• 제목/요약/키워드: Reactive transport

검색결과 131건 처리시간 0.03초

CFD 모델을 이용한 체승 도시협곡의 흐름과 반응성 대기오염물질 확산 특성 연구 (A Study on the Characteristics of Flow and Reactive Pollutants' Dispersion in Step-up Street Canyons Using a CFD Model)

  • 김은령;박록진;이대근;김재진
    • 대기
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    • 제25권3호
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    • pp.473-482
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    • 2015
  • In this study, street canyons with a higher downwind building (so called, step-up street canyons) are considered for understanding characteristics of flow and reactive pollutants' dispersion as a basic step to understand the characteristics in wider urban areas. This study used a CFD_NIMR_SNU coupled to a chemistry module just including simple $NO_X-O_3$ photochemical reactions. First, flow characteristics are analyzed in step-up street canyons with four aspect ratios (0.33, 0.47, 0.6, 0.73) defined as ratios of upwind building heights to downwind building height. The CFD_NIMR_SNU reproduced very well the main features (that is, vortices in the street canyons) which appeared in the wind-tunnel experiment. Wind speed within the street canyons became weak as the aspect ratio increased, because volume of flow incoming over the upwind building decreased. For each step-up street canyon, chemistry transport model was integrated up to 3600 s with the time step of 0.5 s. The distribution patterns of $NO_X$ and $O_3$ were largely dependent on the mean flow patterns, however, $NO_X$ and $O_3$ concentrations were partly affected by photochemical reactions. $O_3$ concentration near the upwind lower region of the street canyons was much lower than background concentration, because there was much reduction in $O_3$ concentration due to NO titration there. Total amount of $NO_X$ in the street canyons increased with the aspect ratio, resulting from the decrease of mean wind intensity.

생물벽체내 유기오염물질 TCE의 생물학적 분해 모의를 위한 수치모델개발 (Developing a Numerical Model for Simulating In-Situ Biodegradation of an Organic Contaminant, TCE, in Biobarrier)

  • 왕수균;오재일;배범한
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제8권4호
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    • pp.12-20
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    • 2003
  • 본 연구에서는 원위치 생물학적 처리 과정에서 공대사 기작에 의해 분해되는 유기오염물질의 성상과 거동을 모의하기 위한 수학적 모델을 제기하였다. 토양구조 내에서 부동유역의 존재가 처리 과정에 미치는 영향을 고려하기 위하여 이중공극 개념을 적용하였으며, 유기오염물질의 거동과 생물학적 처리에 미치는 미생물의 영향을 수학적으로 표현하기 위하여 수정된 Monod식과 토양상 미생물의 미소군집모형이 적용되었다. 가상의 원위치 생물학적 처리 과정에 대한 모델의 적용을 통하여 공극내 생체축적으로 인한 투수능의 감소가 지하수 흐름에 미치는 영향이 예시되었다. 가상의 생물학적 처리 과정에 대한 모델의 모의결과는 부동유역의 존재가 유기오염물질의 생물학적 가용성을 저감시키며, 생물벽체의 형성 및 처리과정에 있어 외부로부터의 미생물 및 영양물질 주입정의 위치가 효과적인 처리 계획의 수립을 위해 중요하다는 것을 보여 주었다.

Breakthrough Curves and Miscible Displacement of Cadmium Through Double-Layered Reclaimed Soils Amended with Macroporous Granule

  • Kim, Hye-Jin;Ryu, Jin-Hee;Kim, Si-Ju;Park, Mi-Suk;Chung, Doug-Young
    • 한국토양비료학회지
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    • 제44권1호
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    • pp.15-21
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    • 2011
  • Transport of heavy metals such as Cd is affected by several rate-limiting processes including adsorption and desorption by exchange reactions in soils. In this study, column transport and batch kinetic experiments were performed to assess Cd mobility in a double-layered soil with a reclaimed saline and sodic soil (SSS) as top soil and macroporous granule (MPG) as a bottom layer. For individual soil layer having different physical and chemical properties, Cd was considered to be nonlinear reactivity with the soil matrix in layered soils. The dispersive equation for reactive solutes was solved with three types of boundary conditions for the interface between soil layers. The adsorption of Cd with respect to the saline-sodic sandy loam and the MPG indicated that the nature of the sites or the mechanisms involved in the sorption process of Cd was different and the amounts of Cd for both of samples increases with increasing amounts of equilibrium concentration whereas the amount of Cd adsorbed in saline-sodic sandy loam soil was higher than that in MPG. The results of breakthrough curve indicating relative Cd retardation accompanied by layer material and sequence during leaching showed that the number of pore volumes to reach the maximum relative concentration of 1 increased in the order of MPG, SSS, and double layer of SSS-MPG. Breakthrough curves (BTCs) from column experiments were well predicted with our double-layered model where independently derived solute physical and retention parameters were implemented.

