Browse > Article
http://dx.doi.org/10.13160/ricns.2013.6.2.104

Adsorption of Uranium (VI) Ion on 1-Aza-12-Crown-4 Synthetic Resin with Styrene Hazardous Material  

Kim, Joon-Tae (Department of Chemistry, Chosun University)
Publication Information
Journal of Integrative Natural Science / v.6, no.2, 2013 , pp. 104-110 More about this Journal
Abstract
1-Aza-12-crown-4 macrocyclic ligand was combined with styrene (2th petroleum in 4th class hazardous materials) divinylbenzene copolymer having 1%, 2%, 3%, and 6% crosslinks by a substitution reaction, in order to synthesize resin. These synthetic resins were confirmed by chlorine content, elementary analysis and IR-spectrum. As the results of the effects of pH, equilibrium arrival time, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over and adsorption equilibrium of uranium ion was about 2 hours. In addition, adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > iron ($Fe^{3+}$) > lutetium ($Lu^{3+}$) ions, adsorbability of the uranium ion was in the crosslinks order of 1%, 2%, 3%, and 6% was increased with the lower dielectric constant.
Keywords
1-Aza-12-crown-4; Macrocyclic Ligand; Styrene; Crosslink; Divinylbenzene;
Citations & Related Records
Times Cited By KSCI : 4  (Citation Analysis)
연도 인용수 순위
1 Y. G. Ha, "Decomposition of monazite sand", J. Korean Chem. Soc., Vol. 23, No. 3, pp. 136-140, 1979.
2 K. W. Chi, Y. S. Ahn, K. T. Shim, H. Huh, and J. S. Ahn, "Synthesis of diazacrown ethers containing phenolic side arms and their complex with divalent metal ions", Bull. Korean Chem. Soc., Vol. 23, No. 5, pp. 688-692, 2002.   과학기술학회마을   DOI   ScienceOn
3 H. K. Frensdorff, "Salt complexes of cyclic polyethers. Distribution equilibria", J. Am. Chem. Soc., Vol. 93, No. 19, pp. 4684-4688, 1971.   DOI
4 P. G. Grimslery, L. F. Lindoy, H. C. Lip, R. J. Smith, and J. T. Baker, "Synthesis of new 14-, 15- and 16- membered crown compounds containing oxygen and nitrogen heteroatoms", Aust. J. Chem., Vol. 30, pp. 2095-2098, 1977.   DOI
5 J. D. Kim, "Extraction characteristics of heavy metals for soil washing of mine tailings-contaminated soil according to particle size distribution", J. Korean Chem. Soc., Vol. 19, No. 1, pp. 98-104, 2008.   과학기술학회마을
6 G. Bombieri and G. Depaoli, "Crown ether complexes of actinide elements (an x-ray study of the conformational change of the crown ether within the $UO_{2}(NO_{3})_{2}(H_{2}O)_{2}$ (18-crown-6) molecule)", J. Inorg. Nucl. Chem., Vol. 40, pp. 799-802, 1978.   DOI   ScienceOn
7 T. Hayashita, J. H. Lee, S. Chen, and R. A. Bartsch, "Selective column concentration of alkali-metal cations with a crown ether carboxylic acid resin", Anal. Chem., Vol. 63, pp. 1844-1847, 1991.   DOI
8 E. Blasius and P. G. Maurer, "Darstellung von austauschern mit kryptanden als ankergruppen", Makromol. Chem., Vol. 178, pp. 649-657, 1977.   DOI
9 J. T. Kim, "Adsorption of uranium(VI) ion on synthetic resin adsorbent with styrene hazardous materials", J. Korean Ind. Eng. Chem., Vol. 20, No. 2, pp. 165-171, 2009.   과학기술학회마을
10 H. Egawa, T. Nonaka, and M. Ikari, "Preparation of macroreticular chelating resins containing dihydroxyphosphino and/or phosphono groups and their adsorption ability for uranium", J. Appl. Poly. Sci., Vol. 29, pp. 2045-2055, 1984.   DOI   ScienceOn
11 M. Y. Suh, T. Y. Eom, and I. S. Suh, "Chromatographic behavior of cryptand[2,2] modified resin on metal cations", Bull. Korean Chem. Soc., Vol. 8, No. 5, pp. 366-372, 1987.   과학기술학회마을
12 J. A. Dean (Ed), "Lange's handbook of che- mistry", 13th, McGraw-Hill Book Company, New York etc, pp. 9-30-9-65, 1985.
13 K. Joe, E. H. Lee, K. W. Kim, and K. Song, "Adsorption of an uranyl ion onto a divinylbenzene amidoxime resin in sodium carbonate solutions", Anal. Sci. Tech., Vol. 21, No. 4, pp. 326-331, 2008.
14 K. C. Kang, S. S. Kim, M. H. Baik, S. H. Kwon, and S. W. Rhee, "Sorption of aqueous uranium(VI) ion onto a cation-exchangeable K-birnessite colloid", Anal. Sci. Tech., Vol. 23, No. 6, pp. 566-571, 2010.   DOI   ScienceOn
15 J. T. Kim, "Adsorption characteristics of uranium (VI) ion on OenNdien resins with styrene hazardous material", Appl. Chem. Eng., Vol. 22, No. 6, pp. 697-702, 2011.
16 C. J. Pedersen, "Crystalline salt complexes of macrocyclic polyethers", J. Am. Chem. Soc., Vol. 92, No. 2, pp. 386-391, 1970.   DOI