• 제목/요약/키워드: SEI growth

검색결과 132건 처리시간 0.029초

SEI 성장 모델을 이용한 리튬 이온 배터리의 캘린더 노화 연구 (Study of the Calendar Aging of Lithium-Ion Batteries Using SEI Growth Models)

  • 전동협;채병만;이상우
    • 공업화학
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    • 제35권1호
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    • pp.48-53
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    • 2024
  • 전기화학 기반의 SEI 성장 모델을 이용하여 리튬이온 배터리의 캘린더 노화 및 장기 수명을 예측하였다. 네 가지 유형의 장기 SEI 성장 모델(용매 확산 제한 모델, 전자 이동 제한 모델, 리튬-간극 확산 제한 모델, 반응 제한 모델)을 적용하여 수치해석이 이루어졌고, 캘린더 에이징 동안의 용량 감소와 리튬 재고 손실을 계산하였다. 수치해석 결과, 전자 이동 제한 모델과 리튬-간극 확산 제한 모델이 낮은 용량 감소를 보였으며, 용매 확산 제한 모델과 반응 제한 모델은 10년이내에 80%의 용량 감소를 보였다. 캘린더 노화 중 저온 보관 시 SEI의 성장을 저하시켜 용량 감소가 적었다. 사이클링 중 C-rate가 증가할수록 SEI 두께 증가로 수명 하락이 크게 나타났으나 그 차이는 크지 않았다.

Crouzon's disease 의 증례 (CROUZON'S DISEASE: A Case Report)

  • 손흥규;김순주;최병재;이명숙
    • 대한소아치과학회지
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    • 제11권1호
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    • pp.249-254
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    • 1984
  • This is a case report of Crouzon's disease as a kind of craniofacial dysostosis by premature closure of unilateral coronal suture, showed plagiocephalic skull. 5-year-old boy was visited for the treatment of dental caries and oral examination. Physical examination showed hypertelorism, internal strabismus, and saddle nose. Intraoral radiographs showed congenital missing of upper right and left deciduous and permanent lateral incisors. Cephalometric analysis showed shortening the posterior cranial base length, clockwise growth pattern and class III and open bite tendency. Posterior-anterior and submentovertex view showed multiple radiolucencies-digital impression on inner surface of cranial vault. Maxillo-facial and neuro-surgical treatment was required to improvement of facial esthetics and optic complications. Continuous examination was needed to the growth and development.

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수직 Bridgman 법에 의한 CdTe 단결정 성장에 관한 연구 (A Study on the CdTe Single Crystal Growth by Vertical Bridgman Method)

  • 이종기;김욱;백홍구
    • 한국주조공학회지
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    • 제10권4호
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    • pp.324-331
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    • 1990
  • The single crystal of CdTe was grown by modified 6 zone Bridgman method under the conditions of excess Te and excess Cd. To prevent the constitutional supercooling, the crystal growth was done under the temperature gradient of $17^{\circ}C/cm$ in front of the solid /liquid interface and the growth rate was 3mm/hr. The grain morphologies and the growth mechanism were investigated in excess Te and excess Cd conditions. The grain size of excess Te crystal was increased with an increase of the distance from the tip but, in the case of excess Cd crystal, single crystal was not obtained because of the cavities due to the excess Cd vapors so that the grain size was not increased with an increase of the distance from the tip. In addition, the growth of single crystal of CdTe was done with repeated necking ampoule. It was found that the necking had no effects on the grain selection because the cavities trapped in the necking portion acted as heterogeneous nucleation sites.

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리튬금속전극의 덴드라이트 성장 억제 방안의 연구 동향 (Review on Effective Skills to Inhibit Dendrite Growth for Stable Lithium Metal Electrode)

  • 김예랑;박지혜;황유진;정철수
    • 전기화학회지
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    • 제25권2호
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    • pp.51-68
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    • 2022
  • 리튬금속전지는 높은 에너지 밀도를 구현시킬 수 있음에도 불구하고, 단락, 낮은 쿨롱 효율, 용량 손실, 사이클 성능 감소 등의 문제를 초래하는 덴드라이트 성장을 억제시키는 기술은 아직 학술연구 단계에 머물러 있다. 본 논문에서는 최근까지 발표된 리튬금속전극에서 덴드라이트 성장을 억제시킬 수 있는 방법을 4가지로 분류하여 분석해보았다. 즉, 리튬금속전극의 부피 팽창에 대응할 수 있는 유연한 SEI (solid electrolyte interface) 층, 덴드라이트 성장을 물리적으로 억제시킬 수 있는 SEI 지지층, 균일한 리튬 확산을 유도하여 리튬 성장을 조절하는 SHES (self-healing electrostatic shield) 메커니즘, 그리고 리튬의 균일한 전착을 유도하는 마이크로패터닝 등에 대해 연구된 사례들의 장단점을 분석하여, 리튬금속전극의 실용화 연구에 도움을 주고자 한다.

