• 제목/요약/키워드: Reduction process

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Electrochemical Reduction Process for Pyroprocessing (파이로프로세싱을 위한 전해환원 공정기술 개발)

  • Choi, Eun-Young;Hong, Sun-Seok;Park, Wooshin;Im, Hun Suk;Oh, Seung-Chul;Won, Chan Yeon;Cha, Ju-Sun;Hur, Jin-Mok
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.279-288
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    • 2014
  • Nuclear energy is expected to meet the growing energy demand while avoiding CO2 emission. However, the problem of accumulating spent fuel from current nuclear power plants which is mainly composed of uranium oxides should be addressed. One of the most practical solutions is to reduce the spent oxide fuel and recycle it. Next-generation fuel cycles demand innovative features such as a reduction of the environmental load, improved safety, efficient recycling of resources, and feasible economics. Pyroprocessing based on molten salt electrolysis is one of the key technologies for reducing the amount of spent nuclear fuel and destroying toxic waste products, such as the long-life fission products. The oxide reduction process based on the electrochemical reduction in a LiCl-$Li_2O$ electrolyte has been developed for the volume reduction of PWR (Pressurized Water Reactor) spent fuels and for providing metal feeds for the electrorefining process. To speed up the electrochemical reduction process, the influences of the feed form for the cathode and the type of anode shroud on the reduction rate were investigated.

Evaluation of Mobile Emissions Reduction Strategies Using Travel Demand Model and Analytic Hierarchy Process (교통수요모형과 의사결정모형을 이용한 자동차 배출저감정책 평가)

  • Lee, Kyu Jin;Park, Kwan Hwee;Shim, Sang Woo;Choi, Keechoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.5
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    • pp.1123-1133
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    • 2015
  • This study proposed an evaluation method of mobile emissions reduction strategies for air quality management. The proposed method was considered Travel Demand Model (TDM) and Analytic Hierarchy Process (AHP), while an existing method was focused on quantitative factors. AHP of the evaluation indices of mobile emissions reduction strategies show that quantitative evaluation indices such as air pollutants and greenhouse gas reduction are more important than the political evaluation indices (Consistency with an upper plan, Policy applicability, Technical applicability and feasibility) and each weight of air pollutants and greenhouse gas reduction are found to be 0.373 and 0.218. The early scrapping policy of decrepit diesel vehicle is the best policy in the proposal method using TDM and AHP but this result differs from evaluated result by TDM or AHP respectively. These results are limited to the basic assumption and range of reduction scenarios but are expected to contribute to establish more reasonable and effective mobile emission reduction strategies.

Electrochemical Properties of Molydenum (V) Complexes with Multidentate Ligands Containing Nitrogen or / and Oxygen Donor Atom (질소, 산소 주게원자 리간드를 가진 몰리브덴 (V) 착물의 전기화학적인 성질)

  • Sang Oh OH;Soo Gyun ROH
    • Journal of the Korean Chemical Society
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    • v.33 no.5
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    • pp.484-495
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    • 1989
  • Reactions of $(Et_4N)_2[MoOCl_5]$ with multidentate ligands containing nitrogen or/and oxygen donor atom (EDTA, DTPA, IDA, CyDTA, OX) produce a series of binuclear molybdate (V) complexes. The prepared Mo (V) complexes has been identified by Elemental Analysis, Infrared Spectra, Proton Magnetic Resonance Spectra, and Electronic Spectra. The electrochemical reduction mechanism has been studied by Cyclic voltammetry, Controlled Potential Coulometry, and Spectrophotometry in pH 3.571-10.375 acetate, borate, phosphate/sodium hydroxide, phosphate, ammonium/ammonia buffers. The cyclic voltammogram of the Mo-EDTA, DTPA, IDA, CyDTA complexes at pH < ca. 6.00 have shown two reduction waves. The first reduction wave shows two electron process and the second reduction wave shows two electron process. The cyclic voltammogram of the Mo-EDTA, DTPA, IDA, CyDTA complexes at pH < ca. 8.00 has shown one reduction wave. This reduction wave show four electron process. The cyclic voltammogram of the Mo-OX complex at pH < ca. 7.2 has shown one reduction wave. This reduction wave show four electron process.

