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Growth and Characterization for $CdIn_2S_4/GaAs$ Epilayers ($CdIn_2S_4$ 에피레이어 성장과 특성)

  • Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.239-242
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    • 2004
  • A stoichiometric mixture of evaporating materials for $CdIn_2S_4$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, $CdIn_2S_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by hot wall epitaxy(HWE) system. The source and substrate temperatures were $630^{\circ}C$ and $420^{\circ}C$ respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction(DCXD). The carrier density and mobility of $CdIn_2S_4$ single crystal thin films measured from Hall effect by van der Pauw method are $9.01{\times}10^{16}\;cm^{-3}$ and $219\;cm^2/V{\cdot}s$ at 293 K, respectively. From the optical absorption measurement, the temperature dependence of energy band gap on $CdIn_2S_4$ single crystal thin films was found to be $E_g(T)\;=\;2.7116\;eV\;-\;(7.74{\times}10^{-4}\;eV)T^2/(T+434)$. After the as-grown $CdIn_2S_4$ single crystal thin films was annealed in Cd-, S-, and In-atmospheres, the origin of point defects of $CdIn_2S_4$ single crystal thin films has been investigated by the photoluminescence(PL) at 10 K.

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Photoconductive Property and Its Application of $Sb_2S_3$ Thin film ($Sb_2S_3$ 박막의 광도전특성 및 그 응용)

  • Yun, Young Hoon;Park, Ki Cheol;Choi, Gyu Man;Kim, Ki Wan
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.5
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    • pp.699-705
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    • 1986
  • Sb2S3 thin films were fabricated by vacuum evaporation of compound Sb2S3 at a pressure of 10**-5 torr. and in argon ambient. Then, their electrical and photoconductive properties were investigated. The Sb2S3 glass-layer showed maximum photosensitivity at the deposition rate of 250\ulcornersec, and Sb2S3 porous layer had mininum dielectric constant of 1.5 at the deposition rate of 0.3 um/sec and argon partial pressure of 0.2torr. Sb2S3 multi-layers were prepared at the different thickness ratio (B/A) to find the proper structural property suited for camera pick-up tube. Here, A is the sum of the thickness of Sb2S3 porous layer and Sb2S3 fine grain layer, and B is the thickness of Sb2S3 fine grain layer. As a result, photosensitivity had a peak value at the thickness ratio (B/A) of 60%.

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Improvement of precipitation forecasting skill of ECMWF data using multi-layer perceptron technique (다층퍼셉트론 기법을 이용한 ECMWF 예측자료의 강수예측 정확도 향상)

  • Lee, Seungsoo;Kim, Gayoung;Yoon, Soonjo;An, Hyunuk
    • Journal of Korea Water Resources Association
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    • v.52 no.7
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    • pp.475-482
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    • 2019
  • Subseasonal-to-Seasonal (S2S) prediction information which have 2 weeks to 2 months lead time are expected to be used through many parts of industry fields, but utilizability is not reached to expectation because of lower predictability than weather forecast and mid- /long-term forecast. In this study, we used multi-layer perceptron (MLP) which is one of machine learning technique that was built for regression training in order to improve predictability of S2S precipitation data at South Korea through post-processing. Hindcast information of ECMWF was used for MLP training and the original data were compared with trained outputs based on dichotomous forecast technique. As a result, Bias score, accuracy, and Critical Success Index (CSI) of trained output were improved on average by 59.7%, 124.3% and 88.5%, respectively. Probability of detection (POD) score was decreased on average by 9.5% and the reason was analyzed that ECMWF's model excessively predicted precipitation days. In this study, we confirmed that predictability of ECMWF's S2S information can be improved by post-processing using MLP even the predictability of original data was low. The results of this study can be used to increase the capability of S2S information in water resource and agricultural fields.

Effects of the Preparation Process on the Synthesis and the Luminescence of Ba2SiO4:Eu2+ Phosphor Powders (합성공정이 Ba2SiO4:Eu2+ 형광체 분말의 합성과 발광특성에 미치는 영향)

