• Title/Summary/Keyword: Resin-ceramics

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Effects of Interface Porosity on Dielectric and Piezoelectric Properties of BaTiO3-Polymer Composites of O-3 Type Connectivity (O-3형 BaTiO3-폴리머 복합체의 계면기공율 변화에 따른 유전 및 압전특성)

  • 이형규;김호기
    • Journal of the Korean Ceramic Society
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    • v.26 no.5
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    • pp.617-624
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    • 1989
  • Piezoelectric composites of O-3 connectivity were prepared by thermosetting barium titanate-phenolic resin composite under various cruing pressure. Among three kinds of pore in O-3 type ceramic-polymer composite, such as matrix pores, particle pores, and ceramic-polymer interface pores, the effect of interface porosity on the dielectric and piezoelectric constant was investigated. In pure barium titanate ceramics, the porosity factor of dielectric and piezoelectric constants were 5.7 and 5.0, respectively. However, in BaTiO3-polymer composite, the interface porosity factor of the piezoelectric constant was greater than that of the dielectric constant, interface porosity factor b in d33 was 9.8 and in r 4.6. On the other, piezoelectric voltage constant g33 was independent of the porosity of barium titanate ceramics. But in composite system, the piezoelectric voltage constant g33 was decreased with interface porosity.

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An Archaeochemical Microstructural Study on Koryo Inlaid Celadon

  • Ham, Seung-Wook;Shim, Il-wun;Lee, Young-Eun;Kang, Ji-Yoon;Koh, Kyong-Shin
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1531-1540
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    • 2002
  • With the invention of the inlaying technique for celadon in the latter half of the 12th century, the Koryo potters reached a new height of artistic and scientific achievement in ceramics chemical technology. Inlaid celadon shards, collected in 1991 during the surface investigation of Kangjin kilns found on the southwestern shore of South Korea, were imbedded in epoxy resin and polished for cross-section examination. Backscattered electron images were taken with an electron microprobe equipped with an energy dispersive spectrometer. The spectrometer was also used to determine the composition of micro-areas. Porcelain stone, weathered rock of quartz, mica, and feldspar composition were found to be the raw material for the body and important components in the glaze and white inlay. The close similarity between glaze and black inlay in the microstructure suggests that the glaze material was modified by adding clay with high iron content, such as biotite, for use as black inlay. The deep soft translucent quality of celadon glaze is brought about by its microstructure of bubbles, remnant and devitrified minerals, and the schlieren effect.

The history of the pottery & ceramic conservation (도토기 보존처리 사례(역사) 연구)

  • Ham, Chul-Hee;Yang, Pil-Seung
    • 한국문화재보존과학회:학술대회논문집
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    • 2005.03a
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    • pp.1-11
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    • 2005
  • No one can tell when, exactly, the conservation of potteries & ceramics began, however, according to the documents, it has a long history. Among the materials discovered up to the present, organic adhesives extracted from animals and plants such as bitumen were mainly used and resin, in 19th century, as well. As for inorganic adhesives, clay, lime and plaster were used as well as rivet, as one of mechanical methods. According to the conservation case studies in Korea, lacquer and gilding powdered gold were applied as treatment methods in some ceramics, but, in general, plaster and resins were used widely.

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Polymer meets ceramic: Polymer-driven advancement of ceramic 3D printing technology (고분자와 세라믹의 만남: 고분자를 통한 세라믹 3D 프린팅 기술의 발전)

  • Cha, Chaenyung
    • Ceramist
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    • v.23 no.1
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    • pp.4-15
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    • 2020
  • The recent advances and popularity of 3D printing technology have centered around building polymerbased 'plastic' materials, due to their low cost, simple and efficient processing, and mechanical toughness. For this reason, printable polymers are actively recruited to create 'ceramic resins' that allow more facile fabrication of ceramic materials that are difficult to print directly. Herein, a brief history and the current state of ceramic 3D printing technology aided by polymer is summarized. In addition, a new ceramic 3D printing technology using polymer-derived ceramics (PDC) is also introduced.

Comparative evaluation of micro-shear bond strength to different luting procedures of ceramics to dentin

  • Lee, Yoon-Jeong;Park, Sang-Jin;Choi, Kyoung-Kyu
    • Proceedings of the KACD Conference
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    • 2003.11a
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    • pp.569-569
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    • 2003
  • I. Objectives The purpose of this study was to evaluate the effort of a modified luting procedure called "dual bonding technique" by compare micro-shear bond strength to different luting procedures of ceramics to dentin. II. Materials and Methods Eighty-four freshly extracted caries-and restoration-free human third molar were embedded in epoxy resin using acrylic ring. Flat superficial occlusal dentin surfaces were obtained, initially using a Low speed diamond saw and exposed detin surface was group with #600-grit SiC paper.(omitted)

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Review of a Laminate Veneer Technique using a Castable Apatite Ceramic Material (Castable Apatite Ceramics Laminate Veneers 술식에 대한 고찰)

  • Yang, Jae-Ho
    • The Journal of the Korean dental association
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    • v.25 no.11 s.222
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    • pp.1019-1028
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    • 1987
  • 결손된 치질과 변색된 법랑질을 수복하기 위해 많은 재료와 술식이 개발되어왔다. 즉 silicate cement, PMMA resin, BISGMA composite resin, glass ionomer cement, porcelain등이 이용되어 왔으나 이것들은 biocompatible하지 않아 이상적인 재료는 아니다. 따라서 인간의 결손된 enamel을 수복할 수 있는 새로운 생역학적인 재료가 필요하게 되었다. 필자는 최근 관심의 대상이 되고 있는 porcelain laminate veneer system(층상 도재 전장관)에 관하여 문헌을 중심으로 고찰해 보고자 한다(국내에서는 장완식 교수께서 1987년 6월10일 보철학교실 세미나에서 video tape를 통해 소개한바 있음). 여기서는 Hobo, Iwata(1985)등이 소개한 castable apatite ceramic material을 이용한 laminate veneer술식에 관해 기술하고 내화성 모형(refractory cast)을 이용한 laminate술식과 비교 기술하고자 한다.

