• Title/Summary/Keyword: Rough electrode

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Optical Properties of Soluble Polythiophene for Flexible Solar Cell

  • Kim, Byoung-Ju;Park, Eun-Hye;Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • v.6 no.4
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    • pp.91-93
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    • 2018
  • Polythiophene-$TiO_2$ composite was synthesized with different molar ratios of thiophene and titaniumisopropoxide ($Ti(OPr)_4$) for flexible solar cell application as a flexible electrode or an active material. The $Ti(OPr)_4$ was stabilized by thiophene. The thiophene was polymerized by ferric chloride catalyst. The synthesized polythiophene exhibited strong UV-visible absorption in the range of the wavelength shorter than 500 nm. Field emission scanning electron microscope (FESEM) image of low concentration of $TiO_2$ film showed smooth surface. However, FESEM image of high concentration of $TiO_2$ film exhibited relatively rough surface. Polythiophene concentration dependent strong photoluminescence quenching of surfrhodamine-B was observed.

Enhanced Si based negative electrodes using RF/DC magnetron sputtering for bulk lithium ion batteries

  • Hwang, Chang-Muk;Park, Jong-Wan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.277-277
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    • 2010
  • The capacity of the carbonaceous materials reached ca. $350\;mAhg^{-1}$ which is close to theorestical value of the carbon intercalation composition $LiC_6$, resulting in a relatively low volumetric Li capacity. Notwithstanding the capacities of carbon, it will not adjust well to the need so future devices. Silicon shows the highest gravimetric capacities (up to $4000\;mAhg^{-1}$ for $Li_{21}Si_5$). Although Si is the most promising of the next generation anodes, it undergoes a large volume change during lithium insertion and extraction. It results in pulverization of the Si and loss of electrical contact between the Si and the current collector during the lithiation and delithiation. Thus, its capacity fades rapidly during cycling. We focused on electrode materials in the multiphase form which were composed of two metal compounds to reduce the volume change in material design. A combination of electrochemically amorphous active material in an inert matrix (Si-M) has been investigated for use as negative electrode materials in lithium ion batteries. The matrix composited of Si-M alloys system that; active material (Si)-inactive material (M) with Li; M is a transition metal that does not alloy with Li with Li such as Ti, V or Mo. We fabricated and tested a broad range of Si-M compositions. The electrodes were sputter-deposited on rough Cu foil. Electrochemical, structural, and compositional characterization was performed using various techniques. The structure of Si-M alloys was investigated using X-ray Diffractometer (XRD) and transmission electron microscopy (TEM). Surface morphologies of the electrodes are observed using a field emission scanning electron microscopy (FESEM). The electrochemical properties of the electrodes are studied using the cycling test and electrochemical impedance spectroscopy (EIS). It is found that the capacity is strongly dependent on Si content and cycle retention is also changed according to M contents. It may be beneficial to find materials with high capacity, low irreversible capacity and that do not pulverize, and that combine Si-M to improve capacity retention.

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Self-textured Al-doped ZnO transparent conducting oxide for p-i-n a-Si:H thin film solar cell

  • Kim, Do-Yeong;Lee, Jun-Sin;Kim, Hyeong-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.50.1-50.1
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    • 2009
  • Transparent conductive oxides (TCOs) play an important role in thin-film solar cells in terms of low cost and performance improvement. Al-doped ZnO (AZO) is a very promising material for thin-film solar cellfabrication because of the wide availability of its constituent raw materials and its low cost. In this study, AZO films were prepared by low pressurechemical vapor deposition (LPCVD) using trimethylaluminum (TMA), diethylzinc(DEZ), and water vapor. In order to improve the absorbance of light, atypical surface texturing method is wet etching of front electrode using chemical solution. Alternatively, LPCVD can create a rough surface during deposition. This "self-texturing" is a very useful technique, which can eliminate additional chemical texturing process. The introduction of a TMA doping source has a strong influence on resistivity and the diffusion of light in a wide wavelength range.The haze factor of AZO up to a value of 43 % at 600 nm was achieved without an additional surface texturing process by simple TMA doping. The use of AZO TCO resulted in energy conversion efficiencies of 7.7 % when it was applied to thep-i-n a-Si:H thin film solar cell, which was comparable to commercially available fluorine doped tin oxide ($SnO_2$:F).