Novel estimation method of operating life in lithium-ion pouch cells

  • Kim, Hyosung;Kim, Jaekwang;Kim, Nayeong;Lee, Ilbok;Hwang, Keebum;Bae, Joongho;Yoon, Songhun
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.266-275
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    • 2018
  • Herein, a novel operating life (OL) test method was evaluated with 200 mAh pouch-type lithium-ion batteries. By combining the calendar life (CL) test with intermediate pulse power cycling, more realistic life prediction was possible, which encompassed real operation of batteries accompanying with thermal acceleration. Larger capacity decrease and resistance increase of pouch cell were observed in the OL test, which was well explained using the SEI film growth model. After dissemble of pouch cell, capacity loss and resistance increase mostly occurred within anode, reflecting that SEI film growth on anode surface was highly attributable to cell degradation.

E국민학교생 6~11세 아동에 있어서 악안면 연조직의 성장변화에 관한 누년적 연구 (A Longitudinal Study of The Soft Tissue Profile Changes in 6 to 11 Years Children)

  • 박영철;손병화
    • 대한치과의사협회지
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    • 제23권6호통권193호
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    • pp.527-538
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    • 1985
  • The purpose of this study is to evaluate the chronologic changes of the soft tissue profile in 6 to 11 years children. The author analyzed 174 cephalometric roentgenograms of 13 boys and 16 girls taken from the ages of 6 to 11 to assess the growth changes of the soft tissue profile. The results were obtained as follow: 1. Means, standard deviation and coefficient of variation of children were obtained. 2. Items which showed difference between males and females in longitudinal study were prn. Sn. A', and Ls that were greater than females variation. 3. With age, thickness of the soft tissue were increased except Ls. 4. Nasolabial angle and facial convexity had no significant change with age and sex.

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Molecular Basis of Drug Resistance: Epidermal Growth Factor Receptor Tyrosine Kinase Inhibitors and Anaplastic Lymphoma Kinase Inhibitors

  • Yang, Sei-Hoon
    • Tuberculosis and Respiratory Diseases
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    • 제75권5호
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    • pp.188-198
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    • 2013
  • Over the past decade, several kinase inhibitors have been approved based on their clinical benefit in cancer patients. Unfortunately, in many cases, patients develop resistance to these agents via secondary mutations and alternative mechanisms. To date, several major mechanisms of acquired resistance, such as secondary mutation of the epidermal growth factor receptor (EGFR) gene, amplification of the MET gene and overexpression of hepatocyte growth factor, have been reported. This review describes the recent findings on the mechanisms of primary and acquired resistance to EGFR tyrosine kinase inhibitors and acquired resistance to anaplastic lymphoma kinase inhibitors, primarily focusing on non-small cell lung carcinoma.

Effects of Ridge Height in Dry Paddy Field on Growth and Seed Yield of Soybean Cultivars

  • Seong, Rak-Chun;Park, Sei-Joon;Shim, Sang-In
    • 한국작물학회지
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    • 제45권2호
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    • pp.88-92
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    • 2000
  • Excessive soil water in paddy field induces growth losses during the vegetative stages of soybean plants. Our objectives were to know growth responses of soybean as affected by the level of ridge heights. A field experiment was conducted at the Research Farm of Korea University near Seoul in 1996. Ten cultivars of soybean (Glycine max (L.) Merrill) were planted at the ridge heights of 10, 30, and 50cm in paddy soil on 27 June. Total dry matter accumulation at the 10cm ridge height was severely decreased until the growth stage of R5 as compared to the ridge heights of 30 and 50cm, and this decrement was mainly due to both reduced leaf and stem dry weights. However, seed dry weight was not significantly decreased at the lower ridge height with the increment of harvest index. Cultivar differences were found on seed dry weight, crop growth rate from R1 to R5, and leaf/stem ratio of R5. From the above results, soybean growth responses to excessive soil water in paddy field were different between seed filling stage and late vegetative to early reproductive growth stages.

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