• Title/Summary/Keyword: Reinforcing Filler

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Effects of Reinforcing Fillers on Far-infrared Vulcanization Characteristics of EPDM (보강제에 따른 EPDM의 원적외선 가교 특성 연구)

  • Kim, J.S.;Lee, J.H.;Jung, W.S.;Bae, J.W.;Park, H.C.;Kang, D.P.
    • Elastomers and Composites
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    • v.44 no.1
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    • pp.47-54
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    • 2009
  • EPDM(Ethylene-propylene-diene-terpolymer) compound reinforced with carbon black having four different particle size, acetylene black(thermal conductivity carbon black), and silica were manufactured by internal mix and open mill. To investigate the effect of particle size of filler and filler type on far-infrared vulcanization, intermal temperature of compound, degree of curing, infrared spectroscopy, and thermal analysis were measured. The thermal conductivity of far-infrared vulcanized EPDM compound increased with increasing particle size of carbon filler, but hot air vulcanized EPDM compound is not affected by particle size. The thermal conductivity was increased in the order of carbon black < silica < acetylene black(thermal conductivity carbon black).

Effect of Carbon-based Nanofillers on the Toughening Behavior of Epoxy Resin

  • Lee, Gi-Bbeum;Kim, Haeran;Shin, Wonjae;Jeon, Jinseok;Park, In-Seok;Nah, Changwoon
    • Elastomers and Composites
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    • v.56 no.3
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    • pp.179-186
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    • 2021
  • Carbon-based nanofillers, including nanodiamond (ND) and carbon nanotubes (CNTs), have been employed in epoxy matrixes for improving the toughness, using the tow prepreg method, of epoxy compounds for high pressure tanks. The reinforcing performance was compared with those of commercially available toughening fillers, including carboxyl-terminated butadiene acrylonitrile (CTBN) and block copolymers, such as poly(methyl methacrylate)-b-poly(butyl acrylate)-b-poly(methyl methacrylate) (BA-b-MMA). CTNB improved the mechanical performance at a relatively high filler loading of ~5 phr. Nanosized BA-b-MMA showed improved performance at a lower filler loading of ~2 phr. However, the mechanical properties deteriorated at a higher loading of ~5 phr because of the formation of larger aggregates. ND showed no significant improvement in mechanical properties because of aggregate formation. In contrast, surface-treated ND with epoxidized hydroxyl-terminated polybutadiene considerably improved the mechanical properties, notably the impact strength, because of more uniform dispersion of particles in the epoxy matrix. CNTs noticeably improved the flexural strength and impact strength at a filler loading of 0.5 phr. However, the improvements were lost with further addition of fillers because of CNT aggregation.

Microwave Application to the Vulcanization of Rubber Compound -(I) The Heating Characteristics of While Carbon by Microwave- (마이크로파를 응용한 Rubber Compound의 가황 - (I) 마이크로파에 의한 White Carbon의 가열특성 -)

  • Park, C.Y.;Kim, J.K.;Min, S.K.
    • Elastomers and Composites
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    • v.32 no.5
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    • pp.318-324
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    • 1997
  • Since the rigid and continuous networks of high-purity silica(white carbon) were relatively transparent to microwaves, high purity silica coupled with microwaves using a zirconia susceptor at room temperature and it was then heated to its melting temperature. The low-purity silica, contained small amount of impurities, yielded greater microwave absorption owing to easy motion of the interstitial alkali ions and it was then heated to its melting temperature. X-ray diffraction patterns of the low-purity silica were broader than those of the high-purity silica due to higher concentration of non-bridging bond and more deformed random network structure. In the vulcanization process of whitened or coloured rubber compound which is employing low-purity silica(white carbon) as a reinforcing filler, vulcanizate could be obtained effectively by microwave heating energy.

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Studies on the Surface Treatment of Kaolin Filler(Part 2) -Morphological Studies by SEM- (Kaolin 충전제(充塡劑) 표면처리(表面處理)에 관(關)한 연구(硏究)(제(弟) 2 보(報)) -주사전자현미경(走査電子顯微鏡)에 의(依)한 morphology-)

  • Kwon, Dong-Yong;Hong, Sung-Il;Kim, Sun-Ho;Lee, Yong-Moo;Huh, Dong-Sub
    • Elastomers and Composites
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    • v.18 no.4
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    • pp.135-139
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    • 1983
  • Scanning electron microscopy studies were conducted to examine the surface treatment effects of treating agents the proposed in the previous studies on various vulcanizates. Fracture surfaces of the vulcanizates compounded with kaolin treated with sodium polyphosphate of poly(maleic anhydride) presented favorable results as expected from the results of the previous studies. In other words, treating agents such as sodium polyphosphate and poly(maleic anhydride) show considerable reinforcing effects on the vulcanizates.

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A Study on Flexural Strength of RC Beam Strengthen with GFRP by Anchor Dimension (무기계 충진제를 이용한 GFRP보강 RC보의 앵커 간격에 따른 휨 성능에 대한 연구)

  • Jung, Si-Young;Choi, Ha-Jin;Park, Jong-Chul;Choi, Oan-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.29-30
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    • 2010
  • In this study, inorganic filler is used to improve the flexural strength of RC beam with GFRP instead of epoxy in wet condition. The flexural strength of RC beams was investigated by different condition with reinforcing frames and anchors dimension.