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Prediction of Crack Propagation Path Using Boundary Element Method in IC Packages (반도체 패키지의 경계요소법에 의한 균열진전경로의 예측)

  • Chung, Nam-Yong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.3
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    • pp.15-22
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    • 2008
  • Applications of bonded dissimilar materials such as integrated circuit(IC) packages, ceramics/metal and resin/metal bonded joints, are very increasing in various industry fields. It is very important to analyze the thermal stress and stress singularity at interface edge in bonded joints of dissimilar materials. In order to investigate the IC package crack propagating from the edge of die pad and resin, the fracture parameters of bonded dissimilar materials and material properties are obtained. In this paper, the thermal stress and its singularity index for the IC package were analyzed using 2-dimensional elastic boundary element method(BEM). From these results, crack propagation direction and path by thermal stress in the IC package were numerically simulated with boundary element method.

Analyses of Stress Singularities on Bonded Interfaces in the IC Package by Using Boundary Element method (경계요소법을 이용한 반도체 패키지의 응력특이성 해석)

  • Park, Cheol-Hee;Chung, Nam-Yong
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.6
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    • pp.94-102
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    • 2007
  • Applications of bonded dissimilar materials such as large scale integration (LSI) packages, ceramics/metal and resin/metal bonded joints, are very increasing in various industry fields. It is very important to analyze the thermal stress and stress singularity at interface edge in LSI. In order to investigate stress singularities on the bonded interface edges and delamination of die pad and resin in the IC package. In this paper, stress singularity factors(${\Gamma}_i$) and stress intensity factors($K_i$) considering thermal stress in the IC package were analyzed by using the 2-dimensional elastic boundary element method(BEM).

Fabrication of Porous Reaction Bonded Silicon Carbide with Multi-Layered Pore Structures (다층 기공구조를 갖는 다공성 반응소결 탄화규소 다공체 제조)

  • Cho, Gyoung-Sun;Kim, Gyu-Mi;Park, Sang-Whan
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.534-539
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    • 2009
  • Reaction Bonded Silicon Carbide(RBSC) has been used for engineering ceramics due to low-temperature fabrication and near-net shape products with excellent structural properties such as thermal shock resistance, corrosion resistance and mechanical strength. Recently, attempts have been made to develop hot gas filter with gradient pore structure by RBSC to overcome weakness of commercial clay-bonded SiC filter such as low fracture toughness and low reliability. In this study a fabrication process of porous RBSC with multi-layer pore structure with gradient pore size was developed. The support layer of the RBSC with multi-layer pore structure was fabricated by conventional Si infiltration process. The intermediate and filter layers consisted of phenolic resin and fine SiC powder were prepared by dip-coating of the support RBSC in slurry of SiC and phenol resin. The temperature of $1550^{\circ}C$ to make Si left in RBSC support layer infiltrate into dip-coated layer to produce SiC by reacting with pyro-carbon from phenol resin.

Composite Thick Films Based on Highly-Packed Nano-Porous Ceramics by Aerosol Deposition and Resin Infiltration

  • Kim, Hong-Gi;Kim, Hyeong-Jun;Nam, Song-Min
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.111-111
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    • 2010
  • 최근 전자 소자의 집적기술은 기존의 2차원에서 System on package (SOP) 개념에 기반을 둔 3차원 집적 기술로 발전 되어가고 있다. 소자의 3차원 실장을 실현시키는 과정에서 세라믹의 여러 유용성이 언급되어져 왔지만, 취성이 매우 크다는 등의 단점이 있었다. 이러한 이유로 연성을 가지는 폴리머와 세라믹을 합성한 복합체 기판에 대하여 많은 연구가 되고 있다. 그러나 세라믹 제작을 위해서는 높은 공정온도가 요구되고 있고 이러한 높은 공정상에서의 온도는 3차원 실장에 있어서 문제점이 되고 있다. 이러한 문제점을 극복하기 위하여 상온에서 치밀한 세라믹 후막을 제작할 수 있는 공정인 Aerosol Deposition Method (ADM)방법으로 세라믹-폴리머 후막의 제조를 시도하였다. 일반적으로 ADM은 수백 나노의 출발 파우더를 사용하여 치밀한 세라믹 막을 형성하는데 사용된다. 본 연구에서는 ADM으로 100 nm미만의 나노 세라믹 파우더를 사용하여 다공성의 세라믹 후막을 제조한 후 resin을 함침시키는 방법으로 세라믹-폴리머 후막의 제조를 시도하였다. 그 결과 운송가스, aerosol 농도 등의 공정조건을 변화시켜 다공성의 $Al_2O_3$ 후막을 제조하였고, 이 다공성 후막은 반투명의 특성을 보이며 고충전율로 형성되었다. 이렇게 제조된 나노 다공성 $Al_2O_3$ 후막에 cyanate ester resin을 함침시키는 방법을 사용하여 $Al_2O_3$-cyanate ester 복합체 후막을 제조하였으며, 이의 비유전율 및 품질계수는 각각 1 MHz에서 6.7, 1000으로 우수한 유전특성을 보임이 확인되었다.

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