• Title/Summary/Keyword: Recyclability

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Prediction of tensile strength degradation of corroded steel based on in-situ pitting evolution

  • Yun Zhao;Qi Guo;Zizhong Zhao;Xian Wu;Ying Xing
    • Steel and Composite Structures
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    • v.46 no.3
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    • pp.385-401
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    • 2023
  • Steel is becoming increasingly popular due to its high strength, excellent ductility, great assembly performance, and recyclability. In reality, steel structures serving for a long time in atmospheric, industrial, and marine environments inevitably suffer from corrosion, which significantly decreases the durability and the service life with the exposure time. For the mechanical properties of corroded steel, experimental studies are mainly conducted. The existing numerical analyses only evaluate the mechanical properties based on corroded morphology at the isolated time-in-point, ignoring that this morphology varies continuously with corrosion time. To solve this problem, the relationships between pit depth expectation, standard deviation, and corrosion time are initially constructed based on a large amount of wet-dry cyclic accelerated test data. Successively, based on that, an in-situ pitting evolution method for evaluating the residual tensile strength of corroded steel is proposed. To verify the method, 20 repeated simulations of mass loss rates and mechanical properties are adopted against the test results. Then, numerical analyses are conducted on 135 models of corrosion pits with different aspect ratios and uneven corrosion degree on two corroded surfaces. Results show that the power function with exponents of 1.483 and 1.091 can well describe the increase in pit depth expectation and standard deviation with corrosion time, respectively. The effect of the commonly used pit aspect ratios of 0.10-0.25 on yield strength and ultimate strength is negligible. Besides, pit number ratio α equating to 0.6 is the critical value for the strength degradation. When α is less than 0.6, the pit number increases with α, accelerating the degradation of strength. Otherwise, the strength degradation is weakened. In addition, a power function model is adopted to characterize the degradation of yield strength and ultimate strength with corrosion time, which is revised by initial steel plate thickness.

Physical Property of Carbon Fiber Reinforced Thermoplastic Polymer based Composites by Repeating Processing of PP Composition (PP 복합 조성물의 반복 가공에 의한 열가소성 폴리머 탄소섬유 강화 복합재료의 물리적 특성 변화 연구)

  • Jin-Woo Lee;Jae-Young Lee;Seoung-Bo Shin;Jae-Hyung Park;Hyun-Ju Park;Kyung-Hun Oh;Jin-Hyuk Huh;Yun-Hae Kim;Ji-Eun Lee
    • Composites Research
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    • v.37 no.2
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    • pp.68-75
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    • 2024
  • Polypropylene (PP), a thermoplastic resin with excellent mechanical, thermal, chemical, and water resistance properties, has been attracting attention due to its economic efficiency and recyclability. However, repeated processing of thermoplastic resins can lead to property degradation, and the point at which quality degradation occurs varies depending on the processing conditions. In this study, we evaluated the performance changes of composite materials with repeated processing by blending PP resin with various additives and conducting extrusion and injection processes repeatedly. In addition, we evaluated the mechanical properties of composite materials to evaluate the effect of MFI value change during repeated processing on fiber impregnation in composite material processing.

Exploring sustainable packaging design (지속 가능한 포장 디자인 탐구)

  • AN BOWEN
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.4
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    • pp.495-499
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    • 2024
  • This article summarizes the importance, definition, key strategies and future directions of sustainable packaging design.In modern society, sustainable packaging design is not only concerned with environmental protection and resource conservation, but also involves economic, social and cultural sustainable development.This paper explores strategies to reduce environmental burden and promote ecological balance by using environmentally friendly materials, optimizing packaging design, improving packaging recyclability and reuse. In addition, the article emphasizes the importance of design innovation, such as adopting a simplified design concept and modular system, as well as increasing the versatility of packaging.It also explores the application of life cycle assessment in packaging design to ensure that every step from design to disposal minimizes environmental impact. Finally, despite the environmental and social benefits that sustainable packaging design brings, it still faces technical, economic and regulatory challenges in practice.Future design will require interdisciplinary collaboration, integration of advanced technologies, consumer education and engagement, and enhanced policy and standard-setting to promote widespread adoption and practice of sustainable packaging.

