• 한국물환경학회지
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• 제22권1호
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• pp.59-65
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• 2006

The effluent limitations for individual industry based on the best available technology economically achievable (BAT) have been required to achieve effective regulation. BAT assessment criteria that are suitable for the circumstances of Korean industry were developed in the previous study. The criteria were applied to determine the BAT for petrochemical basic compound manufacturing (PBCM) and plastics and synthetic resins manufacturing (PSRM) industry. Wastewater discharged from the each category contains high concentration of COD and toluene. Eighteen sites were surveyed and wastewater qualities were analyzed. Six and two different technologies were applied to the PBCM and PSRM industry for the end-of-pipe treatment process, respectively. The technology candidates were evaluated in terms of environmental impacts, economically achievability, treatment performance and economical reasonability. As the result, the technology options: typical activated-sludge process + sand filtration + activated carbon adsorption (PBCM) and wet oxidation + chemical precipitation + typical activated-sludge process + chemical precipitation (PSRM) were selected as the BAT for each industry.

• 한국군사과학기술학회지
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• 제18권3호
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• pp.293-299
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• 2015

We analyzed the damage effect on Glass Fibre Reinforced Plastics(GFRP) under air flow by irradiation of continuous wave near-IR laser. Damage process and temporal temperature distribution were demonstrated and material characteristics were observed with laser intensity, surface flow speed and angle. Surface temperature on GFRP rapidly increased with laser intensity, and the damaged pattern was different with flow characteristics. In case of no flow, penetration on GFRP by burning and flame generation after laser irradiation was appeared at once. GFRP was penetrated by the heat generated from resin ignition. In case of laser irradiation under flow, a flame generated after burning extinguished at once by flow and penetration pattern on GFRP were differently shown with flow angle. From the results, we presented the damage process and its mechanism.

• Composites Research
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• 제23권1호
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• pp.31-36
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• 2010

본 연구는 탄소섬유강화플라스틱(CFRP) 복합재료로 제작된 항공기 등 구조물의 낙뢰에 의한 손상을 방지하기 위하여 전도성 은나노입자를 탄소섬유에 코팅한 후 에폭시 수지로 함침함으로써 CFRP의 전기전도도를 향상시키는 방법에 대한 것이다. 전기전도도 측정은 4점측정법을 통해 저항값을 측정하고 이를 전기전도도 값으로 변환하였으며, 나노입자 코팅 상태와 전기전도도의 변화를 관찰하였다. 또한 SEM과 EDS를 통해 탄소섬유 표면에 코팅된 은나노입자의 존재와 전기적 네트워크가 형성된 것을 확인하였다. 결과로써 일반 CFRP의 약 3배 이상의 전기전도도를 얻을 수 있었다.

• Composites Research
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• 제33권3호
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• pp.153-160
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• 2020

질화붕소(BN)는 높은 열전도도를 가지는 2D 형상의 부도체로 복합재료의 강화 필러로 연구되고 있는 물질이다. 본 연구에서는 판상의 육방정 질화붕소(h-BN)를 탄소섬유 다발 사이에 첨가하여 BN이 함유된 탄소섬유강화 복합소재(CFRPs)를 제조하여 BN 필러가 CFRP의 여러 물성에 어떤 영향을 주는지 탐구하였다. 사용된 프리프레그의 수지 총량의 0-15 wt%의 BN 필러가 프리프레그 층 사이에 첨가되었다. BN 필러가 첨가된 복합소재의 인장강도는 최대 13.6%, 계면간 전단응력은 최대 6.7% 증가하는 것을 관찰하였다. BN 첨가량에 따른 열전도도와 전기전도도의 변화와, BN의 첨가량에 따른 시편의 단면 형상 변화 또한 관찰되어 탄소섬유-BN-에폭시 복합소재의 물성 제어 가능성을 제시하였다.

