• 제목/요약/키워드: Resin-arrival time

검색결과 6건 처리시간 0.02초

Adsorption of Rare Earth Metal Ion on N-Phenylaza-15-Crown-5 Synthetic Resin with Styrene Hazardous Material

  • Kim, Se-Bong;Kim, Joon-Tae
    • 통합자연과학논문집
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    • 제7권2호
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    • pp.130-137
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    • 2014
  • Resins were synthesized by mixing N-phenylaza-15-crown-5 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslink of 1%, 2%, 6%, and 12% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermo gravimetric analysis (TGA), surface area, and IR-spectroscopy. The effects of pH, equilibrium arrival time, dielectric constant of solvent and crosslink on adsorption of metal ions by the synthetic resin adsorbent were investigated. The metal ions were showed fast adsorption on the resins above pH 4. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium (VI) > zinc (II) > europium (III) ions. The uranium ion adsorbed in the order of 1%, 2%, 6%, and 12% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

Adsorption Characteristics of Al (III), Ni (II), Sm (III) Ions on Resin with Styrene Hazardous Material in Reinforcement Water Fire Extinguishing Agent

  • Kim, Joon-Tae
    • 통합자연과학논문집
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    • 제6권3호
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    • pp.151-157
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    • 2013
  • The ion exchange resins were synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous material) divinylbenzene (DVB) copolymer with crosslinks of 1%, 6%, and 15% by substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, surface area, and IR-spectrum. The object of this study was to seperate the metal ion absorbed in reinforcement water fire extinguishing agent. As the results of the effects of pH, equilibrium arrival time, and crosslink of synthetic resin on metal ion adsorption for resin adsorbent, the metal ions were showed high adsorption at pH 3 or over and adsorption equilibrium of metal ions was about 2 hours. In addition, adsorption selectivity for the resin in water was the order of Al (III) > Ni (II) > Sm (III) ions, adsorbability of the metal ions was in the crosslinks order of 1%, 6%, and 15%.

Adsorption of Uranium (VI) Ion on 1-Aza-12-Crown-4 Synthetic Resin with Styrene Hazardous Material

  • Kim, Joon-Tae
    • 통합자연과학논문집
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    • 제6권2호
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    • pp.104-110
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    • 2013
  • 1-Aza-12-crown-4 macrocyclic ligand was combined with styrene (2th petroleum in 4th class hazardous materials) divinylbenzene copolymer having 1%, 2%, 3%, and 6% crosslinks by a substitution reaction, in order to synthesize resin. These synthetic resins were confirmed by chlorine content, elementary analysis and IR-spectrum. As the results of the effects of pH, equilibrium arrival time, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over and adsorption equilibrium of uranium ion was about 2 hours. In addition, adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > iron ($Fe^{3+}$) > lutetium ($Lu^{3+}$) ions, adsorbability of the uranium ion was in the crosslinks order of 1%, 2%, 3%, and 6% was increased with the lower dielectric constant.

복수 캐비리 충전 균형 조절을 위한 자동 런너 밸브 조절기 개발 (Development of Automatic Runner-Valve Actuator for The Filling Balance of Multi Cavity)

  • 이영주;이은진;박형필;차백순;이병옥
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2009년도 춘계학술대회 논문집
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    • pp.370-373
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    • 2009
  • The runner-valve is an effective solution for the filling balance of the multi cavity molds. Automation of the runner-valve system is necessary for more efficient and accurate control of the filing balance. We designed an automatic runner-valve actuator for the automation and characterized the actuator by experiment. We obtained a linear relationship between motor-driving time and the height of the runner-valve. However, the motor-driving times for upward and downward directions were different due to the frictional characteristics of the actuators. Also we obtained the motor-driving times for backlashes of the 4 actuators. The results were used to formulate the relationship between the resin-arrival time and the flow rate change of the runner-valve with the theoretical equation that was derived in the previous research.

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통전한 우드세라믹의 전기적 성질 (Electrical Properties of Woodceramics with Sending an Electric Current)

  • 오승원
    • Journal of the Korean Wood Science and Technology
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    • 제35권4호
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    • pp.9-13
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    • 2007
  • 소나무로 제조된 톱밥보드를 수지함치율을 달리하여 함침한 후 $650^{\circ}C$로 탄화하여 우드세라믹을 제조하고 통전하여 이들의 전기적 성질 및 표면온도를 측정하였다. 고정저항이 작을수록 낮은 전압으로 통전하여도 우드세라믹의 표면온도가 높음을 알 수 있었으며, 저항이 클수록 표면온도를 $70^{\circ}C$ 이상 올리기 위해서는 전압을 높게해야 할 것으로 판단된다. 또한 전압을 높게 했을 때 우드세라믹에 흐르는 전류, 전력 및 표면온도는 높게 나타났으며, 동일 전압 하에서는 목표온도가 높을수록 도달시간, 전류 및 전력을 증가하였다.