• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 1999.07a
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• pp.307-312
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• 1999

현재 우리나라에서 매년 생산되는 농산부산물은 볏짚, 왕겨 등이 주를 이루는데 에너지원으로서 적당한 것은 왕겨이다 하지만 왕겨는 단순히 농업의 부산물로 여겨질 정도로 농민들의 소득증대에의 기여도가 매우 낮다. 또한 왕겨는 내외피가 규소로 치밀하게 피복되어 있으므로 부식퇴기 어려움에도 불구하고 왕겨를 축사의 깔개로 이용 후 퇴비화함에 따라 농지내 왕겨 환원속도가 부식속도 보다 빨라서 토양속에 미부식 왕겨가 누적되어 농지내 토양환경을 열악하게 하고 있으며 왕겨를 축사내 깔개로 이용함에 따라 어린 가축의 생육장애 등이 제기피고 있으며 장래에는 악취로 인한 대기오염 문제와 가축의 질병 문제 등이 추가로 제기될 가능성이 많다. (중략)

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.3
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• pp.50-57
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• 2014

In this study, we investigated the physical properties of kraft pulps made from rice husk, peanut husk and garlic stems. These agricultural byproducts were collected individually, and then various pulps were manufactured from them by controlling active alkali, sulfidity, reaction time and the liquor ratio in the kraft pulping process in order to analyze the applicability of these agricultural byproducts as raw materials for kraft pulps. After kraft pulping, we measured yield, flake content, fiber length, fiber width and freeness of pulps, and the fiber shapes of the pulps were observed by using an optical microscope. When the higher active alkali, longer reaction time and lower liquor ratio were applied in kraft pulping process, reject content decreased and fiber yield increased. The pulp from garlic stems had the longest fiber length and that from rice husk showed the highest intial freeness. All of the pulps from agricultural byproducts showed higher initial freeness, shorter fiber length and the similar fiber width compared to OCC, BCTMP and hardwood BKP. The fibers of the pulps made from agricultural byproducts showed a similar shape to those of commercial pulps. It was concluded that these agricultural byproducts had a potential as raw materials to produce an alternative pulp to the commercial pulps.

• Bulletin of the Korean Chemical Society
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• v.31 no.2
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• pp.344-350
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• 2010

The improved photocatalytic performance of a carbon/$TiO_2$ composite was studied for the Bisphenol A (BPA) decomposition. Titanium tetraisopropoxide (TTIP) and a rice husk from Korea were heterogeneously mixed as the titanium and carbon sources, respectively, for 3 h at room temperature, and then thermally treated at $600^{\circ}C$ for 1 h in $H_2$ gas. The transmission electron microscopy (TEM) images revealed that the bulk carbon partially covered the $TiO_2$ particles, and the amount that was covered increased with the addition of the rice husk. The acquired carbon/$TiO_2$ composite exhibited an anatase structure and a novel peak at $2{\theta}=32^{\circ}$, which was assigned to bulk carbon. The specific surface area was significantly enhanced to 123~164 $m^2/g$ in the carbon/$TiO_2$ composite, compared to $32.43m^2/g$ for the pure $TiO_2$. The X-ray photoelectron spectroscopy (XPS) results showed that the Ti-O bond was weaker in the carbon/$TiO_2$ composite than in the pure $TiO_2$, resulting in an easier electron transition from the Ti valence band to the conduction band. The carbon/$TiO_2$ composite absorbed over the whole UV-visible range, whereas the absorption band in the pure$TiO_2$ was only observed in the UV range. These results agreed well with an electrostatic force microscopy (EFM) study that showed that the electrons were rapidly transferred to the surface of the carbon/$TiO_2$ composite compared to the pure $TiO_2$. The photocatalytic performance of the BPA removal was optimized at a Ti:C ratio of 9.5:0.5, and this photocatalytic composite completely decomposed 10.0 ppm BPA after 210 min, whereas the pure $TiO_2$ achieved no more than 50% decomposition under any conditions.

• Journal of the Korea institute for structural maintenance and inspection
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• v.19 no.2
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• pp.117-124
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• 2015

Currently, Eco-friendly construction materials are widely utilized for reducing $CO_2$ emission in construction. Furthermore various engineering fibers are also added for improving a brittle behavior in concrete. In the paper, concrete specimens with 10% and 20% replacement ratio with RHA (Rice Husk Ash) are prepared, and engineering behaviors in RHA and OPC concrete are evaluated with different addition of coconut fiber from 0.125~0.375% of volume ratio. Several basic tests including compressive strength, tensile strength, flexural strength, impact resistance, and bond strength are performed, and crack width and deflections are also measured in flexural test. RHA is evaluated to be very effective in strength development and 0.125% of fiber addition leads significant improvement in tensile strength, ductility, and crack resistance. RHA and coconut fiber are effective construction material both for reutilization of limited resources and performance improvement in normal concrete.