A Synthesis of LiCoO2 using the CoSO4 Recovered from Cathode Material Scrap and its Electrochemical Properties (폐 리튬 이차전지로부터 회수된 황산코발트 제조 및 이를 이용해 합성된 산화리튬코발트 양극활물질의 전기화학적 특성)

  • Kim, Mi-So;Ha, Jong-Keun;Park, Se-Bin;Ahn, Jou-Hyeon;Choi, Im-Sic;Cho, Kwon-Koo
    • Journal of the Korean Electrochemical Society
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    • v.17 no.2
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    • pp.111-118
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    • 2014
  • The electrochemical properties using the cells assembled with the synthesized $LiCoO_2$(LCO) were evaluated in this study. The LCO was synthesized from high-purity cobalt sulfate($CoSO_4$) which is recovered from the cathode scrap in the wastes lithium ion secondary battery(LIB). The leaching process for dissolving the metallic elements from the LCO scrap was controlled by the quantities of the sulfuric acid and hydrogen peroxide. The metal precipitation to remove the impurities was controlled by the pH value using the caustic soda. And also, D2EHPA and $CYANEX^{(R)}272$ were used in the solvent extraction process in order to remove the impurities again. The high-purity $CoSO_4$ solution was recovered by the processes mentioned above. We made the 6 wt.% $CoSO_4$ solution mixed with distilled water. And the 6 wt.% $CoSO_4$ solution was mixed with oxalic acid by the stirring method and dried in oven. $LiCoO_2$ as a cathode material for LIB was formed by the calcination after the drying and synthesis with the $Li_2CO_3$ powder. We assembled the cells using the $LiCoO_2$ powders and evaluated the electrochemical properties. And then, we confirmed possibility of the recyclability about the cathode materials for LIBs.

Mesoporous Silica-Carbon Composite Membranes for Simultaneous Hydrolysis and Separation of Chiral Epoxide (카본/메조세공 실리카 복합 막을 응용한 키랄 에폭사이드의 가수분해반응과 동시 분리)

  • Choi, Seong Dae;Jeon, Sang Kwon;Park, Geun Woo;Yang, Jin Young;Kim, Geon-Joong
    • Applied Chemistry for Engineering
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    • v.25 no.5
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    • pp.503-509
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    • 2014
  • The carbon/porous silica composite membrane was fabricated in a simple manner, which could be successfully for the simultaneous separation and production of chiral epoxides and 1,2-diols, based on their differences in hydrophilic/hydrophobic natures. The chiral Co(III)-$BF_3$ salen catalyst adopted in the membrane reactor system has given the very high enantioselectivity and recyclability in hydrolysis of terminal epoxides such as ECH, 1,2-EB, and SO. The optically pure epoxide and the chiral catalyst were collected in the organic phase after hydrolysis reaction. The hydrophilic water-soluble 1,2-diol product hydrolyzed by chiral salen diffused into the aqueous phase through the SBA-16 or NaY/SBA-16 silica composite layer during the reaction. The water acted simultaneously as a reactant and a solvent in the membrane system. One optical isomer was obtained with high purity and yield, and furthermore the catalysts could be recycled without observable loss in their activity in the continuous flow-type membrane reactor.

A Design of Low Cost Differential GPS System based on Web-Service (웹서비스 기반의 저가형 위성항법보정시스템 설계)

  • Jung, Se-Hoon;Seo, Ho-Seok;Park, Dong-Gook;Sim, Chun-Bo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.8 no.3
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    • pp.487-498
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    • 2013
  • A variety of location-based services applications, such as missing children search, emergency rescue requests and so on that requiring high-precision location information are increasing. Precision of GPS that can be used in most systems, however, is still low. In this paper, we design and propose a low cost differential global positioning system(DGPS) based on Web services using object-oriented modeling technique which can offer useable location service, variety device and safe service in wireless environment. The proposed system is designed with UML based on object-oriented modeling to maximize system recyclability and system scalability. In addition, we would like to improve the precision of the GPS in accordance with mobile station location when build low cost mobile station, location differential framework and server. We implement a communication interface based on web-service which is available in the form of a variety of services and can offer stable according to mobile environments. Finally, as performance evaluation results, we can obtain precision location within 1 ~ 2m through proposed system and 88.5% probability of less than 2m.

Current Status of Plastic Recycling in Korea (국내 플라스틱 리싸이클링 현황)

  • Lee, Sang-hun
    • Resources Recycling
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    • v.28 no.6
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    • pp.3-8
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    • 2019
  • Recently, plastic waste in Korea has been recognized as a critical issue due to an increase in massive production of plastics, difficulty in disposal of waste plastics, and public recognition of toxicity in micro-plastics, etc. To resolve those problems, the regulation to reduce plastics consumption may be primarily considered but, in this case, clarification should be made on the rationales and the action plans in the regulation for individual waste plastic items. Another problem is the small capital sizes of domestic recycling companies, which leads to poor R&D capacity, low recycling yields and thus lowering values of recycling items. This adversely affects consumers' perception. The R&D toward recycling technical progress should take into account the environmental friendliness and recyclability from the early product design stages. Certainly, this should be supported in governmental policy and public action plans. In addition, by referring to advanced policies of i.e. European Union, the recycling industry should be recognized as an opportunity toward new investment & employment. If necessary, the regulation of plastic consumption through a formal evaluation process such as Life Cycle Assessment (LCA) will also be helpful. The values of recycled plastics should be improved through the identification and elimination of harmful chemical substances potentially contained in the products.