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Natural Indigo Dyeing of Cotton Fabric - One-step reduction/dyeing process - (면직물에의 천연 인디고 염색 - 일단계 환원/염색 공정 -)

  • Shin, Youn-Sook;Cho, A-Rang;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.22 no.2
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    • pp.101-109
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    • 2010
  • The objective of this study is to investigate the characteristics of natural indigo dyeing of cotton fabric. Reduction and dyeing were carried out by one-step process using an infrared dyeing machine at the liquor ratio of 1:100, and subsequently oxidation and washing in water were followed. Dye uptake was increased with the increase of indigo concentration. Over the full range of dyeing tests, the dyeing condition was optimized to $40^{\circ}C$ for 40min. For most of dye concentrations, the cotton fabrics showed mainly PB color. Maximum K/S value was shown at 4g/L of sodium hydrosulfite concentration and the color strength increased with the increase of dye concentration. Value(lightness) decreased with the increase of dye uptake irrespective of mercerization or reduction method, while the mercerized cotton showed two times higher dye uptake than the untreated cotton. Whereas hue of the untreated cotton showed large decrease of P character(5.6~3.5 PB) with the increase of dye uptake, that of the mercerized cotton increased P character(4.7~5.5 PB). Irrespective of mercerization, value and chroma decreased with the increased of dye uptake. In addition, the untreated showed lower chroma than the mercerized cotton. In the case of traditional reduction, hue of the untreated cotton was changed very little with the increase of dye uptake. For hydrosulfite reduction, P character decreased with the increase of dye uptake. The difference of hue value was small with the change of reduction method(hydrosulfite reduction or traditional fermentation). Color character was not influenced by the changed maximum absorption wavelength. Washing fastness showed 4~4/5 shade change rating without any staining. And dry rubbing fastness was good at low color strength. The bacterial reduction ratios of dyed cotton fabric were also increased.

Research on Innovation Technologies for Zero Carbon: Carbon Dioxide Reduction in Construction and Concrete Industries (탄소 제로화를 위한 혁신 기술 연구: 건설 및 콘크리트 산업에서의 이산화탄소 저감 방안 동향)

  • Kim, Joo-Hyun;Park, Jung-Jun;Kim, Jong-Kyu
    • Journal of the Korean Society of Industry Convergence
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    • v.25 no.4_2
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    • pp.549-563
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    • 2022
  • Continuous global warming is causing ecosystem destruction and direct damage to human life. The main cause of global warming is greenhouse gases, which account for more than 90 % of carbon dioxide. The leaders of each country signed the Paris Agreement at the United Nations Convention on Climate Change (UNFCCC) to reduce greenhouse gas emissions. Currently, the total amount of CO2 emitted from South Korea is 664.7 million tons as of 2018, ranking eighth in the world. 37 % of South Korea's total CO2 emissions come from the construction & building field, especially the cement production, which is a construction material. Carbon reduction technologies can be largely divided into four types: carbon reduction (CC), carbon reduction and storage technology (CCS), carbon reduction and utilization technology (CCU), and carbon reduction, storage and utilization technology (CCUS). Overseas, CCUS technology is mainly applied to reduce and store CO2 emitted from construction and construction field. A technology for permanently storing CO2 through mineralization by capturing CO2 and utilizing CO2 into a cement production process was developed, and this technology is applied to the entire cement industry. However, the development of CCUS technology applicable to the cement industry is still insignificant in South Korea. In this study, carbon dioxide reduction technology and methods for reducing carbon dioxide emitted during the cement manufacturing process, which is the main component of concrete mainly used in civil engineering construction, were investigated. Overseas, it has reached the commercialization stage beyond the demonstration stage as a way to reduce carbon dioxide by vomiting carbonation reactions. Accordingly, if carbon dioxide reduction plan technology generated during cement manufacturing is developed based on domestic technology differentiated from foreign technology, it is expected to contribute one more step to the carbon neutrality policy.

