• Resources Recycling
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• v.26 no.3
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• pp.3-16
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• 2017

Chemical catalyst products are applied to various fields such as petrochemical process, air pollution prevention facility and automobile exhaust gas purifier. The domestic and overseas chemical catalyst market is increasing every year, and the amount of waste catalyst generated thereby is also increasing. Most of the used chemical catalyst products, such as desulfurized waste catalysts and automobile waste catalysts containing valuable metals are important recyclable resources from a substitute resource point of view. The recycling processes for recovering valuable metals have been commercialized through some urban mining companies, and SCR denitration catalysts have been recycled through some remanufacturing companies. In this paper, the amount of domestic production and recycling of major catalyst products have thus been investigated and analyzed so as to be used as basic data for establishing industrial support policy for recycling of used chemical catalyst products. Also tasks for promoting the recycling of used chemical catalyst products are suggested.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.7
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• pp.832-838
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• 2003

IMO NOx levels are generally possible to meet by means of primary on-engine measures. Nevertheless further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR system is currently the only available technology proven at full scale to meet the 90% NOx reduction levels. Accordingly, maybe the use of an SCR system on board ship provides the solution to minimize this primary pollutant without increasing fuel consumption. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship. employed a two-stroke diesel engine as a main propulsion. which is a training ship in KMU (Korea Maritime Univ.). The purpose of this paper is to report the results about the basic effects of the above system parameters which is investigated from practical application through its trial use. The degree of NOx removal depends on some parameters. such as the amount of urea solution added, space velocity. reaction gas temperature and activity of catalyst. The preliminary results from trial run are presented.

• Journal of Power System Engineering
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• v.19 no.6
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• pp.68-74
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• 2015

NOx emission has been controlled because it is a major cause of the acid rain and effects considerably on formation and destruction of ozone. A SCR system on diesel engine is necessary to clear TierIII, because IMO(International Maritime Organization) plans on tightening regulations to TierIII at $1^{st}$ January 2016. In this study, flow analysis was accomplished with ANSYS Fluent program so that the SCR system would be retrofitted in training ship KAYA and the temperature distributions of exhaust gas in SCR sytem were investigated after it was installed. As a result, it was confirmed that pressure and velocity distributions in SCR system were depended on pipe line shapes, then it was designed as the pressure was lower. The temperature differential between 1 and 3 point was $15^{\circ}C$ because of evaporative latent heat of urea and the temperature of 4 point after catalyst was increased by $5^{\circ}C$ than 3 point because of exothermic reaction.

• Journal of Power System Engineering
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• v.14 no.6
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• pp.13-19
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• 2010

이 논문에서는 디젤자동차용 LNT와 SCR 촉매의 NO, $NH_3$ 흡착 및 탈리의 기본 특성과 수열화 온도와 시간 및 정량화된 황피독 농도에 대한 de-$NO_x$ 촉매의 내구성을 평가하였다. LNT 촉매는 열적으로 열화됨에 따라 Pt 및 Ba의 소결 및 응집으로 활성이 떨어져 $NO_x$ 전환율은 감소하였다. 반면에 Pt의 비활성화로 중간생성물인 $NH_3$ 생성량은 증가하였으며, 이때 생성된 $NH_3$는 LNT+SCR 복합시스템의 SCR 촉매의 환원제 역할을 담당한다. 1.0 g/L 이상의 황이 피독된 LNT 촉매는 탈황을 하여도 질소 산화물 흡장물질(Ba) 의 성능이 회복이 되지 않아 $NO_x$ 전환율은 회복되지 않았으며, 탈황 후 Pt 재활성화로 인해 NO2 및 SCR 환원제인 $NH_3$ 생성량은 증가하였다. SCR 촉매의 $NO_x$ 전환율은 $700^{\circ}C$ 36h, $800^{\circ}C$ 24h로 수열화 시킨 촉매는 전이금속 입자 성장 및 zeolite 구조 파괴로 인하여 급격하게 떨어졌으며, 0.36 g/L 황 피독된 촉매는 zeolite가 가지는 강산성 특정으로 내피독성이 강하여 탈황시 $NO_x$ 전환율은 회복되었다.