Measurement of Viscosity Behavior in In-situ Anionic Polymerization of ε-caprolactam for Thermoplastic Reactive Resin Transfer Molding (반응액상성형에서 ε-카프로락탐의 음이온 중합에 따른 점도 거동 평가)

  • Lee, Jae Hyo;Kang, Seung In;Kim, Sang Woo;Yi, Jin Woo;Seong, Dong Gi
    • Composites Research
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    • v.33 no.2
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    • pp.39-43
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    • 2020
  • Recently, fabrication process of thermoplastic polyamide-based composites with recyclability as well as impact, chemical, and abrasion resistance have been widely studied. In particular, thermoplastic reactive resin transfer molding (TRTM) in which monomer with low viscosity is injected and in-situ polymerized inside mold has received a great attention, because thermoplastic melts are hard to impregnate fiber preform due to their very high viscosity. However, it is difficult to optimize the processing conditions because of high reactivity and sensitivity to external environments of the used monomer, ε-caprolactam. In this study, viscosity as an important process parameter in TRTM was measured during in-situ anionic polymerization of ε-caprolactam and the solutions for problems caused by high polymerization rate and sensitivity to moisture and oxygen were suggested. Reliability of the improved measurement technique was verified by comparing the viscosity behavior at various environmental conditions including humidity and atmosphere, and it is expected to be helpful for optimization of TRTM process.

Economical Feasibility of the Treatment Methods of the Dredged Sediments from Contaminated Agricultural Reservoirs (농업용 저수지 준설토의 처리 공법에 따른 경제성 분석)

  • Oh, Kyoung-Hee;Cho, Young-Cheol
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.756-762
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    • 2013
  • The economical feasibility was conducted to find the adequate method to treat the dredged sediments from agricultural reservoirs in a pilot project that had been operated to improve the quality of water and benthic environments by dredging of contaminated sediments. For benefit/cost (B/C) analysis, the net expenses were considered as the costs of project, and the benefits were calculated from the saving of waste-treatment cost through reuse of dredged sediment, the saving of construction cost of settling pond, and the values of retained water by dredging. Although the economic feasibility depended on the sites of operation, the average B/C value of the pilot project was estimated as 1.32, indicating this project is economically feasible. Depending on the treatment methods, the B/C values were in the order of the methods of coagulating sedimentation, machinery dewatering, stabilization through exothermic reaction, and soil improvement and stabilization. The machinery dewatering method is estimated as the most adequate one to treat the dredged sediments because of the minimum riskiness of secondary pollution, the recyclability, and its economic feasibility.

Recent Progress in Membrane based Colorimetric Sensor for Metal Ion Detection (색 변화를 활용한 중금속 이온 검출에 특화된 멤브레인 기반 센서의 최근 연구 개발 동향)

  • Bhang, Saeyun;Patel, Rajkumar
    • Membrane Journal
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    • v.31 no.2
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    • pp.87-100
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    • 2021
  • With a striking increase in the level of contamination and subsequent degradations in the environment, detection and monitoring of contaminants in various sites has become a crucial mission in current society. In this review, we have summarized the current research areas in membrane-based colorimetric sensors for trace detection of various molecules. The researches covered in this summary utilize membranes composed of cellulose fibers as sensing platforms and metal nanoparticles or fluorophores as optical reagents. Displaying decent or excellent sensitivity, most of the developed sensors achieve a significant selectivity in the presence of interfering ions. The physical and chemical properties of cellulose membrane platforms can be customized by changing the synthesis method or type of optical reagent used, allowing a wide range of applications possible. Membrane-based sensors are also portable and have great mechanical properties, which enable on-site detection of contaminants. With such superior qualities, membrane-based sensors examined in the researches were used for versatile purposes including quantification of heavy metals in drinking water, trace detection of toxic antibiotics and heavy metals in environmental water samples. Some of the sensors exhibited additional features like antimicrobial ability and recyclability. Lastly, while most of the sensors aimed for a detection enabled by naked eyes through rapid colour change, many of them investigated further detection methods like fluorescence, UV-vis spectroscopy, and RGB colour intensity.