• Title/Summary/Keyword: Removal mechanism

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Manganese Removal in Water Treatment Processes (상수처리에서 망간 제거)

  • Kim, Jinkeun;Jeong, Sanggi;Kim, Jeongsook;Park, Sejin
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.595-604
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    • 2005
  • To determine the characteristics of manganese removal in Korea, 31 multi-regional water treatment plants (WTPs) were examined. The concentration of manganese in raw water was higher than the standards for drinking water at 2 WTPs. Manganese should be properly removed during water treatment processes to reduce the occurrence of black water in the distribution system because $Mn^{+2}$ can cause black deposits when it is oxidized. Manganese can effectively removed by oxidation, followed by sedimentation and filtration as well as absorption by greensand. Manganese absorption by greensand was the major mechanism for the removal of manganese, and it is effectively removed using this process. Regeneration of greensand using an oxidation agent was necessary for continuous and adequate removal of manganese.

Study of ammonia-gas removal′s characteristics using wood-material (침엽수를 이용한 암모니아 가스 제거효율 연구)

  • Park Young Gyu
    • Journal of environmental and Sanitary engineering
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    • v.19 no.2
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    • pp.7-14
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    • 2004
  • This paper was investigated to clarify the possibility of ammonia-gas removal by essential oil. First of all, the chemical analysis was performed to analyze the composition of an essential oil by GC-MS. The monoterpenes in an essential oil react with ammonia by neutralization and their reaction mechanism was elucidated. Based on their chemical neutralized reaction, the removal efficiencies of ammonia gas were studied to derive the optimal conditions in the scrubber tower such as optimal temperature and pH. The experimental result shows that the removal efficiency of ammonia gas was achieved over 80 % by the misty aerosol dispersion of scrubber tower.

Evaluation of effective process for oxidation and coagulation by ferrous ion and hydrogen peroxide

  • Moon, H.J.;Kim, Y.M.;Lee, S.H.
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11b
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    • pp.319-321
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    • 2003
  • This research was carried out to evaluate the removal efficiencies of CODcr and colour for the dyeing wastewater by ferrous solution in Fenton process. The results showed that COD was mainly removed by Fenton coagulation, where the ferric ions are formed in the initial step of Fenton reaction. On the other hand colour was removed by Fenton oxidation rather than Fenton coagulation. The removal mechanism of CODcr and colour was mainly coagulation by ferrous ion, ferric ion and Fenton oxidation. The removal efficiencies were dependent on the ferric ion amount at the beginning of the reaction. However the final removal efficiency of COD and colour was in the order of Fenton oxidation, ferric ion coagulation and ferrous ion coagulation. The reason of the highest removal efficiency by Fenton oxidation can be explained by the chain reactions with ferrous solution, ferric ion and hydrogen peroxide.

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The Investigation of CF4 Decomposition in Methane Premixed Flames on Oxygen Enrichment (산소부화된 메탄 예혼합 화염에서 CF4 분해에 대한 연구)

  • Lee, Ki Yong
    • Journal of the Korean Society of Combustion
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    • v.22 no.4
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    • pp.51-56
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    • 2017
  • The decomposition of tetrafluoromethane has been investigated with the reaction mechanism proposed for freely propagating $CH_4/CF_4/O_2/N_2$ premixed flames on the oxygen enrichment. The factors affecting on the removal efficiency of tetrafluoromethane were analyzed. The increase in flame temperature due to oxygen enrichment has a great influence on the removal efficiency of tetrafluoromethane. At the same oxygen enrichment condition, the removal efficiency in the rich flame is higher than one in the lean flame. The increase of the F/H ratio leads to decrease the flame temperature and the removal efficiency of tetrafluoromethan is decreased at the flame temperature of 2600 K or lower, The elementary reactions that dominate the consumption of tetrafluoromethane are (R1) $CF_4+M=CF_3+F+M$ and (R2) $CF_4+H=CF_3+HF$. (R1) has the greatest effect on the consumption of tetrafluoromethane under the oxygen enhanced flames.

Enhanced Removal of Phenol from Aquatic Solution in a Schorl-catalyzed Fenton-like System by Acid-modified Schorl

  • Xu, Huan-Yan;Prasad, Murari;Wang, Peng
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.803-807
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    • 2010
  • Schorl modified by $H_2SO_4$ has been successfully developed to enhance schorl-catalyzed Fenton-like reaction for removal of phenol in an aqueous solution. The phenol removal percentage can be increased from 4% to 100% by the system of modified schorl and $H_2O_2$. Batch experiments indicate that the percent increases in removal of phenol by increasing the dosage of catalyst, temperature and initial concentration of $H_2O_2$. The results of XRD, FT-IR and SEM suggest that no new phases are formed after removal of phenol by modified schorl. ICP-AES results reveal that more dissolution of iron results in higher catalytic oxidant activity in the system of modified schorl and $H_2O_2$. Besides minor adsorption, mineral-catalyzed Fenton-like reaction governs the process.