• 한국산업보건학회지
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• 제17권4호
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• pp.322-334
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• 2007

This study covers the investigation of the actual condition in the workplace to produce plastics products using synthetic resins and the investigation on the trends amount of the domestic production of thermoplastic resins. To analyze the monomers included in thermoplastic resins frequently used in the workplace, we analyzed thermal characteristics for test compounds using thermogravimetric analysis and did the qualitative analysis using Pyrolyzer GC-MSD & TDS GC-MSD. And then we classified the health hazard of monomers based on GHS classification criteria using information toxicity & carcinogenicity. The number of the workplace to produce plastics products among all domestic manufacturers of 73,884 was 4,391 (5.94%). The number of workers to produce plastics products among all workers of 2,522,750 in all domestic manufacturers was 104,971 (4.16%). The amount of production per year for thermoplastic resins is in the order of PP, HDPE, LDPE, PVC, ABS, PS and such compounds was producing over 1 Million ton per year each. The classification result based on GHS classification criteria for 22 main compounds included thermoplastic resins says 2 compounds of acrylonitrile, naphthalene are in Acute oral category 3 and benzene is in Acute dermal category 1. The classification results of health hazard of carcinogenicity based on IARC & ACGIH carcinogen classification says 2 compounds of benzene, vinyl chloride are in category 1A (known to be human carcinogens).

• Composites Research
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• 제28권4호
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• pp.168-175
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• 2015

탄소섬유 강화 복합재료는 높은 비강도 및 비강성을 가지기 때문에 자동차 산업, 선박, 우주 항공 산업과 같은 다양한 산업 분야에 적용되어 왔으며, 수요가 점차 증가하고 있다. 탄소섬유 강화 복합재료에는 기지재로 주로 에폭시(Epoxy)와 같이 점도가 낮고 젖음 특성이 우수하며 강도가 양호한 열경화성(Thermosetting) 수지가 사용된다. 열경화성 수지는 우수한 물리적 특성을 나타내지만 재사용이 어렵다. 이러한 문제를 해결하기 위하여 재사용이 가능한 탄소섬유 강화 열가소성 수지(Thermoplastic) 복합재료 개발 및 탄소섬유 재사용에 관한 많은 연구들이 진행되고 있다. 본 연구에서는 열분해 방법을 사용하여 탄소섬유/에폭시 복합재료로부터 탄소섬유와 수지를 분리하여 탄소섬유를 재활용하였다. 에폭시의 분해도(Degree of decomposition)는 열중량분석기(TGA)와 시차 주사현미경(SEM)을 통해 확인하였다. 수지로부터 분리해낸 탄소섬유는 절단(Cutting)과 그라인딩(Grinding) 방법을 거쳐 탄소섬유 복합재료 시트(Sheet)를 제조하였다. 재활용 탄소 섬유로 제조된 탄소섬유 시트는 각각 다른 냉각조건에서 결정화 엔탈피(Crystallization enthalpy)와 기계적 특성, 표면과 단면의 형태를 분석하였다.

• 폴리머
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• 제38권6호
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• pp.708-713
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• 2014

대부분의 플라스틱 제품은 사출성형을 통해 생산된다. 사출성형에서 성형수축은 피할 수 없으며 이는 제품에 휨이나 뒤틀림을 유발하여 제품의 치수정밀도를 떨어뜨리는 요인으로 작용한다. 사출성형 시 발생하는 휨이나 뒤틀림은 성형조건이나 제품의 형상에도 영향을 받지만 수지의 물성에 따라서도 다양하게 나타난다. 본 연구에서는 제품의 휨을 제어하기 위해 폴리카보네이트를 유리섬유로 보강하여 물성을 예측하였으며, 이를 이용하여 사출성형해석을 실시하였다. 사출성형해석을 통해 유리섬유로 보강된 수지에서 제품의 휨이 감소하는 것을 확인할 수 있었다. 본 연구방법의 타당성과 신뢰성을 검증하기 위하여 사출실험을 실시하여 수지의 물성에 따른 휨 값을 분석하였으며 해석과 실험에서 유사한 경향의 휨이 발생하는 것을 관찰할 수 있었다. 결론적으로 본 연구에서 수행한 바와 같이 해석 프로그램을 통해 수지의 물성을 설계하고 이를 통한 휨의 제어가 가능함을 확인할 수 있었다.