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Improved Light Output of GaN-Based Light-Emitting Diodes with ZnO Nanorod Arrays (ZnO 나노로드 배열에 의한 GaN기반 광다이오드의 광추출율 향상)

  • Lee, Sam-Dong;Kim, Kyoung-Kook;Park, Jae-Chul;Kim, Sang-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.59-60
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    • 2008
  • GaN-based light-emitting diodes (LEDs) with ZnO nanorod arrays on a planar indium tin oxide (ITO) transparent electrode were demonstrated. ZnO nanorods were grown into aqueous solution at low temperature of $90^{\circ}C$. Under 20 mA current injection, the light output efficiency of the LED with ZnO nanorod arrays on ITO was remarkably increased by about 40 % of magnitude compared to the conventional LED with only planar ITO. The enhancement of light output by the ZnO nanorod arrays is due to the formation of side walls and a rough surface resulting in multiple photon scattering at the LED surface.

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Machining Characteristics According to the Thickness Change When Wire-cut Electrical Discharge Machining of Tungsten Carbide (초경합금재 와이어컷 방전가공시 두께변화에 따른 가공 특성)

  • 이재명;김원일;이윤경;왕덕현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2000.05a
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    • pp.820-823
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    • 2000
  • The characteristics of wire deflection, surface roughness and roundness were observed on changing discharge time for electrical discharge machining(EDM) of tungsten carbide in various conditions of thickness. The wire deflection was decreased as increasing discharge time and wire tension, the gap of deflection was decreased after thickness 60mm and discharge time of 6$\mu\textrm{s}$ due to the changing from fundamental mode to vibration mode. The deflection is the smallest at the water specific resistivity of 7.5 kΩ ㆍcm. The deflection is found to be decreased as increasing dwell time, and the result is due to the vibration of the pressure and the amount of the dielectric. The component of copper(Cu) and zinc(Zn), which is the main material of wire electrode, was observed for rough wire-cutting EDM of STD-11. This phenomena is found to be decreased as the number of EDM is increased. But it will be improved by changing the material and the shape of wire. The roundness of middle is found to be worse than that of upper and it is increased as the thickness of material is increased.

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Characteristics of Surface Morphology According to the Pulse Change When Wire-cut Electrical discharge Machining (와이어컷 방전가공시 펄스변화에 따른 표면형상 특성)

  • 이재명
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2000.04a
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    • pp.537-542
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    • 2000
  • Wire deflection, surface roughness and roundness were observed on changing discharge time for electrical discharge machining(EDM) of STD-11 in various conditions of thickness. The wire deflection was decreased as increasing discharge time and wire tension. The deflection is the smallest at the speed of wire of 10.6m/min and the water specific resistivity of 5k$\Omega$.cm. The deflection is found to be decreased as increasing dwell time. But if the water pressure is high, it is found not to be changed after the vibration of 4sec. The component of copper(Cu) and zinc(Zn), which is the main material of wire electrode, is observed for rough wire-cutting EDM of STD-11. This phenomena is found to be similar in spite of the change of EDM energy level. But it will be improved by changing the material and the shape of wire. The roundness of middle is found to be worse than that of upper and it is increased as the thickness of material is increased.

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Influence of Metal-Coating Layer on an Electrical Resistivity of Thick-Film-Type Thermoelectric Modules Fabricated by a Screen Printing Process (스크린 프린팅 공정에 의해 제조된 열전후막모듈의 전기저항에 미치는 금속코팅층의 영향)

  • Kim, Kyung-Tae;Koo, Hye-Young;Ha, Gook-Hyun
    • Journal of Powder Materials
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    • v.18 no.5
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    • pp.423-429
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    • 2011
  • Thermoelectric-thick films were fabricated by using a screen printing process of n and p-type bismuth-telluride-based pastes. The screen-printed thick films have approximately 30 ${\mu}m$ in thickness and show rough surfaces yielding an empty gap between an electrode and the thick film. The gap might result in an increase of an electrical resistivity of the fabricated thick-film-type thermoelectric module. In this study, we suggest a conductive metal coating onto the surfaces of the screen-printed paste in order to reduce the contact resistance in the module. As a result, the electrical resistivity of the thermoelectric module having a gold coating layer was significantly reduced up to 30% compared to that of a module without any metal coating. This result indicates that an introduction of conductive metal layers is effective to decrease the contact resistivity of a thick-film-typed thermoelectric module processed by screen printing.

