• Title/Summary/Keyword: Residual water content

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Synthesis of Melamine Phosphate-Polyurethane Composite Foam Blown by Water and Characterization of Its Thermal Properties (H2O로 발포된 멜라민포스페이트-폴리우레탄폼 복합체 합성과 열적 특성 분석)

  • Park, Kyeong-Kyu;Lee, Sang-Ho
    • Polymer(Korea)
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    • v.38 no.4
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    • pp.441-448
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    • 2014
  • Polyurethane/melamine phosphate composite foam (MP-PUF) was prepared from poly(adipate)diol/melamine phosphate composite (f=2), polyether-polyol (f=4.6), and PMDI (f=2.5). The thermal properties of MP-PUF such as morphology, closed-cell content, thermal conductivity, and thermal stabilities were characterized. Water was used as a blowing agent, and the composition of melamine phosphate (MP) was maintained at $1.43{\pm}0.3wt%$ of MP-PUF. As the content of water increased, the thermal conductivity of pure polyurethane foam (PUF) decreased, whereas the thermal conductivity of MP-PUF increased. The thermal stabilities of the PUF and the MP-PUF were maximized at 5 php $H_2O$, and then decreased at the higher $H_2O$ contents. The thermal stabilities of MP-PUF were greatly enhanced due to the synergetic effect of MP and urea, which was generated during the blowing process. The temperature of 50% residual mass of MP-PUF increased to $370{\sim}450^{\circ}C$ and the temperature of 30% residual mass exceeded over $700^{\circ}C$. Compared to the PUF, the temperature of 50% residual mass and 30% residual mass were higher than 25 and $70^{\circ}C$, respectively.

Entrapment of Milk Nutrients during Cholesterol Removal from Milk by Crosslinked β-Cyclodextrin

  • Ha, H.J.;Jeon, S.S.;Chang, Y.H.;Kwak, H.S.
    • Food Science of Animal Resources
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    • v.29 no.5
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    • pp.566-572
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    • 2009
  • This study was designed to elucidate the quantities of milk nutrients entrapped during cholesterol removal from milk by crosslinked $\beta$-cyclodextrin ($\beta$-CD, 0.4~1.2%, w/v) and to evaluate the amounts of the residual $\beta$-CD in cholesterol-reduced milk treated by crosslinked $\beta$-CD. The content of lactose in the control milk (without treatment by crosslinked $\beta$-CD) was 4.86%, and the amounts of lactose entrapped by crosslinked $\beta$-CD ranged from 0.00 to 0.03%. The total amounts of the entrapped short-chain free fatty acid (FFA) and free amino acid (FAA) ranged from 0.03 to 0.09 ppm and from 0.28 to $0.71{\mu}mol/mL$, respectively. The amounts of the entrapped water-soluble vitamins (L-ascorbic acid, niacin, thiamine and riboflavin) ranged from 0.02 to 0.05 ppm, 0.01 to 0.06 ppm, 0.00 to 0.06 ppm and 0.01 to 0.06 ppm, respectively. The entrapped amounts of lactose, short-chain FFAs, FAAs and water-soluble vitamins were not remarkably affected by the concentrations of crosslinked $\beta$-CD (0.4~1.2%, w/v). Only very small amounts of residual $\beta$-CD in the cholesterol-removed milk were measured (1.22~3.00 ppm). Based on the data obtained from the present study, it was concluded that the amounts of entrapped nutrients were negligible during cholesterol removal from milk by crosslinked $\beta$-CD, and only trace amounts of residual $\beta$-CD were present in cholesterol-removed milk.