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The Study on Physical Properties of Rubber Compounds with Silica Doped Carbon Black (실리카가 도핑된 카본블랙을 함유한 고무조성물의 물성에 관한 연구)

  • Lee, Seag;Park, Nam-Cook
    • Elastomers and Composites
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    • v.33 no.1
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    • pp.44-51
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    • 1998
  • The purpose of this experiments were investigated on the physical properties of rubber com-pounds containing two types carbon black. Bound rubber and interaction coefficient for com-pounds with pure carbon black were higher than those for the compounds with dual phase carbon black. Slightly higher values in 300% modulus and tensile strength indicated that the ratio of rubber-filler bound to rubber-rubber bound of pure carbon black were higher than those of com-pounds with dual phase carbon black. It was founded that dynamic properties, that is rebound, heat build-up, 0 & $60^{\circ}C$ tan $\delta$, and cut and chip loss of compounds with dual phase carbon black were better than those of compounds with pure carbon black, but abrasion property of dual phase carbon black was lower than those of pure carbon black because of low reinforcing ability.

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Improvement of Abrasion Resistance and Friction of Rubber Blend Composition

  • Lee, Jong-Hwan;Lee, Jieun;Han, Tak Jin;Jeong, Hye Min
    • Elastomers and Composites
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    • v.55 no.3
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    • pp.161-166
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    • 2020
  • On the basis of the use of shoes, the outsole, which is mainly made of rubber, has various characteristics. The most important of these characteristics is abrasion resistance and friction. Generally, the abrasion resistance can be improved by adding more reinforcing filler such as silica to the rubber; however, the friction force drops. Owing to these problems, rubber having excellent abrasion resistance and rubber having excellent frictional force are blended. In this study, various characteristics, including wear resistance and friction, were evaluated by blending NBR/SBR or NBR/BR mixture with high wear resistance and CIIR with high friction. The CIIR was increased up to 60 phr, whereas the friction wear characteristics were rapidly changed in the NBR/CIIR blend ratio from 75:15 to 60:30.

Study on Manufacture and Properties of Polymer Compounds for Cable Sheath (전선피복용 고분자 컴파운드의 제조 및 물성 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.1
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    • pp.42-47
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    • 2019
  • The four different polymer compounds were manufactured to make cable sheath for ship industry. Two kinds of ethylene-vinyl acetate (EVA) were selected as main matrix polymers for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with the contents of fire retardant, silane coated aluminum hydroxide (S-ATH). Rheology, Mooney viscosity, and tensile strength increased with S-ATH contents by reinforcing effect. With increasing fire retardant amount, fire resistance increased, but cold resistance didn't show an obvious enhancement due to polar effect of vinyl acetate in EVA.

Thermal, Curing, Elastic, and Mechanical Properties of Ethylene Propylene Diene Monomer/Polybutadiene/Carbon Black Composites

  • Tae-Hee Lee;Keon-Soo Jang
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.142-151
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    • 2023
  • In this study, we investigate the thermal and mechanical properties of composites comprising ethylene propylene diene monomer (EPDM) and polybutadiene (PB) obtained using carbon black (CB) as a reinforcing and compatibilizing filler. Owing to the significance of elastomeric materials in various industrial applications, blending of EPDM and PB has emerged as a strategic method to optimize the material properties for specific applications. This study offers insights into the blend composition, its microstructure, and the resulting macroscopic behaviors, focusing on the synergetic effects of composite materials. Furthermore, this study delves into curing and rheological behaviors, crosslink densities, and mechanical, thermal, and elastic properties of the elastomeric composites. Through systematic exploration, we believe that this study will be beneficial to material scientists and engineers working on developing advanced elastomeric composites.

Mechanical Properties of Paper Sludge-Polypropylene Composites (제지 슬러지-폴리프로필렌수지 복합재의 기계적 성질)

  • Lee, Phil-Woo;Son, Jung-Il
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.3
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    • pp.51-62
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    • 1999
  • The objective of this research is to develop paper sludge reinforced thermoplastic composites which incorporate the advantages of each component materials. The effects of paper sludge content(0, 10, 20, 30, 40----), mesh size(20~40, 60~80, less than 100mesh), and coupling agent(Epolene E-43 and Epolene G-3003) on the mechanical properties of paper sludge-polypropylene composites were investigated. Composite density increased with an increase in the paper sludge content. When paper sludge is incorporated into a polypropylene matrix, the flexural properties of the composite increase significantly with an increase in the paper sludge mixing ratio. Especially, flexural modulus was improved with increasing paper sludge content. The flexural strength of composites was improved, but flexural modulus reduced somewhat with decreasing paper sludge particle size. The flexural properties of paper sludge-polypropylene composites were improved by using coupling agents to enhance the bonding between reinforcing filler and matrix. Use of the epolene E-43 and G-3003 resulted in considerable improvement in the flexural strength over control specimens. The flexural strength of the G-3003 composite system is higher than that of the E-43 system. Generally, izod notched impact strength of paper sludge-polypropylene composite decreased slightly, whereas izod unnotched impact strength decreased significantly with increasing paper sludge contents. There was no effects of paper sludge particle size on impact strength of paper sludge-polypropylene composites. And izod unnotched impact strength of epolene E-43 composite system sharply decreased but that of G-3003 composite system was no tendency with increasing additive content.

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