포화(飽和)된 사질토(砂質土)내로의 오염물(汚染物) 이동에 대한 시스템 신뢰성(信賴性) 모델의 응용(應用) (Reliability Analysis to Contaminant Migration in Saturated Sandy Soils : System Reliability Approach)

  • 장연수
    • 대한토목학회논문집
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    • 제12권2호
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    • pp.229-237
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    • 1992
  • 2차원 수평흐름에서의 비반응성 오염물 이동에 대한 연속시스템(series system) 신뢰성해석을 농도와 노출시간의 두 극한상태 함수에 대해 시행하였다. 시간에 따라 변화하는 오염원에서의 오염이동모델을 시스템 신뢰해석 모델과 결합하여 오염이 예상되는 지점의 최대농도가 주어진 기간동안에 특정농도를 초과하거나 또는 오염예상 지점이 보통의 농도에 노출되어질 시간이 특정 한계를 초과할 확률을 구하였다. 본 신뢰성 해석의 결과 상기의 두조건을 초과할 확률은 각각의 조건을 초과할 확률보다 큰 것은 확인하였으며 보다 큰 초과확률을 갖는 요소에 의하여 지배되는 것을 발견하였다. 예민도 해석은 투수계수 외에도 횡단 분산계수(transverse dispersivity)도 이차원 오염이동 신뢰성 모델의 중요한 매개 변수임을 보여주었다. 시스템 예민도는 두 요소의 예민도를 동시에 반영하고 있으며 큰 초과확률을 갖는 요소가 해(解)에 보다 큰 영향을 미치는 것을 알게 되었다.

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Mitochondrial Efficiency-Dependent Viability of Saccharomyces cerevisiae Mutants Carrying Individual Electron Transport Chain Component Deletions

  • Kwon, Young-Yon;Choi, Kyung-Mi;Cho, ChangYeon;Lee, Cheol-Koo
    • Molecules and Cells
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    • 제38권12호
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    • pp.1054-1063
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    • 2015
  • Mitochondria play a crucial role in eukaryotic cells; the mitochondrial electron transport chain (ETC) generates adenosine triphosphate (ATP), which serves as an energy source for numerous critical cellular activities. However, the ETC also generates deleterious reactive oxygen species (ROS) as a natural byproduct of oxidative phosphorylation. ROS are considered the major cause of aging because they damage proteins, lipids, and DNA by oxidation. We analyzed the chronological life span, growth phenotype, mitochondrial membrane potential (MMP), and intracellular ATP and mitochondrial superoxide levels of 33 single ETC component-deleted strains during the chronological aging process. Among the ETC mutant strains, 14 ($sdh1{\Delta}$, $sdh2{\Delta}$, $sdh4{\Delta}$, $cor1{\Delta}$, $cyt1{\Delta}$, $qcr7{\Delta}$, $qcr8{\Delta}$, $rip1{\Delta}$, $cox6{\Delta}$, $cox7{\Delta}$, $cox9{\Delta}$, $atp4{\Delta}$, $atp7{\Delta}$, and $atp17{\Delta}$) showed a significantly shorter life span. The deleted genes encode important elements of the ETC components succinate dehydrogenase (complex II) and cytochrome c oxidase (complex IV), and some of the deletions lead to structural instability of the membrane-$F_1F_0$-ATP synthase due to mutations in the stator stalk (complex V). These short-lived strains generated higher superoxide levels and produced lower ATP levels without alteration of MMP. In summary, ETC mutations decreased the life span of yeast due to impaired mitochondrial efficiency.

Simulink를 이용한 단상 UPFC 모델링 및 시뮬레이션 (Simulink-based Modelling and Simulation for a Single-phase UPFC)

  • 강문호
    • 전기학회논문지
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    • 제58권3호
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    • pp.523-530
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    • 2009
  • This paper presents a study on a small scale single-phase UPFC preliminary researches on power quality compensating schemes of electrical railway. As the UPFC is very complicated power-electronic system consisting of grid-connected transformers, four single phase inverters interconnected with dc-link capacitors and various electrical apparatuses, multiple controllers and control algorithms are needed, and entire UPFC has been modelled in the form of block diagrams and simulated by using Simulink. The main purpose of the compensating system is to manage reactive and active powers with the four single phase inverters, so, the control effort has been focused on the power flow control and has been realized through the hysteresis current control of the single phase inverters. And transport-delayed PLL with additional delay-time compensating term has been used to synchronize a grid voltage and the simulation results have shown that the compensating term could improve PLL performance under some frequency variation of the voltage.