• Journal of the Korea Institute of Building Construction
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• v.22 no.6
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• pp.663-672
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• 2022

The purpose of this study is to evaluate the magnesium sulfate resistance of a geopolymer mixed with rice husk powder. General concrete, silica fume mixed concrete, and binary blended geopolymer were selected as comparison targets to confirm the magnesium sulfate resistance, and sulfate deterioration was calculated using the compressive strengths with ages. In addition, the weight change rate and the relative dynamic coefficient of the geopolymer were comparatively analyzed, and the degree of etteringite formation was confirmed using X-ray diffraction analysis. the experiment, the geopolymer mixed with 10% rice husk powder showed 10.8% higher compressive strength than concrete with silica fume when submerged for 56 days. Also, the geopolymer mixed with rice husk powder showed a small weight change rate of 0.9 to 1.45%. composition after immersion in magnesium sulfate through X-ray diffraction analysis, it was observed that a small amount of ettringite was dispersed in the geopolymer containing rice husk powder. Thus, there is a high correlation with the corrosion resistance of magnesium sulfate

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.3
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• pp.79-85
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• 2012

In this study, purified cellulose was prepared from rice husk which is one of the major agricultural residues in Korea. The various bleaching processes such as ozone bleaching, $ClO_2$ bleaching and $H_2O_2$ bleaching were applied to remove residual lignin and impurities. In order to increase the contents of ${\alpha}$-cellulose contents, the effects of acid and alkali treatments were evaluated. Although the multi stages of the bleaching processes resulted in less than 0.5 % residual lignin contents, the application of ozone leaded to the decrease in DP(degree in Polymerization) and ${\alpha}$-cellulose contents. The alkali treatment after bleaching processes resulted in pure cellulose which showed more than 98% of ${\alpha}$-cellulose contents.

• International Journal of Concrete Structures and Materials
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• v.7 no.3
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• pp.225-238
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• 2013

In this study, a two-layer feed-forward neural network was constructed and applied to determine a mapping associating mix design and testing factors of cement-nano silica (NS)-rice husk ash ternary blended concrete samples with their performance in conductance to the water absorption properties. To generate data for the neural network model (NNM), a total of 174 field cores from 58 different mixes at three ages were tested in the laboratory for each of percentage, velocity and coefficient of water absorption and mix volumetric properties. The significant factors (six items) that affect the permeability properties of ternary blended concrete were identified by experimental studies which were: (1) percentage of cement; (2) content of rice husk ash; (3) percentage of 15 nm of $SiO_2$ particles; (4) content of NS particles with average size of 80 nm; (5) effect of curing medium and (6) curing time. The mentioned significant factors were then used to define the domain of a neural network which was trained based on the Levenberg-Marquardt back propagation algorithm using Matlab software. Excellent agreement was observed between simulation and laboratory data. It is believed that the novel developed NNM with three outputs will be a useful tool in the study of the permeability properties of ternary blended concrete and its maintenance.

• Proceedings of the KAIS Fall Conference
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• 2011.05a
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• pp.327-331
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• 2011

Zinc oxide (5, 10 and 15 wt%) impregnated NaZSM-5 zeolite synthesized using rice husk ash as silica source was tested for $CO_2$ adsorption. The materials were characterized by XRD, SEM-EDS, $CO_2$-TPD and BET techniques. The heat of the reaction (${\Delta}$Hr) derived from DSC for ZnO(10%)/NaZSM-5 was found to be 495 Btu/lb and the maximum $CO_2$ adsorption capacity of ZnO(10%)/NaZSM-5 is 140 mg/g of sorbent. Extraction of silica from the agricultural waste, rice husk and its use in the zeolite synthesis is an added advantage in this study. Hence, from the study it is concluded that zinc oxide impregnated NaZSM-5 could be treated as novel material for $CO_2$ adsorption as they were found to be regenerable, selective and recyclable.

• International Journal of Concrete Structures and Materials
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• v.8 no.4
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• pp.301-307
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• 2014

Rice husk ash (RHA) is classified as a highly reactive pozzolan. It has a very high silica content similar to that of silica fume (SF). Using less-expensive and locally available RHA as a mineral admixture in concrete brings ample benefits to the costs, the technical properties of concrete as well as to the environment. An experimental study of the effect of RHA blending on workability, strength and durability of high performance fine-grained concrete (HPFGC) is presented. The results show that the addition of RHA to HPFGC improved significantly compressive strength, splitting tensile strength and chloride penetration resistance. Interestingly, the ratio of compressive strength to splitting tensile strength of HPFGC was lower than that of ordinary concrete, especially for the concrete made with 20 % RHA. Compressive strength and splitting tensile strength of HPFGC containing RHA was similar and slightly higher, respectively, than for HPFGC containing SF. Chloride penetration resistance of HPFGC containing 10-15 % RHA was comparable with that of HPFGC containing 10 % SF.

• Korean Journal of Materials Research
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• v.22 no.6
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• pp.321-327
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• 2012

The production of functional activated carbon materials starting from inexpensive natural precursors using environmentally friendly and economically effective processes has attracted much attention in the areas of material science and technology. In particular, the use of plant biomass to produce functional carbonaceous materials has attracted a great deal of attention in various aspects. In this study the preparation of activated carbon has been attempted from rice husks via a chemical activation-assisted microwave system. The rice husks were milled via attrition milling with aluminum balls, and then carbonized under purified $N_2$. The operational parameters including the activation agents, chemical impregnation weight ratio of the calcined rice husk to KOH (1:1, 1:2 and 1:4), microwave power heating within irradiation time (3-5 min), and the second activation process on the adsorption capability were investigated. Experimental results were investigated using XRD, FT-IR, and SEM. It was found that the BET surface area of activated carbons irrespective of the activation agent resulted in surface area. The activated carbons prepared by microwave heating with an activation process have higher surface area and larger average pore size than those prepared by activation without microwave heating when the ratio with KOH solution was the same. The activation time using microwave heating and the chemical impregnation ratio with KOH solution were varied to determine the optimal method for obtaining high surface area activated carbon (1505 $m^2$/g).