• Title/Summary/Keyword: Reduction Technology

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Preparation of Copper Nanoparticles and Catalytic Properties for the Reduction of Aromatic Nitro Compounds

  • Duan, Zhongyu;Ma, Guoli;Zhang, Wenjun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4003-4006
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    • 2012
  • A novel copper nanoparticles were synthesized from cupric sulfate using hydrazine as reducing reagents. A series of aromatic nitro compounds were reacted with sodium borohydride in the presence of the copper nanoparticles catalysts to afford the aromatic amino compounds in high yields. Additionally, the catalysts system can be recycled and maintain a high catalytic effect in the reduction of aromatic nitro compounds.

A Method of Effective Vibration Reduction for Positioning Systems Undergoing Frequent Short-distance Movement (단거리 이동을 반복하는 위치결정장치를 위한 효율적인 진동저감 방법)

  • Hong, Seong-Wook;Bae, Gyu-Hyun
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.3
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    • pp.421-428
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    • 2013
  • The current vibration reduction methods for positioning systems lead to either complicated motion or the need for additional hardware when the positioning systems carry out frequent short-distance movements. This paper proposes a simple yet efficient vibration reduction method for positioning systems subjected to frequent short-distance movements. The essence of the proposed method is the trapezoidal or triangular velocity profiles, whose acceleration/deceleration rates are designed to be related to the natural frequency of concern. The combined use of the proposed method and the input shaping method is also proposed for the possible application to multi-mode systems. Experiments are performed to validate the proposed method. The simulation and experiments prove that the proposed method is of great use for residual vibration reduction in positioning systems subjected to frequent short-distance movement.

Effects of Ionic Strength, Background Electrolytes, Heavy Metals, and Redox-Active Species on the Reduction of Hexavalent Chromium by Ecklonia Biomass

  • PARK DONGHEE;YUN YEOUNG-SANG;JO JI HYE;PARK JONG MOON
    • Journal of Microbiology and Biotechnology
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    • v.15 no.4
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    • pp.780-786
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    • 2005
  • The biomass of the brown seaweed, Ecklonia, was used to remove Cr(VI) from wastewater. Previously, Cr(VI) was removed through its reduction to Cr(III) when brought into contact with the biomass. In this study, the effects of ionic strength, background electrolytes, and Cr(III), Ni(II), Zn(II), and Fe(III) on the Cr(VI) reduction were examined. An increased ionic strength inhibited the Cr(VI) reduction. The presence of other heavy metals, such as Cr(III), Ni(II), or Zn(II), only slightly affected the Cr(VI) reduction, while Fe(III) enhanced the reduction. Although the above various parameters could affect the reduction rate of Cr(VI) by Ecklonia biomass, these effects were relatively smaller than those of pH and temperature. In addition, the previously derived rate equation was found to be applicable over a range of ionic strengths and with different background electrolytes. In conclusion, Ecklonia, bioniass may be a good candidate as a biosorbent for the removal of Cr(VI) from wastewaters containing various other impurities, and scale-up to a practical process may be accomplished using the previously derived rate equation.

A Study on the Reduction Measures of CO2 Emission in the Commercial Sector of Korea (상업부분에 있어서 이산화탄소 저감방안에 관한 연구)

