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Adsorption Characteristics of Al (III), Ni (II), Sm (III) Ions on Resin with Styrene Hazardous Material in Reinforcement Water Fire Extinguishing Agent

  • Kim, Joon-Tae (Department of Herb Material Industry, Dongshin University)
  • Received : 2013.07.19
  • Accepted : 2013.09.23
  • Published : 2013.09.30

Abstract

The ion exchange resins were synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous material) divinylbenzene (DVB) copolymer with crosslinks of 1%, 6%, and 15% by substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, surface area, and IR-spectrum. The object of this study was to seperate the metal ion absorbed in reinforcement water fire extinguishing agent. As the results of the effects of pH, equilibrium arrival time, and crosslink of synthetic resin on metal ion adsorption for resin adsorbent, the metal ions were showed high adsorption at pH 3 or over and adsorption equilibrium of metal ions was about 2 hours. In addition, adsorption selectivity for the resin in water was the order of Al (III) > Ni (II) > Sm (III) ions, adsorbability of the metal ions was in the crosslinks order of 1%, 6%, and 15%.

Keywords

References

  1. K. W. Chi, Y. S. Ahn, K. T. Shim, H. Huh, and J. S. Ahn, "Synthesis of diazacrown ethers containing phenolic side arms and their complex with divalent metal ions", Bull. Korean Chem. Soc., Vol. 23, No. 5, pp. 688-692, 2002. https://doi.org/10.5012/bkcs.2002.23.5.688
  2. H. K. Frensdorff, "Salt complexes of cyclic polyethers. Distribution equilibria", J. Am. Chem. Soc., Vol. 93, No. 19, pp. 4684-4688, 1971. https://doi.org/10.1021/ja00748a006
  3. P. G. Grimslery, L. F. Lindoy, H. C. Lip, R. J. Smith, and J. T. Baker, "Synthesis of new 14-, 15- and 16- membered crown compounds containing oxygen and nitrogen heteroatoms", Aust. J. Chem., Vol. 30, pp. 2095-2098, 1977. https://doi.org/10.1071/CH9772095
  4. J. D. Kim, "Extraction characteristics of heavy metals for soil washing of mine tailings-contaminated soil according to particle size distribution", J. Korean Chem. Soc., Vol. 19, No. 1, pp. 98-104, 2008.
  5. G. Bombieri and G. Depaoli, "Crown ether complexes of actinide elements (an x-ray study of the conformational change of the crown ether within the $UO_2(NO_3)_2(H_2O)_2$ (18-crown-6) molecule)", J. Inorg. Nucl. Chem., Vol. 40, pp. 799-802, 1978. https://doi.org/10.1016/0022-1902(78)80154-7
  6. S. S. Kim, M. Park, N. H. Hur, and J. Choi, "Development of heavy metal adsorbent utilizing natural zeolite", J. Environ. Agric., Vol. 10, No. 1, pp. 11-19, 1991.
  7. T. Hayashita, J. H. Lee, S. Chen, and R. A. Bartsch, "Selective column concentration of alkali-metal cations with a crown ether carboxylic acid resin", Anal. Chem., Vol. 63, pp. 1844-1847, 1991. https://doi.org/10.1021/ac00017a032
  8. E. Blasius, and P. G. Maurer, "Darstellung von austauschern mit kryptanden als ankergruppen", Makromol. Chem., Vol. 178, pp. 649-657, 1977. https://doi.org/10.1002/macp.1977.021780302
  9. C. Y. Lee and J. T. Kim, "Adsorption of metal ions on synthetic resin with styrene hazardous materials in water fire extinguishing agent", Appl. Chem. Eng., Vol. 21, No. 2, pp. 142-147, 2010.
  10. H. Egawa, T. Nonaka, and M. Ikari, "Preparation of macroreticular chelating resins containing dihydroxyphosphino and/or phosphono groups and their adsorption ability for uranium", J. Appl. Poly. Sci., Vol. 29, pp. 2045-2055, 1984. https://doi.org/10.1002/app.1984.070290613
  11. M. Y. Suh, T. Y. Eom, and I. S. Suh, "Chromatographic behavior of cryptand[2,2] modified resin on metal cations", Bull. Korean Chem. Soc., Vol. 8, No. 5, pp. 366-372, 1987.
  12. S. H. Kim, "Adsorption characteristics of heavy metal ions on 1-aza-18-crown-6-styrene-DVB synthetic resin", Dongshin University, Ph. D. Dissertation, Naju, Korea, 2008.
  13. K. C. Kang, S. S. Kim, M. H. Baik, S. H. Kwon, and S. W. Rhee, "Sorption of aqueous uranium(VI) ion onto a cation-exchangeable K-birnessite colloid", Anal. Sci. & Tech., Vol. 23, No. 6, pp. 566-571, 2010. https://doi.org/10.5806/AST.2010.23.6.566
  14. J. T. Kim, "Adsorption characteristics of metal ions on the macrocyclic synthetic resin adsorbent with styrene hazardous material", J. Korean Soc. Environ. Anal., Vol. 15, No. 1, pp. 35-41, 2012.
  15. C. Y. Lee and J. T. Kim, "Adsorption of metal ions on synthetic resin with styrene hazardous materials in water fire extinguishing agent", Appl. Chem. Eng., Vol. 21, No. 2, pp. 142-147, 2010.
  16. J. T. Kim, Adsorption of uranium() ion on 1-aza-12-crown-4 synthetic resin with styrene hazardous material, J. Chosun Natural Sci., Vol. 6, No. 2, pp. 104-110, 2013. https://doi.org/10.13160/ricns.2013.6.2.104
  17. S. M. Howdle, K. Jerabek, V. Leocorbo, P. C. Marr, and D. C. Sherrington, "Reversibly collapsible macroporous poly (styrene-divinylbenzene) resins", Polymer, Vol. 41, No. 19, pp. 7272-7277, 2000.
  18. J. A. Dean (Ed), "Lange's handbook of chemistry", 13th, McGraw-Hill Book Company, New York, pp. 9-30-9-65, 1985.
  19. C. J. Pedersen, "Crystalline salt complexes of macrocyclic polyethers", J. Am. Chem. Soc., Vol. 92, No. 2, pp. 386-391, 1970. https://doi.org/10.1021/ja00705a605

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