• Title/Summary/Keyword: S-PVA

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A Study on Pyroelectric Properties of PLZT/PVA Composite Material (PLZT/PVA 복합재료의 초전특성에 관한 연구)

  • Lee, E.S.;Choi, S.C.;Park, H.;Kim, J.W.
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.605-612
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    • 1990
  • In Pb1-xLax(Zry, Tiz)1-x/4O3 system, it selects the composition 7/65/35 (x=7, y=65, z=35) that was reported to have eminent Pyroelectric properties, and that is sintered with PbZrO3+0.3wt.% PbO2 atmosphere powder. From the sintered ceramic and Poly Vinyl Alcohol, the thin wafers are fabricated with 0-3connectivity, and they are researched in Pyroelectric properties and the others according to volume ratio between ceramic and polymer. It was possible to fabricate the film containing ceramic up to 80vol% in PVA polymer. The increment of PLZT ceramic volume fraction improve the pyroelectric coefficient of the composite. On Pyroelectric coefficient and the figure of merit, a little inflection caused by glass point(Tg) of PVA appeared. The degree of inflection is proportioned to the amount of PVA.

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PVA/Silica Hybrid Membrane Containing Sulfonic Acid Croup for Direct Methanol Fuel Cells Application (Sulfonic acid group을 갖는 PVA/Silica Hybrid막의 DMFC 응용)

  • Young Moo Lee;Dae Sik Kim;Kwang Ho Shin;Ho Bum Park;Ji Won Rhim
    • Membrane Journal
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    • v.13 no.2
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    • pp.101-109
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    • 2003
  • In the present study, crosslinked poly(vinyl alcohol) (PVA) membranes were prepared at various crosslinking agent content using sulfosuccinic acid (SSA) containing sulfonic acid group ($SO_3H)$. To reduce methanol permeability, silica was introduced to the membrane using sol-gel process. The hybrid membranes were studied in relation to proton conductivity and methanol permeability. It was found that both these properties were very dependent on the effect of SSA content as a crosslinking agent and as a donor of hydrophilic $SO_3H)$ group. The proton conductivities of these PVA/SSA/Silica membranes are in the range from $10^{-3}\;to\;10^{-2}$S/cm and the methanol permeabilities are in the range from $10^{-8}\;to\;10^{-7}\;cm^2/sec$.

Fabrication of Electrospun Juniperus Chinensis Extracts loaded PVA Nanofibers (향나무 추출물을 함유하는 PVA 나노섬유 제조)

  • Kim, Jeong-Hwa;Lee, Jung-Soon
    • Science of Emotion and Sensibility
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    • v.19 no.2
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    • pp.35-42
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    • 2016
  • Electrospinning is a simple and effective process for producing nanofiber with diameter range from nanometers to micrometers which have high specific surface area. Hence, medicated nanofibers can be readily fabricated using a solution containing a mixture of a plant-extracts and a polymer. It has proved that Juniperus Chinensis can be effectively used for the prevention of UV and SLS-induced advers skin reaction such as radical production, inflammation and skin cell damage. It also found that Juniperus Chinensis has efficient ingredient of antifungal activity and house dust mite repellent effect. The fabrication of PVA nanofibers containing Juniperus Chinensis extracts by electrospinning has been studied. PVA/Juniperus Chinensis extracts composite nanofibers were produced at different Juniperus Chinensis concentrations (0.25, 0.5, 1.5 wt. %). The parameters of electrospinning including polymer contents, voltage and tip-to-collector distance (TCD) were optimized for fabrication process. The study show that 12 wt. % PVA, 10kV applied voltage and TCD 10~20 cm are the best condition to obtain uniform PVA/Juniperus Chinensis extracts composite nanofibers. Morphologies of the electrospun composite nanofiber were observed by using a field emission scanning electron microscope. It has been found that the average diameters of fibers increased by the adding of Juniperus Chinensis extracts. As the results, PVA/Juniperus Chinensis extracts composite nanofibers having a diameter in the range from 310~360 nm were successfully prepared via an electrospinning.