  • Lee, Dong Kun;Jung, Tae Yong;Youn, So Won
    • Journal of Environmental Impact Assessment
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    • v.8 no.4
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    • pp.59-72
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    • 1999
  • The purpose of the study is to propose the concrete and realistic alternative measures for $CO_2$ emission reduction on commercial sector. To achieve the purpose, this study adopted AIM/KOREA simulation model modified from AIM(Asia-Pacific Integrated Model) originally developed by Japan National Environmental Research Institute. The results of simulation demonstrate that the $CO_2$ emission from the commercial sector in 1995 was estimated 864 million TC(tons of carbon); however, according to the base scenario, $CO_2$ emission in 2020 is expected to be increased to 1,872 million TC, which is 2.17 times greater than that in 1995. In order to mitigate the ever-increasing $CO_2$ emission, the results of AIM/KOREA simulations under various scenarios showed that the 30-thousand-won carbon tax scenario does not successfully motivate the selection of advanced technology; however, with the 300-thousand-won carbon tax, a substantial amount of $CO_2$ emission reduction by 1.69 million TC from the BaU((Business-as-Usual)scenario is expected to be achieved by year 2020. Such substantial reduction of $CO_2$ emission under the 300-thoudsand-won carbon tax scenario is due to the introduction of advanced technology, such as use of condensing boilers, forced by heavier carbon tax. Under the scenario that presumes the maximum introduction of gas-burning industrial appliances, an 2.66 million TC of $CO_2$ reduction was expected. The results of this study suggest that the $CO_2$ emission reduction measures can be interpreted in many different views. However, if people and industries are fully aware of the economic benefit of energy saving, a certain level of $CO_2$ reduction by a successful introduction of advanced energy saving technology appears to be achieved without carbon tax or subsidies.

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Effects of Extracellular Electron Shuttles on Microbial Iron Reduction and Heavy Metals Release from Contaminated Soils

  • Hwang, Yun Ho;Shim, Moo Joon;Oh, Du Hyun;Yang, Jung-Seok;Kwon, Man Jae
    • Journal of Soil and Groundwater Environment
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    • v.19 no.2
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    • pp.16-24
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    • 2014
  • To test the potential effects of extracellular electron shuttles (EES) on the rate and extent of heavy metal release from contaminated soils during microbial iron reduction, we created anaerobic batch systems with anthraquinone-2,6-disulfonate (AQDS) as a surrogate of EES, and with contaminated soils as mixed iron (hydr)oxides and microbial sources. Two types of soils were tested: Zn-contaminated soil A and As/Pb-contaminated soil B. In soil A, the rate of iron reduction was fastest in the presence of AQDS and > 3500 mg/L of total Fe(II) was produced within 2 d. This suggests that indigenous microorganisms can utilize AQDS as EES to stimulate iron reduction. In the incubations with soil B, the rate and extent of iron reduction did not increase in the presence of AQDS likely because of the low pH (< 5.5). In addition, less than 2000 mg/L of total Fe(II) was produced in soil B within 52 d suggesting that iron reduction by subsurface microorganisms in soil B was not as effective as that in soil A. Relatively high amount of As (~500 mg/L) was released to the aqueous phase during microbial iron reduction in soil B. The release of As might be due to the reduction of As-associated iron (hydr)oxides and/or direct enzymatic reduction of As(V) to As(III) by As-reducing microorganisms. However, given that Pb in liquid phase was < 0.3 mg/L for the entire experiment, the microbial reduction As(V) to As(III) by As-reducing microorganisms has most likely occurred in this system. This study suggests that heavy metal release from contaminated soils can be strongly controlled by subsurface microorganisms, soil pH, presence of EES, and/or nature of heavy metals.

Isolation and Identification of an Anaerobic Dissimilatory Fe(III)-Reducing Bacterium, Shewanella putrefaciens IR-1

  • Hyun, Moon-Sik;Kim, Byung-Hong;Chang, In-Seop;Park, Hyung-Soo;Kim, Hyung-Joo;Kim, Gwang-Tae;Kim, Mi-a;Park, Doo-Hyun
    • Journal of Microbiology
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    • v.37 no.4
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    • pp.206-212
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    • 1999
  • In order to isolate a Fe(III)-reducer from the natural environment, soil samples were collected from various patty fields and enriched with ferric citrate as a source of Fe(III) under anaerobic condition. Since the enrichment culture was serially performed, the Fe(III)-reduction activity was serially diluted and cultivated on an agar plate containing lactate and ferric citrate in an anaerobic glove box. A Gram negative, motile, rod-shaped and facultative anaerobic Fe(III)-reducer was isolated based on its highest Fe(III)-reduction activity, Bacterial growth was coupled with oxidation of lactate to Fe(III)-reduction, but the isolate fermented pyruvate without Fe(III), The isolate reduced an insoluble ferric iron (FeOOH) as well as a soluble ferric iron (ferric citrate). Using the BBL crystal enteric/non-fermentor identification kit and 16S rDNA sequence analysis, the isolate was identified as Shewanella putrefaciens IR-1.

