• Journal of the Korean Applied Science and Technology
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• v.17 no.2
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• pp.113-119
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• 2000

Alkylation of phenol with tert-butanol in the liquid phase on mordenite was studied. The influence of many reaction parameters such as calcination temperature, reaction temperature, t-butanol/phenol molar ratio on catalytic properties was discussed. The main products were 2,4-di-t-butylphenol, o-t-butylphenol, p-t-butylphenol, the last of these was wanted product. In order to enhance the selectivity of p-t-butylphenol, optimum conditions were recommended at $500^{\circ}C$ calcination temperature, $140^{\circ}C$ reaction temperature, 1.0 molar ratio of reactants over mordenite. P-t-butylphenol was formed with 90% isomer selectivity at optimum conditions after 4hr reaction. On the basis of the behavior obtained in the cases mentioned, optimum conditions and catalytic properties for t-butylation of phenol were provided.

• Journal of Environmental Health Sciences
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• v.29 no.2
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• pp.56-61
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• 2003

This study was performed to examine the effects of chaff as a bulking material on temperature, pH, weight and volume reduction and salinity in aerobic composting of food wastes. Volume ratios of food wastes to chaff in reactor of Control, Ch-1. Ch-2, Ch-3 and Ch-4 were 4:0, 4:1, 4:2, 4:3 and 4:4. respectively. Reactors were operated for 24 days with 1 hour stirring by 1 rpm and 2 hours aeration per day. The lowering of the volume ratio of food wasted to chaff resulted in the reaction at higher reaction temperature and the elongation of the high temperature reaction period. The lowering of the volume ratio of food wastes to chaff resulted in the more faster pH increase. The lowering of the volume ratio of food wastes to chaff resulted in the more faster reduction in the weight and the volume of wastes. Salinities were condensed by reaction days. The final salinity of Control and the final range of salinities of chaff mixtures were 2.79%, and 2.18~2.37%. respectively.

• Proceedings of the KIEE Conference
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• 1985.07a
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• pp.191-193
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• 1985

Reaction temperature md piezoelectric properties of Pb(Mn1/3 Sb2/3)0.08 Ti0.495 Zr0.425 $O_3$ ceramics by hydrothermal synthesis method have been investigated. Sintering density and dielectric constant of sample increased with increasing of hydrothermal reaction temperature, while decreased rapidly above $240^{\circ}C$. Electromechanical coupling factor kp was almost constant at the reaction temperature $160^{\circ}-240^{\circ}C$.

• Proceedings of the KAIS Fall Conference
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• 2004.11a
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• pp.280-283
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• 2004

Effect of H2 spillover rate as function of reduction temperature on reaction kinetics was evaluated. Reaction kinetics including yield, conversion, activation energy and selectivity of 1-butene isomerization over Pt/HxMoO/SiO were measured as reaction temperature was increased. While conversion of 1-butane was decreased, yield of iso-butene was increased. Two kinds of reaction mechanism were proposed from the change of selectivity as function of temperature.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10b
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• pp.934-939
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• 1998

This study discusses the results of adiabatic temperature rise tests which were performed considering various parameters, such as cement type, water-cement ratio, unit cement weigh, admixtures and placing temperature, which influence the temperature rise(K) and reaction velocity ($\alpha$). Theadiabatic temperature rise models obtained from this study are similar to those of Japan Concrete Institute. The models to calculate temperature rise and reaction velocity could be used the analysis f concrete thermal stress.

• Journal of the Korean Ceramic Society
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• v.30 no.5
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• pp.357-364
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• 1993

Chemical reaction occurred in the interface of Mn-Zn ferrite and glass after bonding. Effects of the formation of reaction layer on the magnetic properties were investigated. The composition of glass was 23PbO-61SiO2-6ZnO-8Na2O-2K2O and the ferrite was chosen to have a high permeability. Toroid samples of ferrites bonded with glasses, were heat-treated at $700^{\circ}C$, 80$0^{\circ}C$ and 90$0^{\circ}C$ for 1h. The reaction was observed to increase with bonding temperature, resulting in the development of reaction layer. Subsequently the initial permeability was found to be decreased. The permeabilities decreased by 25% with increasing bonding temperature from $700^{\circ}C$ to 80$0^{\circ}C$. At the bonding temperature of 90$0^{\circ}C$, the permeability was decreased by 45%, compared to that of 80$0^{\circ}C$.

• Journal of the Korean Society of Combustion
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• v.15 no.4
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• pp.1-8
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• 2010

Mild combustion is considered as a promising combustion technology for energy saving and low emission of combustion product gases. In this paper, the controllability of reaction region in mild combustion is examined by using co-axial air nozzle. For this purpose, numerical approach is carried out. Propane is considered for fuel and air is considered for oxidizer and the temperature of air is assumed 900K slightly higher than auto ignition temperature of propane. But unlike main air, the atmospheric condition of co-axial air is considered. Various cases are conducted to verify the characteristics of Co-Axial air burner configuration. The use of coaxial air can affect reaction region. These modification help the mixing between fuel and oxidizer. Then, reaction region is reduced compare to normal burner configuration. The enhancement of main air momentum also affects on temperature uniformity and reaction region. The eddy dissipation concept turbulence/chemistry interaction model is used with two step of global chemical reaction model.

• 제어로봇시스템학회:학술대회논문집
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• 1993.10a
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• pp.595-600
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• 1993

The heat of reaction has been estimated from heat balance relationships around the reactor. The heat balance equations were formulated with the assumptions that the reactor temperature is uniformly distributed and the jacket temperatures are axially distributed. We have obtained the temperature distribution of jacket contents by FDM. And then, we have rearranged the heat balance equations so that the heat of reaction can be estimated from the finite number of temperature measurements, i.e., temperatures of the reactor contents, at the jacket inlet and outlet, respectively. The proposed method for reaction heat estimation on were applied to industrial batch reactors ; one is ABS polymerization reactor and the other is SAN polymerization reactor. We have also examined the variation of overall heat transfer coefficients for the reactors during reaction.

• 한국전산유체공학회:학술대회논문집
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• 2003.08a
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• pp.219-224
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• 2003

An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. As for the electrochemical reaction, among several chemical reaction models, one that fits the data best is adopted after a comprehensive comparative study. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a specified average current density. The procedure is iterative as the local current density, or the reaction rate, is allowed to vary with the gas composition. A series of calculations are then carried out to examine the effects of gas flow rate, gas composition, gas usage rate, inlet gas temperature, and average current density on the fuel cell performance. The fuel cell characteristics, such as the temperature, current density distributions, and the concentration fields, for various operating conditions are presented and discussed.

• Korean Journal of Metals and Materials
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• v.50 no.6
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• pp.445-448
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• 2012

We studied the effect of temperature and reaction time by investigating the various temperatures and reaction times in the reduction of molybdenum oxide ($MoO_3$) to molybdenum (Mo) powder in hydrogen gas. We also studied the effect of the reaction of reduction according to the various hydrogen gas flow rates. We surveyed the reduction from molybdenum oxide to molybdenum powder in hydrogen gas and checked two temperature ranges, one from $400^{\circ}C$ to $600^{\circ}C$ and the other from $700^{\circ}C$ to $900^{\circ}C$. We found that the reaction ratio of molybdenum oxide increased with an increasing temperature and also increased with an increasing reaction time, but hydrogen gas did not influence the reduction ratio of molybdenum oxide. We examined molybdenum powders fabricated by ball milling for two hours, using with X-ray diffraction (XRD) and a scanning electron microscopy (SEM).