Browse > Article
http://dx.doi.org/10.5012/bkcs.2012.33.12.4003

Preparation of Copper Nanoparticles and Catalytic Properties for the Reduction of Aromatic Nitro Compounds  

Duan, Zhongyu (Hebei Provincial Key Lab of Green Chemical Technology & High Efficient Energy Saving, School of Chemical Engineering & Technology, Hebei University of Technology)
Ma, Guoli (Hebei Provincial Key Lab of Green Chemical Technology & High Efficient Energy Saving, School of Chemical Engineering & Technology, Hebei University of Technology)
Zhang, Wenjun (Hebei Provincial Key Lab of Green Chemical Technology & High Efficient Energy Saving, School of Chemical Engineering & Technology, Hebei University of Technology)
Publication Information
Abstract
A novel copper nanoparticles were synthesized from cupric sulfate using hydrazine as reducing reagents. A series of aromatic nitro compounds were reacted with sodium borohydride in the presence of the copper nanoparticles catalysts to afford the aromatic amino compounds in high yields. Additionally, the catalysts system can be recycled and maintain a high catalytic effect in the reduction of aromatic nitro compounds.
Keywords
Copper; Nanoparticles; Catalysis; Nitro reduction; Aromatic amino compounds;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Joseph, T.; Kumar, K. V.; Ramaswamy, A. V.; Halligudi, S. B. Catal. Commun. 2007, 8, 629.   DOI   ScienceOn
2 Khan, F. A.; Dash, J.; Sudheer, C.; Gupta, R. K. Tetrahedron Lett. 2003, 44, 7783.   DOI   ScienceOn
3 Rai, G.; Jeong, J. M.; Lee, Y. S.; Kim, H. W.; Lee, D. S.; Chung, J. K.; Leea, M. C. Tetrahedron Lett. 2005, 46, 3987.   DOI   ScienceOn
4 Figueras, F.; Coq, B. J. Mol. Catal. A: Chem. 2001, 173, 223.   DOI   ScienceOn
5 Tan, X. Y.; Zhang, Z. X.; Xiao, Z. H.; Xu, Q.; Liang, C. H.; Wang, X. H. Catal. Lett. 2012, 142, 788.   DOI
6 Zheng, Y. F.; Ma, K.; Wang, H. L.; Sun, X.; Jiang, J.; Wang, C. F.; Li, R.; Ma, J. T. Catal. Lett. 2008, 124, 268.   DOI
7 Lagrost, C.; Preda, L.; Volanschi, E.; Hapiot, P. J. Electroanal. Chem. 2005, 585, 1.   DOI   ScienceOn
8 Magdalene, R. M.; Leelamani, E. G.; Nanje, G. N. M. J. Mol.Catal A: Chem. 2004, 223, 17.   DOI   ScienceOn
9 Cardenas-Lizana, F.; Gomez-Quero, S.; Keane, M. A. Catal. Commun. 2008, 9, 475.   DOI   ScienceOn
10 Vilella, I. M. J.; Miguel, S. R.; Scelza, O. A. Chem. Eng. J. 2005, 114, 33.   DOI   ScienceOn
11 Kuroda, K.; Ishida, T.; Haruta, M. J. Mol. Catal A: Chem. 2009, 298, 7.   DOI   ScienceOn
12 Swathi, T.; Buvaneswari, G. Materials Lett. 2008, 62, 3900.   DOI   ScienceOn
13 Kumar, P. S.; Rai, K. L. Chemical Papers 2012, 66, 772.   DOI
14 Gowda, S.; Gowda, D. C. Tetrahedron. 2002, 58, 2211.   DOI   ScienceOn
15 Ley, S. V.; Thomas, A. W. Angew. Chem. Int. Ed. 2003, 42, 5400.   DOI   ScienceOn
16 Reymond, S.; Cossy, J. Chem. Rev. 2008, 108, 5359.   DOI   ScienceOn
17 Qiu, G. M.; Wang, C. J.; Zhang, Y. J.; Huang, S.; Liu, X. L.; Zhang, B. J.; Zhou, X. L. Bull. Korean Chem. Soc. 2012, 33, 2603.   DOI   ScienceOn
18 Lu, L.; Sui, M. L.; Lu, K. Science 2000, 287, 1463.   DOI   ScienceOn
19 Safaei-Ghomi, J.; Ziarati, A.; Teymuri, R. Bull. Korean Chem. Soc. 2012, 33, 2679.   DOI   ScienceOn
20 Ranjit, S.; Duan, Z.; Zhang, P.; Liu, X. Org. Lett. 2010, 12, 4134.   DOI   ScienceOn
21 Khan, F. A.; Dash, J.; Sudheer, C.; Gupta, R. K. Tetrahedron Lett. 2003, 44, 7783.   DOI   ScienceOn
22 Chaubal, N. S.; Sawant, M. R. J. Mol. Catal A: Chem. 2007, 261, 232.   DOI   ScienceOn