Characteristics of the Tactile Brainwave on the Surface of Interior Finishing Materials - Focusing on the measurement of 'α-wave against β wave' - (실내마감재 표면에 감각하는 촉각적 뇌파특성 - '베타파에 대한 알파파' 측정 중심으로 -)

  • Yeo, Mi;Lee, Chang No
    • Korean Institute of Interior Design Journal
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    • v.25 no.2
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    • pp.59-69
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    • 2016
  • This study aimed to understand the importance of applying finishing materials into interior space, and to add meaning to the creation of functional space, associated interior finishing materials with brain science. To achieve this purpose, brainwave(EEG) experiment was conducted. The brainwave appearing when sensing the surface of interior finishing materials with hands was measured. The locations of the electrode were FP1, FP2, F3, F4, C3, C4, P3, P4, O1, O2, F7, F8, T3, T4, T5, T6, CZ, FZ, and PZ and in addition to these, AFZ was added. Eight(8) kinds of finishing materials: metallic material, film paper, lumbar, stone, glass, silk wallpaper, fabric, and paint were used to measure '${\alpha}$-wave against ${\beta}$ wave.' As a result, it was found that the most activated finishing material in term of relaxation was film paper, followed by metallic, glass, paint, fabric, stone, lumbar, and silk wallpaper. To explain in light of this, (1) '${\alpha}$-wave against ${\beta}$ wave' was the most activated at ch1-FP1 and ch2-FP2, and at ch17-AFZ and ch19-FZ, which indicated that metopic-prefrontal lobe showed the highest activation in relaxation. Film paper, among the finishing materials, showed the highest increase in relaxation. (2) In general, '${\alpha}$-wave against ${\beta}$ wave' relaxation was inhibited at ch13-T3 and ch14-T4, and at ch15-T5 and ch16-T6 and the arousal in the temporal lobe was prominent. Silk wallpaper, among the finishing materials, showed the highest arounsal effect. As a result of measuring the superficial touch on the silk wallpaper, which was regarded as the most rough material among the eight finishing materials, the arousal effect of ${\alpha}$-wave against ${\beta}$-wave, among the brainwave characteristics, was found to be the highest. (3) to judge from the scope of this experiment regarding the tactile sensation over the finishing materials, it is considered that the brainwave reaction sometimes appeared contrastive depending on whether the surface was smooth or rough and there also appeared a difference in relaxation and arousal reaction of the brainwave depending on whether the surface was hot or cold, but the sensation on the surface texture was often evaluated differently depending on who you were. For this reason, this study has some limitations.

Effects of PZT-Electrode Interface Layers on Capacitor Properties (PZT 박막 캐퍼시터의 특성에 기여하는 PZT-전극계면층의 영향)

  • Kim, Tae-Ho;Gu, Jun-Mo;Min, Hyeong-Seop;Lee, In-Seop;Lee, In-Seop
    • Korean Journal of Materials Research
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    • v.10 no.10
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    • pp.684-690
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    • 2000
  • In order to study effects of interfacial layers between $Pb(Zr,Til)Q_3(PZT)$ films and electrodes for Metal-Ferroelectric-MetaI(MFM) structure capacitors, we have fabricated the capacitors with the Pt/PZT/interfacial-layer/Pt/$TiO_2/SiO_2$/Si structure. $PbTiO_3(PT)$ interfacial layers were formed by sol-gel deposition and PbO, ZrO, and $TiO_2$ thin layers were deposited by reactive sputtering. $TiO_2$ interface layers result in the finest grains of PZT(crystalline Temp. $600^{\circ}C$) films compare to $PbO_2\;and\;ZrO_2$ layers. However, as the thickness of $TiO_2$ layer increases. PZT thin films become rough and electrical characteristics were deteriorated due to remained anatase phase. On the other hand. PT interface layers result in improved morphology of PZT films and do not significantly change ferroelectric properties. It is a also observed that seed layers at the middle and top of PZT films do not give significant effects on grain size but the PT seed layer at the interface between the bottom electrode and the PZT films results in the small grain size.

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The Technical Solution for Various Array Methods in Resistivity Survey (전기비저항 탐사의 다양한 배열 방법에 대한 해석 기법)

  • Park, Chung-Hwa
    • The Journal of Engineering Geology
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    • v.17 no.1 s.50
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    • pp.49-55
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    • 2007
  • Various away methods are required in the electrical resistivity survey in order to find anomalous zone reliably. Array methods are classified as several groups. Among these group, a curved survey along the fixed elevation is designed to increase the mobility of men and survey equipments at the rough terrain. Another method is performed at the survey using inclined, curved, and horizontal boreholes. A survey can also be conducted in an arbitrary location by measurements of potentials for a multi sources. The complex data acquired using various away methods are represented by a correct images reconstructed from the 3D inversion. The element division is applied to the region in which the boreholes are curved and inclined because of a spatial discrepancies between the coordinate of each electrode and the nodal point in a model. The resistivity images are obtained from a good agreement for the anomalous zones in open slope and in survey using an inclined borehole.