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Application of Energy Dissipation Technology in High-Rise Buildings

  • Hu, Da-Zhu;Zhang, Xiao-Xuan;Li, Guo-Qiang;Sun, Fei-Fei;Jin, Hua-Jian
    • International Journal of High-Rise Buildings
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    • v.10 no.2
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    • pp.137-147
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    • 2021
  • The principle of energy dissipation technology is to dissipate or absorb the seismic energy input through the deformation or velocity change of dampers installed in the main structure of high-rise buildings, so as to reduce the seismic response of the buildings. With the development of energy dissipation technology, recognized as an effective and new measurement for reducing seismic effects, its application in high-rise buildings has become more and more popular. The appropriate energy dissipation devices suitable for high-rise buildings are introduced in this paper. The effectiveness of energy-dissipation technology for reducing the seismic response of high-rise buildings with various structural forms is demonstrated with a number of actual examples of high-rise buildings equipped with various energy dissipation devices.

Evaluation of Excess Sludge Reduction in the OSA Process using Kinetic Parameter and Mass Balance (동역학계수 및 물질수지를 이용한 OSA공정의 잉여슬러지 감량능 평가)

  • Nam, Duck-Hyun;Jang, Hyung-Suk;Ha, Kuem-Ryul;Kim, Joon-Kyu;Ju, Jae-Young;Jung, In-Ho;Park, Chul-Hwi
    • Journal of Korean Society on Water Environment
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    • v.25 no.4
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    • pp.530-538
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    • 2009
  • The Oxic-Settling-Anaerobic (OSA) treatment process, a modified Conventional Activated Sludge (CAS) process, was developed for the purpose of sludge reduction. The insertion of a sludge holding tank into a sludge return line, an anaerobic reactor, forming an OSA process, may provide a cost-effective way of reducing excess sludge production during a process. The OSA process was evaluated for its sludge reduction ability by kinetic parameter and mass balance, with an observed excess sludge reduction of 63.5%, as $P_{X.VSS}$, compared with the conventional activated sludge process.

High Electrochemical Activity of Pt-Cu Alloy Support on Carbon for Oxygen Reduction Reaction (산소 환원 반응을 위한 탄소기반 Pt-Cu 합금의 높은 전기적 촉매 활성)

  • KIM, HAN SEUL;RYU, SU CHAK;LEE, YOUNG WOOK;SHIN, TAE HO
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.549-555
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    • 2019
  • Electrocatalysis of oxygen reduction reaction (ORR) using Pt nanoparticles or bimetal on carabon was studied. Currently, the best catalyst is platinum, which is a limited resource and expensive to commercialize. In this paper, we investigated the cheaper and more active electrocatalysts by making Pt nanoparticles and adding 3D transition metal such as copper. Electrocatalysts were obtained by chemical reduction based on ethylene glycol solutions. Elemental analysis and particle size were confirmed by XRD and TEM. The electrochemical surface area (ECSA) and activity of the catalyst were determined by electrochemical techniques such as cyclic voltammetry and linear sweep voltammetry method. The commercialized Pt support on carbon (Pt/C, JM), synthesis Pt/C and synthesis Pt3Cu1 alloy nanoparticles supported on carbon were compared. We confirmed that the synthesized Pt3-Cu1/C has high electrochemical performance than commercial Pt/C. It is expected to develop an electrocatalyst with high activity at low price by increasing the oxygen reduction reaction rate of the fuel cell.