Removal of PCBs in Aqueous Phase in Ultraviolet (UV), Ultrasonic (US), and UV/US Processes (자외선 및 초음파 공정에 의한 수용액 상의 PCBs 분해)

  • Lee, Dukyoung;Son, Younggyu
    • Journal of Soil and Groundwater Environment
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    • v.26 no.4
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    • pp.1-7
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    • 2021
  • The removal of PCBs (Polychlorinated biphenyls) in aqueous phase was investigated in the ultraviolet (UV) process, ultrasonics (US) process and ultraviolet/ultrasonic (UV/US) process using PCB No.7 and Aroclor 1260. For PCB No.7 relatively high removal efficiency over 90% was obtained during 20 min in the UV process and UV/US process. On the other hand, lower removal efficiency of 50 - 70% was achieved for it consisted of individual congeners of PCBs containing 3~8 of chlorine atom. It was found that the dechlorination reaction (the photolytic cleavage of C-Cl bond) was considered as a main removal mechanism in the UV process while PCBs were removed by cavitation-induced radical reaction in the US process. No significant dechlorination occurred in the US process. Consequently, it was suggested that the UV process or UV/US process was applicable for the removal of PCBs in aqueous phase in terms of the removal efficiency and operation time. In addition, the application of saturating gas such as Ar and Air could be considered to control redox condition and enhance the severity of acoustic cavitation for the removal of PCBs.

Study on the Measurement of Emission Spectrum and Reaction Mechanism of OH Radical in the Nitrogen Corona Discharge System for Removal of $NO_x$ in Flue Gas (배연가스의 $NO_x$제거용 코로나 방전장치에서 OH 발광 스펙트럼 측정 및 관련 반응 연구)

  • Park, Chul-Woung;Hahn, Jae-Won;Shin, Dong-Nam
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.27-38
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    • 1999
  • We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

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Progressive Collapse Resistance of RC Frames under a Side Column Removal Scenario: The Mechanism Explained

  • Hou, Jian;Song, Li
    • International Journal of Concrete Structures and Materials
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    • v.10 no.2
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    • pp.237-247
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    • 2016
  • Progressive collapse resistance of RC buildings can be analyzed by considering column loss scenarios. Using finite element analysis and a static test, the progressive collapse process of a RC frame under monotonic vertical displacement of a side column was investigated, simulating a column removal scenario. A single-story 1/3 scale RC frame that comprises two spans and two bays was tested and computed, and downward displacement of a side column was placed until failure. Our study offers insight into the failure modes and progressive collapse behavior of a RC frame. It has been noted that the damage of structural members (beams and slabs) occurs only in the bay where the removal side column is located. Greater catenary action and tensile membrane action are mobilized in the frame beams and slabs, respectively, at large deformations, but they mainly happen in the direction where the frame beams and slabs are laterally restrained. Based on the experimental and computational results, the mechanism of progressive collapse resistance of RC frames at different stages was discussed further. With large deformations, a simplified calculation method for catenary action and tensile membrane action is proposed.

Analysis of the Power for a Decanter-Type Centrifuge (II) - Total Power and the Power-Transmission Mechanism - (Decanter형 원심분리기의 동력 계산 (II) - 총동력과 동력전달 기구 -)

  • Suh, Yong-Kweon;Han, Geun-Jo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.7
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    • pp.938-947
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    • 2003
  • In this paper, we derived the formula for estimating the power of the electric motors needed to operate the Decanter-type centrifuge. In the derivation of the formula the sludge-removal torque is to be supplied from the formula derived in the first paper. The intricate nature of the transmission mechanism in the planetary gear trains of the sludge-removal power and torque has been clarified in this second paper. In particular we considered two-motor system, where the main motor drives the machine while the differential-speed control motor plays the role of braking in adjusting the differential speed. Sample calculation for the specific design treated in the first paper showed that the selection criterion for the main motor depends on the lower limit of the differential speed; when the lower limit is set low, it should be selected based on the steadily operating power, while it should be selected based on the starting power when the lower limit is set high. The total power required by both the main motor and the differential-speed control motor increases as the differential speed is decreased. It is suggested that the power loss in the differential-speed control motor could be minimized by attaching an electric generator to it.

Wear Patterns and Mechanisms of Cutting Tool in Cutting of Machinable Ceramics (가공성 세라믹 절삭에서 공구의 마멸 패턴과 메카니즘)

  • Jang, Sung-Min;Baek, Seung-Yub
    • Journal of the Korean Society of Safety
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    • v.25 no.5
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    • pp.1-6
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    • 2010
  • When the ceramic material is being machined, micro crack and brittle fracture dominate the process of material removal. Generally, ceramics are very difficult-to-cut materials and machined using conventional method such as grinding and polishing. However, such processes are generally cost-expensive and have low material removal rate. Machinable ceramics used in this study contain BN powder to overcome these problem and for productivity elevation. This paper focuses on machinability evaluation during end mill process with CNC machining center in this study. Experiment for this purpose is performed for tool wear patterns and mechanism.