• Advanced Composite Materials
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• 제17권3호
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• pp.277-299
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• 2008

High quality and expedient processing repair methods are necessary to enhance the service life of bridge structures. Deterioration of concrete can occur as a result of structural cracks, corrosion of reinforcement, and freeze.thaw cycles. Cost effective methods with potential for field implementation are necessary to address the issue of the vulnerability of bridge structures and how to repair them. Most infrastructure related applications of fiber-reinforced plastics (FRPs) use traditional hand lay-up technology. The hand lay-up is tedious, labor-intensive and relies upon personnel skill level. An alternative to traditional hand lay-up of FRP for infrastructure applications is Vacuum Assisted Resin Transfer Molding (VARTM). VARTM uses single sided molding technology to infuse resin over fabrics wrapping large structures, such as bridge girders and columns. There is no work currently available in understanding the interface developed, when VARTM processing is adopted to wrap fibers such as carbon and/or glass over concrete structures. This paper investigates the interface formed by carbon fiber processed on to a concrete surface using the VARTM technique. Various surface treatments, including sandblasting, were performed to study the pull-off tensile test to find a potential prepared surface. A single-lap shear test was used to study the bond strength of CFRP fabric/epoxy composite adhered to concrete. Carbon fiber wraps incorporating Sikadur HEX 103C and low viscosity epoxy resin Sikadur 300 were considered in VARTM processing of concrete specimens.

• 대한조선학회논문집
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• 제55권3호
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• pp.205-214
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• 2018

This paper deals with the experimental study on the hygrothermal ageing effect to the strength of Carbon Fiber Reinforced Plastics (CFRP) materials for marine leisure boat manufactured by vacuum assisted resin infusion method. The experiments performed consist of tensile, flexural and shear tests according to American Society for Testing and Materials (ASTM) and Korean Industrial Standards (KS) test methods. Test coupons are varied from uni-directional(UD, $0^{\circ}$, $90^{\circ}$), Bi-Directional (BD), and Double-Bias (DB) carbon fiber fabrics in conjunction with epoxy resin. The results of tensile test show that tensile strength reduces significantly while not the same degree of reduction is observed for elasticity modulus with respect to the existence of hygrothermal ageing effect. This implies that the tensile strain induced from external load holds steady values but ultimate strength values change widely under hygrothermal ageing effect. In case of the flexural test, $0^{\circ}$ UD shows more strength reduction than $90^{\circ}$ UD while BD has reduced values in both flexural strength and elasticity modulus under hygrothermal ageing effect. It is learned that the bending strain induced from external load and ultimate strength values are reduced with respect to hygrothermal ageing effect. Shear test performed only on DB materials, and the results show marginal reduction in ultimate strength and moderate reduction in elasticity modulus. This means that the shear strain varies more than ultimate shear strength with respect to hygrothermal ageing effect. The experiment conducted in this paper clearly demonstrates the differences in material properties of the CFRP for the consideration of hygrothermal ageing effect. Findings obtained from this experimental study can serve as a fundamental input data for the realistic structural responses of marine leisure boat built in CFRP materials.

• Carbon letters
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• 제7권2호
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• pp.87-96
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• 2006

This paper describes the physical properties of filled Nylon6 composites resin with nano-sized carbon black particle and graphite nanofibers prepared by melt extrusion method. In improving adhesions between resin and fillers, the surface of the carbon filler materials were chemically modified by thermo-oxidative treatments and followed by treatments of silane coupling agent. Crystallization temperature and rate of crystallization increased with increases in filler concentration which would act as nuclei for crystallization. The silane treatments on the filler materials showed effect of reduction in crystallization temperature, possibly from enhancement in wetting property of the surface of the filler materials. Percolation transition phenomenon at which the volume resistivity was sharply decreased was observed above 9 wt% of carbon black and above 6 wt% of graphite nanofiber. The graphite nanofibers contributed to more effectively in an increase in electrical conductivity than carbon black did, on the other hand, the silane coupling agent negatively affected to the electrical conductivity due to the insulating property of the silane. Positive temperature coefficient (PTC) phenomenon, was observed as usual in other composites, that is, temperature increase results conductivity increase. The dispersity of the fillers were excellently approached by melt extrusion of co-rotational twin screw type and it could be illustrated by X-ray diffraction and SEM.