• Korean Chemical Engineering Research
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• v.52 no.4
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• pp.443-450
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• 2014

Selective catalytic reduction of nitrogen monoxide by hydrogen ($H_2$-SCR of NO) over platinum catalysts impregnated on zirconia-incorporated silica ($ZrO_2-SiO_2$) and manganese oxide ($MnO_x$) was investigated. $Pt-MnO_x$ catalyst showed low conversions and low yields of $N_2O$ and $NO_2$ at $100{\sim}350^{\circ}C$. On the other hand, NO conversions over $Pt/ZrO_2-SiO_2$ were very high, but $N_2O$ was predominantly produced at $100-150^{\circ}C$ and the yield of $NO_2$ increased with temperature at $200-300^{\circ}C$, resulting in poor $N_2$ yields. $Pt-MnO_x/ZrO_2-SiO_2$ exhibited a small enhancement in $N_2$ yield at $100-150^{\circ}C$ due to the synergy of $MnO_x$ and $ZrO_2-SiO_2$. The surface composition and oxidation state of the catalyst components and the acidity of the catalysts were examined. IR spectra of the adsorption of NO and their subsequent reactions with hydrogen on these catalysts were also recorded. The variations of conversion and product yield according to the catalyst components in the $H_2$-SCR of NO were discussed in relation to their catalytic roles.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.2
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• pp.265-273
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• 2011

HC-SCR was conducted using Fe/ZSM5 catalyst coated over 200 cpi cordierite in the conditions of atomspheric pressure and $200^{\circ}C-500^{\circ}C$. Among the tested hydrocarbon reductants, isobutane (i-$C_4H_{10}$) showed the highest de-$NO_x$ yield of 69% at $320^{\circ}C$ with the mole ratio of reductant/$NO_x$ =1.0. De-$NO_x$ yield resulted by the change of alkane reductant was increased as the carbon number of alkane reductant was increased. The order of increase of de-$NO_x$ yield was proportional to the order of decrease of bonding energy between C and H of reductant, where the H abstraction step from alkane molecule could be the rate controlling step of HC-SCR.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.12
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• pp.2255-2261
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• 2000

To eliminate $NO_x$ in diesel emission. selective catalyst reduction (SCR) was used in real diesel engine. Among the SCR methods, metal oxide and perovskite catalysts were introduced in this paper. The removal efficiencies with various major, promoter catalysts on ${\gamma}-Al_2O_3$ at different reaction temperature were investigated, and $LaCuMnO_x$ catalyst which has high removal efficiency at the temperature of real diesel exhaust gas was selected. $NO_x$ reduction was carried out over these catalysts in the flow-through type reactor using by-pass ($SV=3,300h^{-1}$). Under the given condition to this study, perovskite catalysts showed considerably high removal efficiency and $LaCuMnO_x$ was the best one among these catalysts in the temperature range of $150{\sim}450^{\circ}C$.

• Proceedings of the KAIS Fall Conference
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• 2011.12b
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• pp.496-498
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• 2011

본 논문에서는 알루미늄 드로스를 재활용하여 생성 된 수산화알루미늄을 이용하여 질소산화물 제거 SCR 촉매를 제조하였다. 현재 상용중인 촉매와 화학적 특성과 질소산화물 제거 효율을 비교하기 위해 동일 타입의 하니컴 형태의 $V_2O_5-WO_3-TiO_2-Al_2O_3$ SCR 촉매를 제조하였으며, XRF와 BET를 사용하여 화학적 특성을 평가 비교하였다. 또한 MR(Micro Reactor)을 이용하여 $350^{\circ}C$와 $450^{\circ}C$에서 질소산화물 제거 평가를 실시하였으며, 평가 결과 80~90%의 제거 효율을 확인하였다.

• 한국전산유체공학회:학술대회논문집
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• 2010.05a
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• pp.368-375
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• 2010

To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the NH3-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed device. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of NH3 by numerical simulation.

• Journal of computational fluids engineering
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• v.15 no.4
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• pp.9-16
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• 2010

To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the $NH_3$-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore, it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed devices. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of $NH_3$ by numerical simulation.