• Title/Summary/Keyword: SOL

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Correlation Research of Dispersion Factors on the Silica Sol Prepared from Fumed Silica (흄드실리카로부터 제조된 실리카졸의 분산인자 상관성 연구)

  • Park, Min-Gyeong;Kim, Hun;Lim, Hyung Mi;Choi, Jinsub;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.26 no.3
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    • pp.136-142
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    • 2016
  • To study the dispersion factors of silica sol prepared from fumed silica powder, we prepared silica sol under an aqueous system using a batch type bead mill. The dispersion properties of silica sol have a close relationship to dispersion factors such as pH, milling time and speed, the size and amount of zirconia beads, the solid content of fumed silica, and the shape and diameter of the milling impellers. Especially, the silica particles in silica sol were found to show dispersion stability on a pH value above 7, due to the electrostatic repulsion between the particles having a high zeta potential value. The shape and diameter of the impellers installed in the bead mill for the dispersion of fumed silica was very important in reducing the particle size of the aggregated silica. The median particle size ($D_{50}$) of silica sol obtained after milling was also optimized according to the variation of the size and amount of the zirconia beads that were used as the grinding medium, and according to the solid content of fumed silica. The dispersion properties of silica sol were investigated using zeta potential, turbiscan, particle size analyzer, and transmission electron microscopy.

Synthesis of Silica/Alumina Composite Membrane Using Sol-Gel and CVD Method for Hydrogen Purification at High Temperature (Sol-gel 및 CVD법을 이용한 고온 수소 분리용 silica/alumina 복합막의 합성)

  • 서봉국;이동욱;이규호
    • Membrane Journal
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    • v.11 no.3
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    • pp.124-132
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    • 2001
  • Silica membranes were prepared on a porous ${\alpha}$-alumina tube with pore size of 150nm by sol-gel and chemical vapor deposition(CVD) method for hydrogen separation at high temperatures. Silica and ${\gamma}$-lumina membranes formed by the sol-gel method possessed a large amount of mesopores of a Knudsen diffusion regime. In order to improve the $H_2$ selectivity, silica was deposited in the sol-gel derived silica/${\gamma}$-alumina layer by thermal decomposition of tetraethyl orthosilicate(TEOS) at $600^{\circ}C$. The CVD with forced cross flow through the porous wall of the support was very effective in plugging mesopores that were left unplugged in the membranes. The CVD modified silica/alumina composite membrane completely rejected nitrogen permeation and thus showed a high $H_2$ selectivity by molecular sieve effect. the permeation of hydrogen was explained by activated diffusion and the activation energy was 9.52kJ/mol.

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High-sensitivity ZnO gas Sensor with a Sol-gel-processed SnO2 Seed Layer (Sol-Gel 방법으로 제작된 SnO2 seed layer를 적용한 고반응성 ZnO 가스 센서)

  • Kim, Sangwoo;Bak, So-Young;Han, Tae Hee;Lee, Se-Hyeong;Han, Ye-ji;Yi, Moonsuk
    • Journal of Sensor Science and Technology
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    • v.29 no.6
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    • pp.420-426
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    • 2020
  • A metal oxide semiconductor gas sensor is operated by measuring the changes in resistance that occur on the surface of nanostructures for gas detection. ZnO, which is an n-type metal oxide semiconductor, is widely used as a gas sensor material owing to its high sensitivity. Various ZnO nanostructures in gas sensors have been studied with the aim of improving surface reactions. In the present study, the sol-gel and vapor phase growth techniques were used to fabricate nanostructures to improve the sensitivity, response, and recovery rate for gas sensing. The sol-gel method was used to synthesize SnO2 nanoparticles, which were used as the seed layer. The nanoparticles size was controlled by regulating the process parameters of the solution, such as the pH of the solution, the type and amount of solvent. As a result, the SnO2 seed layer suppressed the aggregation of the nanostructures, thereby interrupting gas diffusion. The ZnO nanostructures with a sol-gel processed SnO2 seed layer had larger specific surface area and high sensitivity. The gas response and recovery rate were 1-7 min faster than the gas sensor without the sol-gel process. The gas response increased 4-24 times compared to that of the gas sensor without the sol-gel method.

Comparision of Immobilized TiO2 Catalyst for Water Purification (정수처리용 TiO2 고정화 촉매 비교)

  • Jeon, En Ju;Kang, Sung Hwan;Kim, Byung Ug;Rim, Jay Myung
    • Journal of Korean Society of Water and Wastewater
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    • v.13 no.3
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    • pp.101-106
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    • 1999
  • This research aims to compare immobilized catalysts prepared by various methods and determine suitable $TiO_2$ catalyst for water purification. Sol-gel method by Anderson and powder coation method by Tanaka ate famous in the methods to immobilize catalyst. Therefore, the $TiO_2$ catalyst for this research was prepared by sol-gel method and powder coating method. Its structure was tested by X-ray diffractometer (XRD), Scanning electron microseope (SEM). Durability of a catalyst-support couple in an solution was investigated. too. Experimental results were summarized as following; i) Optimum ratio of Ti : $H_2O$ : $H^+$ to obtain stable sol was 1 : 10 : 0.1 and the XRD patterns of $TiO_2$ film immobilized by sol-gel method which were fired at $700^{\circ}C$ showed that the catalyst had an anatase structure. ii) The particle size of $TiO_2$ prepared by sol-gel method was less than $5{\mu}$, but it was observed that coated side was not unifiom. iii) Sol-gel method was very effective to obtain $TiO_2$ catalyst of thin film, but spreadability and durability of a catalyst-support couple in a solution were than $TiO_2$ film immobilized by powder coating method. iv) The particle size of $TiO_2$ immobilized by powder coating method was a little larger than it prepared by sol-gel method, but spreadability and uniformity of $TiO_2$ film and durability of a catalyst-support couple in a solution were better than it immobilized by sol-gel method.

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Space Composition and Layout of the Location of Seon-Un Temple (선운사 입지의 공간구성과 가람 배치)

  • Young-Han Bae;Jeong-Hae Park
    • Industry Promotion Research
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    • v.9 no.2
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    • pp.137-151
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    • 2024
  • This study analyzes the feng shui characteristics of the location of Seon-un Temple in Do-sol Mountain, Gochang from a metaphysical and selfish perspective through field research and literature review.A characteristic element of feng shui was that it prioritized harmony with nature and made it a reference point for selecting a location through a reasonable method. In the Silla Dynasty, adherent monks studied in the Gangseo area, where the Hyeongsepungsu first appeared, and this Hyeongsepungsu of the Gangseo District Law flowed into Korea and played a leading role in selecting the location of the temple and arranging Garam. Seon-un Temple was located under Do-sol Mountain and had no choice but to have great significance, and it was a practice of the desire to achieve Buddhist perfection through Do-sol Stream and Do-sol Small Temple, which enter the kingdom of Buddha. A s a result, the location of Seon-un Temple under Do-sol Mountain in Gochang reflected a variety of feng shui characteristics. In particular, the location of Sun-un Temple in Do-sol Mountain logically used the characteristics and meanings of feng shui and practiced becoming one with nature, which is aimed at spreading Buddhist doctrine and ideology, which has the holiest meaning of Buddhism.