• Title/Summary/Keyword: Resin-arrival time

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Adsorption of Rare Earth Metal Ion on N-Phenylaza-15-Crown-5 Synthetic Resin with Styrene Hazardous Material

  • Kim, Se-Bong;Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.7 no.2
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    • pp.130-137
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    • 2014
  • Resins were synthesized by mixing N-phenylaza-15-crown-5 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous materials) divinylbenzene (DVB) copolymer with crosslink of 1%, 2%, 6%, and 12% by substitution reaction. The synthesis of these resins was confirmed by content of chlorine, element analysis, thermo gravimetric analysis (TGA), surface area, and IR-spectroscopy. The effects of pH, equilibrium arrival time, dielectric constant of solvent and crosslink on adsorption of metal ions by the synthetic resin adsorbent were investigated. The metal ions were showed fast adsorption on the resins above pH 4. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order uranium (VI) > zinc (II) > europium (III) ions. The uranium ion adsorbed in the order of 1%, 2%, 6%, and 12% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

Adsorption Characteristics of Al (III), Ni (II), Sm (III) Ions on Resin with Styrene Hazardous Material in Reinforcement Water Fire Extinguishing Agent

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.6 no.3
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    • pp.151-157
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    • 2013
  • The ion exchange resins were synthesized from 1-aza-18-crown-6 macrocyclic ligand attached to styrene (2th petroleum in 4th class hazardous material) divinylbenzene (DVB) copolymer with crosslinks of 1%, 6%, and 15% by substitution reaction. These synthetic resins were confirmed by chlorine content, elementary analysis, surface area, and IR-spectrum. The object of this study was to seperate the metal ion absorbed in reinforcement water fire extinguishing agent. As the results of the effects of pH, equilibrium arrival time, and crosslink of synthetic resin on metal ion adsorption for resin adsorbent, the metal ions were showed high adsorption at pH 3 or over and adsorption equilibrium of metal ions was about 2 hours. In addition, adsorption selectivity for the resin in water was the order of Al (III) > Ni (II) > Sm (III) ions, adsorbability of the metal ions was in the crosslinks order of 1%, 6%, and 15%.

Adsorption of Uranium (VI) Ion on 1-Aza-12-Crown-4 Synthetic Resin with Styrene Hazardous Material

  • Kim, Joon-Tae
    • Journal of Integrative Natural Science
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    • v.6 no.2
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    • pp.104-110
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    • 2013
  • 1-Aza-12-crown-4 macrocyclic ligand was combined with styrene (2th petroleum in 4th class hazardous materials) divinylbenzene copolymer having 1%, 2%, 3%, and 6% crosslinks by a substitution reaction, in order to synthesize resin. These synthetic resins were confirmed by chlorine content, elementary analysis and IR-spectrum. As the results of the effects of pH, equilibrium arrival time, crosslink of synthetic resin, and dielectric constant of a solvent on uranium ion adsorption for resin adsorbent, the uranium ion showed high adsorption at pH 3 or over and adsorption equilibrium of uranium ion was about 2 hours. In addition, adsorption selectivity for the resin in methanol solvent was the order of uranium ($UO_2{^{2+}}$) > iron ($Fe^{3+}$) > lutetium ($Lu^{3+}$) ions, adsorbability of the uranium ion was in the crosslinks order of 1%, 2%, 3%, and 6% was increased with the lower dielectric constant.

Development of Automatic Runner-Valve Actuator for The Filling Balance of Multi Cavity (복수 캐비리 충전 균형 조절을 위한 자동 런너 밸브 조절기 개발)

  • Lee, Y.J.;Lee, E.J.;Park, H.P.;Cha, B.S.;Rhee, B.O.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.370-373
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    • 2009
  • The runner-valve is an effective solution for the filling balance of the multi cavity molds. Automation of the runner-valve system is necessary for more efficient and accurate control of the filing balance. We designed an automatic runner-valve actuator for the automation and characterized the actuator by experiment. We obtained a linear relationship between motor-driving time and the height of the runner-valve. However, the motor-driving times for upward and downward directions were different due to the frictional characteristics of the actuators. Also we obtained the motor-driving times for backlashes of the 4 actuators. The results were used to formulate the relationship between the resin-arrival time and the flow rate change of the runner-valve with the theoretical equation that was derived in the previous research.

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Electrical Properties of Woodceramics with Sending an Electric Current (통전한 우드세라믹의 전기적 성질)

  • Oh, Seung Won
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.4
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    • pp.9-13
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    • 2007
  • Using sawdust boards made of pine by differing the percentage of resin impregnation, wood-ceramics were manufactured by carbonizing temperature at $650^{\circ}C$. Their electrical properties and surface temperature were measured by sending an electric current. As electrical resistance of woodceramic was lower, its surface temperature, even in a low voltage, became higher. It seemed to be necessary to applying higher voltage to the woodceramic to raise the surface temperature by target temperature $70^{\circ}C$ or more in this study, according as resistance increased. When the voltage increased, woodceramics showed higher level all in electric current, electric power and surface temperature. Arrival time, electric current and electric power increased with increase of target temperature under constant voltage.