난류연소 유동장에서의 확률밀도함수 전달방정식을 이용한 난류혼합 모델링 (Modeling of Turbulent Molecular Mixing by the PDF Balance Method for Turbulent Reactive Flows)

  • 문희장
    • 한국연소학회지
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    • 제2권1호
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    • pp.39-51
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    • 1997
  • A review of probability density function(PDF) methodology and direct numerical simulation for the purpose of modeling turbulent combustion are presented in this study where particular attention is focused on the modeling problem of turbulent molecular mixing term appearing in PDF transport equation. Existing mixing models results were compared to those evaluated by direct numerical simulation in a turbulent premixed medium with finite rate chemistry in which the initial scalar field is composed of pockets of partially burnt gases to simulate autoignition. Two traditional mixing models, the least mean square estimations(LMSE) and Curl#s model are examined to see their prediction capability as well as their modeling approach. Test calculations report that the stochastically based Curl#s approach, though qualitatively demonstrates some unphysical behaviors, predicts scalar evolutions which are found to be in good agreement with statistical data of direct numerical simulation.

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DIRECT COMPUTATION OF MARGINAL OPERATING CONDITIONS FOR VOLTAGE COLLAPSE

  • Lee, Kyung-Jae;Jung, Tay-Ho
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1989년도 하계종합학술대회 논문집
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    • pp.195-201
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    • 1989
  • Voltage collapse is a serious concern to the electirc utility industry. It is common to associate steady-state stability with the ability of the transmission system to transport real power and to associate voltage collapse with the inability to provide reactive power at the necessary locations within the system. An algorithm to directly calculate the critical point of system voltage collapse was presented by the authors. The method (based on the ordinary power flow equations and explicit requirement of singularity of the Jacobian matrix) is basically one degree of freedom with proper load distribution factors. This paper suggests a modified algorithm to increase the degree of freedom, introducing the nonlinear programming technique. The objective function is a distance measure between the present operating point and the closest voltage collapse point. Knowledge of the distance and the most vulnarable bus from the voltage collapse point of view may be used as a useful index for the secure system operation.

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Simulating Bioremediation of Uranium-Contaminated Aquifers

  • 왕수균
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 추계학술발표회
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    • pp.161-166
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    • 2002
  • Bioremediation of trace metals in groundwater may require the manipulation of redox conditions via the injection of a carbon source. To simulate the numerous biogeochemical processes that will occur during the bioremediation of trace-metal-contaminated aquifers, a reactive transport model has been developed. The model consists of a set of coupled mass balance equations, accounting for advection, hydrodynamic dispersion, and a kinetic formulation of the biological or chemical transformations affecting an organic substrate, electron acceptors, corresponding reduced species, and trace metal contaminants of interest, uranium in this study. The redox conditions of the domain are characterized by estimating the pE, based on the concentrations of the dominant terminal electron acceptor and its corresponding reduced specie. This pE and the concentrations of relevant species we then used by a modified version of MINTEQA2, which calculates the speciation/sorption and precipitation/dissolution of the species of interest under equilibrium conditions. Kinetics of precipitation/dissolution processes are described as being proportional to the difference between the actual and calculated equilibrium concentration.

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Fe$^{0}$ 과 계면활성제를 이용한 PCE의 탈염소화 반응에 관한 연구 (Dechlorination of PCE Using Zero-Valent Iron and Surfactants)

  • 조현희;박재우
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2000년도 추계학술대회
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    • pp.119-123
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    • 2000
  • In-situ treatment technologies have been proposed to transform or remove pollutants from contaminated groundwater. Zero-valent iron(Fe$^{0}$ ), metallic iron, is being evaluated as a permeable reactive material to retard the transport of wide array of highly mobile contaminants in groundwater. In this research, tetrachloroethylene(PCE) dechlorination by powdered zero-valent iron in buffered aqueous solution was studied with and without the presence of surfactants. The rate of dechlorination of PCE by zero-valent iron with surfactant was much higher than without surfactant. The presence of surfactant increased the apparent rate of dechlorination because the surfactants influenced the dissolution of PCE into the aqueous phase.

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