Tensile Behavior of Hybrid Fiber Reinforced Cement Composite According to the Hooked Steel Fiber and Polyvinyl Alcohol Fiber Blending Ratio and Strain Rate (후크형 강섬유와 폴리비닐알코올 섬유의 혼합 비율과 변형속도에 따른 하이브리드 섬유보강 시멘트복합체의 인장거동)

  • Son, Min-Jae;Kim, Gyu-Yong;Lee, Sang-Kyu;Kim, Hong-Seop;Nam, Jeong-Soo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.98-105
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    • 2017
  • In this study, the fiber blending ratio and strain rate effect on the tensile behavior of hybrid fiber reinforced cement composite was evaluated. Hooked steel fiber and polyvinyl alcohol fiber were used for reinforcing fiber. The fiber blending ratio of HSF+PVA were 1.5+0.5, 1.0+1.0 and 0.5+1.5vol.%. As a results, the tensile strength, strain capacity and fracture toughness of the hooked steel fiber reinforced cement composites were improved by the increase of the bond strength of the fiber and the matrix according to increase of strain rate. However, the tensile stress sharply decreased after the peak stress because of the decrease in the number of straightened pull-out fibers by micro cracks in the matrix around hooked steel fiber. On the other hand, PVA fiber showed cut-off fracture at strain rate $10^{-6}/s$ with multiple cracks. However, at the strain rate $10^1/s$, the multiple cracks and strain capacity were decreased because of the pull-out fracture of PVA fiber. The HSF1.5PVA0.5 shown the highest tensile strength because the PVA fiber suppressed the micro cracks in the matrix around the hooked steel fiber and improved the pull-out resistance of hooked steel fiber. Thus, DIF of strain capacity and fracture toughness of HSF1.5PVA were greatly improved. In addition, the synergistic response of fracture toughness was positive because the tensile stress was slowly decreased after the peak stress by improvement of the pull-out resistance of hooked steel fiber at strain rate $10^1/s$.

A Study on Optimal Conditions by means of Experimental Design for Preparation of Starch/PVA Blends 1. Taguchi method (실험계획법을 이용한 전분/PVA 블렌드 제조 최적조건 탐구에 관한 연구 1. 다구찌 방법)

  • Lee, Myoung-Seok;Hong, Young-Keun
    • Elastomers and Composites
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    • v.40 no.2
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    • pp.128-135
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    • 2005
  • Optimal conditions for preparation of starch/PVA blends were investigated with the consideration of factors that may influence mechanical properties of the blends. $L_{27}(3^{13})$ experimental designs based on Taguchi method were performed and then tensile strength, strain at break, Young's modulus and tear strength of films of the blends were measured to determine the optimal conditions for preparation. Interaction effects for each factor were determined from analysis of variables. Results of $L_{27}(3^{13})$ experiments indicated that glycerol and urea were important process factors affecting optimization of the mechanical properties.

Preparation and Property of Ceramic/Polymer 3-3 Composites with Matrices (각종 Matrix를 이용한 Ceramic/Polymer 3-3 Composies의 제작 및 특성)

  • Park, J.H.;SaGong, G.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1122-1124
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    • 1993
  • In this study, piezoceramics/polymer composites with 3-3 connectivity were made by BURPS(Burnout Plastic Sphere) technique with PZT ceramics and PVA sphere. And physical and dielectric properties dependent on the PVA wt.% were investigated. The density of porous piezoceramic and pieaoceramic/polymer composites were decreased almost linearly with increasing the PVA wt.%.