$CO_2$ Capture Process using Aqueous Monoethanolamine (MEA): Reduction of Solvent Regeneration Energy by Flue gas Splitting (모노에탄올아민(MEA)을 이용한 이산화탄소 포집공정: 배가스 분할 유입을 통한 흡수제 재생 에너지 절감 연구)

  • Jung, Jaeheum;Lim, Youngsub;Jeong, Yeong Su;Lee, Ung;Yang, Seeyub;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.764-768
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    • 2011
  • The process of $CO_2$ capture using aqueous Monoethanolamine(MEA) has been considered as one of the leading technologies for intermediate-term strategy to reduce the $CO_2$ emission. This MEA process, however, consumes relatively a large amount of energy in the stripper for absorbent regeneration. For this reason, various process alternatives are recently established to reduce the regeneration energy. This paper suggests a flue gas split configuration as one of MEA process alternatives and then simulates this process using commercial simulator. This flue gas splitting has an effect on reducing the temperature of the lower section of absorber as well as decreasing the absorbent flow rate. Compared to the base model, this optimized flue gas split process provides 6.4% reduction of solvent flow rate and 5.8% reduction of absorbent regeneration energy.

Effect of Radial Parameters in Cogging Process on Void Closure for Large Forged Products (단강품 기공의 압착성 향상을 위한 레이디얼 단련변수의 영향)

  • Choi, H.J.;Choi, S.;Yoon, D.J.;Jung, J.H.;Baek, D.K.;Choi, S.K.;Park, H.J.;Lim, S.J.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.05a
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    • pp.67-70
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    • 2008
  • This paper deals with the effect of radial parameters in cogging process such as reduction in height (Rh) and rotational angle ($\theta$) of a billet on a void closure for large forged products. Usually closing and consolidation of internal void defects in a ingot is a vital matter when utilized as large forged products, using a press with limited capacity and the sizes of the ingots becoming larger. Consequently, it is important to develop cogging process for improvement of internal soundness without a void defect and cost reduction by solid forging alone with limited press capacity. For experiments of cogging process, hydraulic press with a capacity of 800 ton was used together with a small manipulator which was made for rotation and overlapping of a billet. Size of a void was categorized into two types; $\emptyset$ 6.0 mm and $\emptyset$ 9.0 mm to investigate the change of closing and consolidation of void defects existed in the large ingot during the cogging process. Also open void and closed void in the ingot were tackled to show the differentiation of closing process of internal voids with respect to void sizes. In this paper systematic configuration for closing process of void defects were expressed based on this experiment results in the cogging process.

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A Study on the Decision For the Process Improvement Alternatives to Reduce the Fraction Defective (불량률(不良率) 감소(減少)를 위한 공정개선대안(工程改善對案) 결정(決定)에 관한 연구(硏究))

  • Lee, Do-Gyeong;Jo, Jin-Hyeong
    • Journal of Korean Society for Quality Management
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    • v.17 no.2
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    • pp.47-54
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    • 1989
  • This study is concerned with the reduction of fraction defective for quality improvement model in manufacturing system. For the methodology, a heuristic method for the selection of alternatives of process improvement is introduced for quality improvement and cost problem subject to cost constraints. This study suggests a model for selecting fraction defective reduction alternatives in multi-stage manufacturing system and a numerical example is presented.

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Bottleneck Scheduling for Cycletime Reduction in Semiconductor Fabrication Line (반도체 FAB공정의 사이클타임 단축을 위한 병목일정계획)

  • 이영훈;김태헌
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2001.10a
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    • pp.298-301
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    • 2001
  • In semiconductor manufacturing, wafer fabrication is the most complicated and important process, which is composed of several hundreds of process steps and several hundreds of machines involved. The productivity of the manufacturing mainly depends on how well they control balance of WIP flow to achieve maximal throughput under short manufacturing cycle time. In this paper mathematical formulation is suggested for the stepper scheduling, in which cycle time reduction and maximal production is achieved.

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Studies of process measurement technology for manufacturing advanced nano devices (첨단 나노소자 공정제어용 측정기술 연구)

  • Cho, Yong Jai
    • Vacuum Magazine
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    • v.2 no.3
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    • pp.4-10
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    • 2015
  • We developed a real-time three-polarizer spectroscopic ellipsometer based on a new data acquisition algorithm and a general data reduction (the process of extracting the ellipsometric sample parameters from the Fourier coefficients). The data acquisition algorithm measures Fourier coefficients of radiant flux waveform accurately and precisely. The general data reduction is introduced to represent the analytic functions of the standard uncertainties of the ellipsometric sample parameters, and the extracted theoretical values closely agree with the corresponding experimental data. Our approach can be used for optimization of measurement conditions, instrumentation, simulation, standardization, laboratory accreditation, and metrology.