  • Park, Jung Hye;Kim, Young Jin
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.184-189
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    • 2013
  • $Ba_2SiO_4:Eu^{2+}$ ($B_2S:Eu^{2+}$) powders were prepared by firing the dry gel obtained by the sol-gel and the hybrid process (sol-gel and combustion), respectively, and their structure and luminescence were investigated. Tetraethyl orthosilicate (TEOS) was used as a Si source. The phase transition was observed with the TEOS content. With 1.2M TEOS, the powders prepared by the sol-gel process without prior calcination were composed of the $B_2S:Eu^{2+}$ single phase, whereas those by the sol-gel and the hybrid process with prior calcination consisted of the dominant $B_2S:Eu^{2+}$ and minor $BaSiO_3:Eu^{2+}$ ($BS:Eu^{2+}$) phases and their emission intensities were approximately two times higher than those without prior calcination. The hybrid process could reduce the process time innovatively compared to the sol-gel process, even though the former was a little inferior to the latter in the emission intensity of $B_2S:Eu^{2+}$. With 1.1M TEOS, the $B_2S:Eu^{2+}$ single phase was obtained by the hybrid process, and its green emission was observed at 505 nm originated from the $4f^65d^1{\rightarrow}4f^7$ transition of $Eu^{2+}$ ions.

A Newly Designed a TiO2-Loaded Spherical ZnS Nano/Micro-Composites for High Hydrogen Production from Methanol/Water Solution Photo-Splitting

  • Kim, Ji-Eun;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2133-2139
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    • 2012
  • A new system using $TiO_2$ (nano-sized, band-gap 3.14 eV)-impregnated spherical ZnS (micro-sized, band-gap 2.73 eV) nano/micro-composites (Ti 0.001, 0.005, 0.01, and 0.05 mol %/ZnS) was developed to enhance the production of hydrogen from methanol/water splitting. The ZnS particles in a spherical morphology with a diameter of about 2-4 mm which can absorb around 455 nm were prepared by hydrothermal method. This material was used as a photocatalyst with loading by nano-sized $TiO_2$ (20-30 nm) for hydrogen production. The evolution of $H_2$ from methanol/water (1:1) photo splitting over the $TiO_2$/ZnS composite in the liquid system was enhanced, compared with that over pure $TiO_2$ and ZnS. In particular, 1.2 mmol of $H_2$ gas was produced after 12 h when 0.005 mol % $TiO_2$/ZnS nano/micro-composite was used. On the basis of cyclic voltammeter (CV) and UV-visible spectrums results, the high photoactivity was attributed to the larger band gap and the lower LUMO in the $TiO_2$/ZnS composite, due to the decreased recombination between the excited electrons and holes.

Mixed Convection Heat Transfer from Vertical In-Line Plates (수직 배열된 평판에서 혼합대류 열전달)

  • Kim, S.Y.;Ree, J.S.;Kwon, S.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.2
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    • pp.123-130
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    • 1991
  • The mixed convection heat transfer from vertical inline plates has been studied numerically by the finite difference method and experimentally with Mach-Zehnder interferometer. The dimensionless spacing, $s/L_1$, the relative length, $L_2/L_1$ and the dimensionless temperature ratio, ${\Phi}_2/{\Phi}_1$ are varied parametically. The lower plate mean Nusselt numbers show same values as $s/L_1$, ${\Phi}_2/{\Phi}_1$ and $L_2/L_1$ increase. The upper plate mean Nusselt numbers increase as $s/L_1$ and ${\Phi}_2/{\Phi}_1$ increase, but $L_2/L_1$ decreases. The upper plate mean Nusselt number is higher than the lower plate mean Nusselt for $s/L_1$ 1.8 at Re=100, $Gr=10^4$, Pr=0.71, $L_2/L_1=0.5$ and ${\Phi}_2/{\Phi}_1=1.0$. A comparison between the experimental and numerical results show good agreement.

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Optical proper of S solute CuInSe$_2$ thin film (S를 고용한 CuInSe$_2$ 박막의 광학 특성)

  • 김규호;이재춘;김민호;배인호
    • Journal of the Korean institute of surface engineering
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    • v.30 no.2
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    • pp.136-143
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    • 1997
  • The photvoltaic power system has received considerable attention as the petroleumalterative energies to the environmental problems in the wored scale. $CuLnSe_2$is one ofthe most promising materials for the fabrication of large-area modules and low cost photovoltaic devices. Sulfur solute CuInSe2 thin films were prepared by RF sputtering using powder targer which were previously compacted by powder of $Cu_2Se, \;In_2Se_3, \;Cu_2S, \;and\;In_2S_3$ in various ratios. The results induicated that the sulfur ratio, the(112) texture, and the energy band gap were increased by the increase of the S/(S+Se) that was controlled by stoichiometric compound. The energy band gap can be shifted from 1.04eV to 1.50eV by abjusting the S/(S+Se) ratio, which maich it possible to obtain perfect match to the solar spectrum.