Potential of gas generation and natural gas hydrate formation in the near seafloor sediment of the Ulleung Basin (울릉분지 천부 퇴적층에서의 가스 생성과 천연가스 하이드레이트 형성 잠재력)

  • Ryu, Byong-Jae;Lee, Young-Joo;Kim, Ji-Hoon;Kim, Il-Soo;Park, Myong-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.419-423
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    • 2006
  • Basic studies on natural gas hydrates in the East Sea were been carried out by the Korea Institute of Geoscience and Mineral Resources (KIGAM) from 2000 to 2004 involving 2D multichannel seismic lines and piston coring. 27 piston cores recovered from the deed-water Ulleung Basin of the East Sea were analyzed in this study. In piston cores cracks generally developed parallel to bedding suggest significant gas content. The core analyses showed high total organic carbon (TOC) content, sedimentation rate and heat flow of sediments. The cores recovered from the southern study area show also high residual hydrocarbon gas concentrations for the formation of natural gas hydrates. This study indicates that there is the potential for the generation of biogenic gas and the formation of natural gas hydrates in the near seafloor sediments of the study area.

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The Synthesis of $Fe_3O_4$ Powder through Glycothermal Process (Glycothermal Process에 의한 $Fe_3O_4$ 분말 합성)

  • 노준석;조승범;최상흘
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1159-1164
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    • 1997
  • Magnetite(Fe3O4) powders were synthesized through glycothermal reaction by using crystalline $\alpha$-FeOOH as precursor and ethyleanne glycol as solvent. The phase, morphology and particle size of synthesized powders were characterized by XRD and an SEM. When only ethylene glycol was used as solvent, the phase was transformed from $\alpha$-FeOOH to $\alpha$-Fe2O3 and finally Fe3O4 at 27$0^{\circ}C$ for 6hr without morphological change. But by addition of water, Fe3O4 powders were synthesized at 23$0^{\circ}C$ for 3hr through solution-recrystalization process. As the content of water addition increased, the particle shape changed from sphere to octahedron and the partcle size increased. When the excess amount of water added, residual $\alpha$-FeOOH or $\alpha$-Fe2O3 was recrystalized.

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Experiments on the GPR Reposnse of the Organic Hydrocarbons (유류오염물질의 GPR 반응에 대한 모델 실험 연구)

  • 김창렬
    • Economic and Environmental Geology
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    • v.37 no.2
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    • pp.185-193
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    • 2004
  • A physical model experiment was conducted using a sand and gravel-filled tank model, to investigate the influence on the GPR response of LNAPL vapor phase effects in the unsaturated zone and of residual phase of LNAPL trapped in the saturated zone. Background measurements of GPR were made with only water in the tank using a fluctuating water table model. Gasoline was, then, injected into the bottom of the model tank to simulate a subsurface discharge from a leaking pipe or tank at depth, obtaining GPR data with rising and lowering of water table. Results from the experiment show the GPR sensitivity to the changes in the moisture content in the vadose zone and its effectiveness for monitoring minor fluctuation of the water table. The results also demonstrate a potential of GPR for monitoring possible vapor phase effects of volatile hydrocarbons in the vadose zone as a function of time, and for detecting the effects of residual phase of hydrocarbons in the water saturated system. In addition, the results provide the basis for a strategy that has the potential to successfully detect and delineate residual LNAPL contamination in the water-saturated system at field sites where the conditions are similar to those simulated in the physcial models described herein.

Prediction of residual compressive strength of fly ash based concrete exposed to high temperature using GEP

  • Tran M. Tung;Duc-Hien Le;Olusola E. Babalola
    • Computers and Concrete
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    • v.31 no.2
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    • pp.111-121
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    • 2023
  • The influence of material composition such as aggregate types, addition of supplementary cementitious materials as well as exposed temperature levels have significant impacts on concrete residual mechanical strength properties when exposed to elevated temperature. This study is based on data obtained from literature for fly ash blended concrete produced with natural and recycled concrete aggregates to efficiently develop prediction models for estimating its residual compressive strength after exposure to high temperatures. To achieve this, an extensive database that contains different mix proportions of fly ash blended concrete was gathered from published articles. The specific design variables considered were percentage replacement level of Recycled Concrete Aggregate (RCA) in the mix, fly ash content (FA), Water to Binder Ratio (W/B), and exposed Temperature level. Thereafter, a simplified mathematical equation for the prediction of concrete's residual compressive strength using Gene Expression Programming (GEP) was developed. The relative importance of each variable on the model outputs was also determined through global sensitivity analysis. The GEP model performance was validated using different statistical fitness formulas including R2, MSE, RMSE, RAE, and MAE in which high R2 values above 0.9 are obtained in both the training and validation phase. The low measured errors (e.g., mean square error and mean absolute error are in the range of 0.0160 - 0.0327 and 0.0912 - 0.1281 MPa, respectively) in the developed model also indicate high efficiency and accuracy of the model in predicting the residual compressive strength of fly ash blended concrete exposed to elevated temperatures.

