Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Enhanced Removal of Phenol from Aquatic Solution in a Schorl-catalyzed Fenton-like System by Acid-modified Schorl

  • Xu, Huan-Yan (College of Materials Science and Engineering, Harbin University of Science and Technology) ;
  • Prasad, Murari (Environmental Chemistry Division, Advanced Materials and Processing Research Institute (C.S.I.R.)) ;
  • Wang, Peng (School of Municipal and Environmental Engineering, Harbin Institute of Technology)
  • Published : 2010.04.20
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Abstract

Schorl modified by $H_2SO_4$ has been successfully developed to enhance schorl-catalyzed Fenton-like reaction for removal of phenol in an aqueous solution. The phenol removal percentage can be increased from 4% to 100% by the system of modified schorl and $H_2O_2$. Batch experiments indicate that the percent increases in removal of phenol by increasing the dosage of catalyst, temperature and initial concentration of $H_2O_2$. The results of XRD, FT-IR and SEM suggest that no new phases are formed after removal of phenol by modified schorl. ICP-AES results reveal that more dissolution of iron results in higher catalytic oxidant activity in the system of modified schorl and $H_2O_2$. Besides minor adsorption, mineral-catalyzed Fenton-like reaction governs the process.

Keywords

References

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