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Preparation and Characterization of PVA/PSSA-MA Electrolyte Membranes Containing Silica Compounds and Surface Fluorination for Fuel Cell Applications (연료전지 응용을 위한 실리카 성분을 함유하며 표면불소화된 PVA/PSSA-MA 막의 제조 및 특성 연구)

  • Kim, Dae-Hoon;Lee, Bo-Sung;Rhim, Ji-Won
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.540-546
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    • 2010
  • In this manuscript, in order to reduce methanol permeability and, at the same time, to increase proton conductivity THS-PSA containing silica compound, responsible for methanol permeability reduction, and sulfonic acid, responsible for proton conductivity enhancement, was applied onto PVA/PSSA-MA membranes. And in order to improve durability, the resulting membranes, PVA/PSSAMA/THS-PSA, were exposed to 500ppm F2 gas at varying reaction times. The surface-fluorinated membranes were characterized through the measurement of contact angles, thermo-gravimetric analysis, and X-ray photoelectron spectroscopy to observe the physico-chemical changes. For the evaluation of the electro-chemical changes in the resulting membranes, its water contents, ion exchange capacity, proton conductivity, and methanol permeability were measured and then compared with the commercial membrane, Nafion 115. Finally, the membran electrode assembly(MEA) was prepared and the cell voltage against the current density was measured. As fluorination time increased, the contents of F2 increased up to maximum 4.3% and to depth of 50 nm. At 60 min of fluorination, the proton conductivity was 0.036 S/cm, larger than Nafion 115 at 0.024 S/cm, and the methanol permeability was $9.26E-08cm^2/s$, less than Nafion 115 at $1.17E-06cm^2/s$.

World's Largest 54-inch TFT-LCD for HDTV Application Using PVA Technology

  • Kim, K.H.;Seomun, S.S.;Chang, H.S.;Song, J.K.;Tak, Y.M.;Kim, S.S.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.288-291
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    • 2003
  • The technology and performance of the world-largest 54-inch LCD TV using PVA mode have been introduced from two points of view: one is to manufacture large-size panels, the other is to improve electro-optical performance required for multimedia applications. Current ongoing research activities that have been explored include new stitching design, one drop filling with column spacer, response time less than one frame rate, color performance and light efficiency enhancement.

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Influence of Surfactant on the Iodine Complex Formation of Some Non-ionic Polymers (비이온성 고분자의 Iodine 착물형성에 대한 계면활성제의 영향)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1031-1037
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    • 2018
  • The formation of a complex between PVP or HPC and iodine was indicated by a red shift in the tri-iode band while PVA-iodine complex showed its characterized band around 500 nm in pure aqueous media. Addition of surfactant SDS resulted in a disapperance of the characteristic blue color of the PVA-iodine complex indicating that the complex is not formed in aqueous surfactant media. However in case of PVP or HPC, presence of the monomers of SDS favored the complex formation but in higher concentration, the micelles of SDS decreased the complex. Complexation was found to increase with increasing content of n-propanol in the system since n-propanol inhibits the formation of gels or microgels in the polymer solution. But in case of PVA-iodine complex, addition of n-propanol led to conversion of bigger polyiodides into smaller ones, which is indicative of increased intermolecular hydrogen bond interaction between propanol and PVA effecting a decrease in the PVA aggregate space.

Super-PVA (S-PVA) Technology for HDTV Application

  • Kim, Kyeong-Hyeon;Berkeley, Brian;Kim, Sang-Soo;Souk, Jun-Hyung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.26-29
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    • 2004
  • S-PVA is a new technology which enables screen quality advantages over S-IPS and MVA, including high transmittance, >1000:1 contrast ratio, sub-10ms response time, and wide angle of view with no off-axis image inversion and undetectable gamma distortion. This new technology will be described in detail. This paper also addresses the other remaining performance issues facing LCD-TV, including Samsung's plans for addressing these challenges. For example, until recently, inter-gray response time and associated motion blur were significant issues for achieving LCD-TV images quality. Samsung has invented DCC-II technology to achieve sub-10ms response time, and this achievement is described herein. Other technology advancements, including next-generation color performance and ultra-low black performance and improvement of off axis image quality are also discussed in this paper.

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