A Study on the Characteristics of the Soil-Geotextile Interface (흙-토목섬유 Interface 특성에 관한 연구)

  • 고홍석;고남영;홍순영
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.33 no.2
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    • pp.82-93
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    • 1991
  • The objective of this paper is to show that the soil-geotextile interaction needs to he addressed in addition to the usual tensile and modulus properties when the geotextile is being designed for a specific application. The soil-geotextile interaction can be directly assessed by standard direct shear test. The data presented here show that the shear strength paramaters describing the soil-geotextile interface can he greatly influenced by the type of the geotextile. In this investigation, we examined nine different geotextiles of varying construction and surface textures with two standard soil, under five loading conditions, and compared the shear strength and the frictional resistance with the corresponding values of soil itself The following conclusions were drawned from this study. 1. The shear stress-strain curve shows that there are the residual shear stresses at the soil-geotextile interface. Because of the hydraulic gradient between the soil and the geotextile, the excessive pore water can migrate into the geotextile and among the filaments and dissipate through the soil-geotextile interface. 2. The shear strength of the soil-geotextile interface is affected by the moisture content of the soil. At moisture content lower than the optimum water content of the Proctor compaction test, the shear strength of the soil-geotextile interface is greater. 3. The type and surface roughness of the geotextile have the greatest influence on the interface friction angle between the soil and the geotextile.

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A Study on the Effects of the Coefficient of Uniformity and Porosity on the Soil-Water Characteristic Curves of Sandy Soils (사질토의 함수특성곡선에 대한 균등계수와 공극율의 영향에 관한 연구)

  • Yoo, Kunsun
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.5
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    • pp.41-47
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    • 2013
  • Well-graded and dense soils have good engineering properties. Unsaturated soil properties such as shear strength, compressibility and permeability are closely related to the soil-water characteristic curve of the soil. Therefore it is important to study the effects of the coefficient of uniformity and the porosity on the soil-water characteristic curve of the sandy soils, which are also related to the grain size distribution and the density of the soil, respectively. In this study soil-water characteristic curves (SWCCs) for six sandy soil specimens were investigated using Tempe pressure cells. The test data were best-fitted to Fredlund and Xing equation. The obtained fitting parameters and the characteristic points of SWCCs were discussed and correlated with the porosity and the coefficient of uniformity of the specimens. The results show that the smaller the porosity of the specimen becomes, the larger the value of the residual matric suction becomes, whereas the larger the coefficient of uniformity of the specimen becomes, the larger the value of the residual matric suction becomes. Regardless of the coefficient of uniformity, the smaller the porosity of the specimen, the flatter the max. slope of SWCC.