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Investigation of Optimal ionic Concentration of Nutrient Solution for the Water Culture of Young Welsh Onion (실파의 수경재배에 적합한 양액농도 구명)

  • Won Jae Hee;Kim Sang Soo;Jeong Byung Chan;Park Kuen Woo
    • Journal of Bio-Environment Control
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    • v.14 no.4
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    • pp.269-274
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    • 2005
  • The purpose of this experiment was to investigate optimal ionic concentration of nutrient solution for water culture of young welsh onion (Allium fistulosum). For the purpose of clarification of optimal nutrient concentration to maximize growth of young welsh onion, different nutrient concentrations of Yamazaki's solution for welsh onion seedling $(NO_3^--N\;9.0,\;NH_4^+-N\;3.0,\;PO_4^{3-}-P\;6.0,\;K^+7.0,\;Ca^{2+}\;2.0,\;Mg^{2+}\;2.0,\;and\;SO_4^{2-}-S\;4.4me{\cdot}L^{-1})$ which selected by prior experiment were treated as 0.6, 1.2, 1.8, and $2.4dS{\cdot}m^{-1}$. Increments of fresh weight, dry weight and top length were the highest in 1.2 and, in the next, were placed by the order of 1.8, 2.4, and $0.6dS{\cdot}m^{-1}$ The regression coefficients for the maximal growth of fresh weight of cv. 'Geurnjanguedaepa' and 'Tokyokuro' were $y=-42.091x^2+171.79x+11.047 (R^2=0.8946,\; R=0.9458^*)\;and\;y=-50.069x2+157.58x+15.414(R^2=0.9343,\;R=0.9692^{**})$, respectively, and optimal EC levels according to regression coefficients were 1.68 and $1.57dS{\cdot}m^{-1}$. As the conclusions, optimal nutrient levels far young welsh onion were $1.2dS{\cdot}m^{-1}$ EC in the early growth stage and $1.6\~l .7dS{\cdot}m^{-1}$ in the later growth stage.

Quality Characteristics of Natto Made by Different Ingredients (재료 구성을 달리하여 제조한 Natto 의 품질특성)

  • O, Seong-Cheon;Jo, Jeong-Sun;Nam, Hae-Yeong
    • Journal of the Korean Dietetic Association
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    • v.6 no.2
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    • pp.117-124
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    • 2000
  • Natto, Traditional Japanese food fermented by Bacillus Natto, has been well known for a good nutritional food. However it has particular flavor, so most Koreans are not fond of it. That is the reason why, garlic(2%) and ginseng(2%) were added to make Natto, acceptable to Koreans. General soybean Natto($S_1$), 2% garlic Natto($S_2$), 2% ginseng Natto($S_3$) and blacksoybean Natto($S_4$) were prepared. The proximate composition revealed the most moisture content in $S_2$among the all samples. The most crude protein, crude fat and ash were found in $S_4$. The non-fibrous and fiber contents were the most in $S_1$and $S_3$. In the texture characteristics, hardness and gumminess were the highest in $S_4$. The highest springness and cohesiveness were found in $S_1$. Adhesiveness and chewing were the best in $S_2$and $S_3$. The minerals composition revealed the most calcium content in $S_3$among the all samples. Fatty acid compositions were mainly consisted of linoleic acid(46.91~48.47%). In the sensory evaluation, $S_3$showed the best preference, appearance and color. In the aspects of taste and texture, $S_4$was mostly preferred. Flavor and viscosity of $S_2$were the best among the all samples. The general soybean Natto($S_1$) without any addition showed low values in most examinations and tests. In the sensory evaluation, $S_3$has the best overall acceptability among the all experimental Nattos.

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Preparation of $NbS_2$ thin film using PLD method (PLD 장치를 이용한 $NbS_2$ 박막의 제작)

  • Park, Jong-Man;Lee, Hea-Yeon;Jeong, Jung-Hyun
    • Journal of Sensor Science and Technology
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    • v.7 no.5
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    • pp.372-376
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    • 1998
  • We developed a pulsed laser deposition(PLD) apparatus for depositing various thin films. In this study, the formation of $NbS_2$ thin film was performed in the vacuum chamber by PLD method. $Al_2O_3$(012) and Si(111) were used as the substrates. In order to investigate the growth conditions of a high crystalline $NbS_2$ thin film, the S/Nb composition ratio was varied from 2.0 to 5.25 and the substrate temperature was varied from the room temperature to $600^{\circ}C$. From the result of X-ray diffraction studies of the prepared $NbS_2$ thin films, it was reported that the $NbS_2$, thin film showed a good crystallinity at substrate temperature $600^{\circ}C$ and with S/Nb composition ratio 4.0 on $Al_2O_3$(012) but did not on Si(111). The films exhibited c-axis orientation.

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