, R., European bans on surfactant trigger transatlantic debate, Environ. Sci. Technol., 31, pp. 316A-320A (1997) https://doi.org/10.1021/es972366q
  15. Scott, M. J. Ph. D. Thesis, California Institute of Technology, Pasadena (1991)
  16. Snyder, S. A., Adham, S., Redding, A. M., Cannon, F. S., DeCarolis, J., Oppenheimer, J., Wert, E. C. and Yoon, Y., Role of membranes and activated carbon in the removal of endocrine disruptors and pharmaceuticals, Desalination, 202 (1-3), pp. 156-181 (2007) https://doi.org/10.1016/j.desal.2005.12.052
  17. Stone, A. T., and Morgan, J. J., Reduction and Dissolution of Manganese(III) and Manganese(IV) Oxides by Organics. 2. Survey of the Reactivity of Organics, Environ. Sci. Technol., 18, pp. 617-624 (1984) https://doi.org/10.1021/es00126a010
  18. Stone, A. T. and Ulrich, H. J., Oxidation of chlorophenols adsorbed to manganese oxide surfaces, Environ. Sci. Technol., 23(4), pp. 421-428 (1989) https://doi.org/10.1021/es00181a006
  19. Stone, A. T., Reductive dissolution of manganese (III/IV) oxides by substituted phenols, Environ. Sci. Technol., 21(10), pp. 979-988 (1987) https://doi.org/10.1021/es50001a011
  20. Tsuda, T., Takino, A., Muraki, K., Harada, H. and Kojima, M., Evaluation of 4-nonylphenols and 4-tert-octylphenol contamination of fish in rivers by laboratory accumulation and excretion experiments, Water Res., 35, pp. 1786-1792 (2001) https://doi.org/10.1016/S0043-1354(00)00445-0
  21. Yadetie, F. and Male, R., Effects of 4-nonylphenol on gene expression of pituitary hormones in juvenile Atlantic salmon(Salmo salar), Aquat. Toxicol., 58, pp. 113-129 (2002) https://doi.org/10.1016/S0166-445X(01)00242-9
  22. Ying, G. G., Williams, B. and Kookana, R., Environmental fate of alkylphenols and alkylphenol ethoxylates - a review, Environ. Int., 28, pp. 215-226 (2002) https://doi.org/10.1016/S0160-4120(02)00017-X