Estimation Model for Simplification and Validation of Soil Water Characteristics Curve on Volcanic Ash Soil in Subtropical Area in Korea (난지권 화산회토양의 토색별 토양수분 특성곡선 및 단일화 추정모형)

  • Hur, Seung-Oh;Moon, Kyung-Hwan;Jung, Kang-Ho;Ha, Sang-Keun;Song, Kwan-Cheol;Lim, Han-Cheol;Kim, Geong-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.6
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    • pp.329-333
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    • 2006
  • Most of volcanic ash soils in South Korea are distributed in Jeju province which is an island placed on southern part of Korea and has steep slope mountain area. There are many soils containing high contents of organic matter (OM) derived from volcanic ash in Jejudo, also. Therefore, irrigation and drainage in volcanic ash soil different with general soil which has low OM content have to be applied with another management way, but studies searching appropriate methods for them are set on insufficient situation because the area of volcanic ash soil in South Korea is only 1.3% (130,000ha). This study was conducted for analysis of soil water content and irrigation quantity appropriate for crops cultivated in volcanic ash soil with high OM content. Although soils with different soil color have the same soil texture, soil water characteristics curve by soil color showed the difference of water retention capability by OM content. But, this characteristics classified with soil color could be unified by scaling technique with similitude analysis method which get dimensionless water content using a present water content, a residual water content and saturated water content (or water content at 10kPa). A relation of gravimetric soil water content (GSWC) and dimensionless water content by the results showed a form of power function. The dimensionless water content (DWC) express a relative saturation degree of present water content. This was also expressed by van Genuchten model which describe the relation between relative saturation degrees and matric potentials. These results on soil water characteristics curve (SWCC) of volcanic ash soil will be the basic of irrigation plan in area having high organic contents into soil.

Fermentation Quality of Italian Ryegrass (Lolium multiflorum Lam.) Silages Treated with Encapsulated-glucose, Glucose, Sorbic Acid and Pre-fermented Juices

  • Shao, Tao;Zhanga, L.;Shimojo, M.;Masuda, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.11
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    • pp.1699-1704
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    • 2007
  • This experiment was carried out to evaluate the effects of adding encapsulated-glucose, glucose, sorbic acid or prefermented juice of epiphytic lactic acid bacteria (FJLB) on the fermentation quality and residual mono- and disaccharide composition of Italian ryegrass (Lolium multiflorum Lam) silages. The additive treatments were as follows: (1) control (no addition), (2) encapsulated-glucose addition at 0.5% for glucose, (3) glucose addition at 1%, (4) sorbic acid addition at 0.1%, (5) FJLB addition at a theoretical application rate of $2.67{\times}10^5$ CFU (colony forming unit) $g^{-1}$, on a fresh weight basis of Italian ryegrass. Although control and encapsulated-glucose treatments had higher contents of butyric acid (33.45, 21.50 g $kg^{-1}$ DM) and ammonia-N/Total nitrogen (114.91, 87.01 g $kg^{-1}$) as compared with the other treated silages, the fermentation in all silages was clearly dominated by lactic acid. This was well indicated by the low pH (4.38-3.59), and high lactic acid/acetic acid (4.39-22.97) and lactic acid content (46.85-121.76 g $kg^{-1}$ DM). Encapsulated-0.5% glucose and glucose addition increased lactic acid/acetic acid, and significantly (p<0.05) decreased ammonia-N/total nitrogen, and the contents of butyric acid and total volatile fatty acids (VFAs) as compared with the control. However, there were higher butyric acid and lower residual mono-and di-saccharides on the two treatments as compared with sorbic acid and FJLB addition, and their utilization efficiency of water soluble carbohydrates (WSC) was lower than that of both sorbic acid and FJLB additions. Sorbic acid addition showed the lowest content of ethanol and ammonia-N/total nitrogen, and the highest content of residual fructose and total mono-and disaccharides as well as the higher lactic acid/acetic acid value. Sorbic acid addition decreased the loss of mono-and disaccharides, and inhibited the activity of clostridial and other undesirable bacteria, and greatly increased the utilization efficiency of fermentable substrates by epiphytic LAB. FJLB addition had the lowest pH value and the highest lactic acid content among all additive treatments, with the most intensive lactic acid fermentation occurring in FJLB treated silage. This resulted in the faster accumulation of lactic acid and faster pH reduction. Sorbic acid and FJLB addition depressed clostridia or other undesirable bacterial fermentation which decreased the WSC loss and saved the fermentable substrate for lactic acid fermentation.