• Elastomers and Composites
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• 제55권2호
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• pp.137-146
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• 2020

Part 1 provides a theoretical introduction of the hydrolysis mechanism, while Part 2 introduces other types of reaction mechanisms after hydrolysis in elastomer and PA66 composites. We reviewed the condensation reaction, which occurs after hydrolysis in bi-functional alkoxy silane (TESPD & TESPT), and investigated its effects on the mechanical properties of the composites. We also reviewed activators such as zinc soap, which enhances the mechanical properties of silica-silane-filled elastomer composites. The interaction parameter of silica-silane-filled elastomer composites [α_C (alpha C)] were also discussed. The effects of hydrolysis on the mechanical property changes in plastic composites were compared and reviewed.

• 한국항공우주학회지
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• 제37권12호
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• pp.1225-1231
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• 2009

인공위성의 반작용 휠 클러스터는 보통 4개의 반작용 휠로 구성이 된다. 각각의 반작용 휠은 인공위성의 자세 축과 일치하게 배치되지 않기 때문에 하나의 반작용 휠에 고장이 일어난 경우 반작용 휠 자체의 센서를 이용한 방법 외에는 고장 분리가 매우 어렵다. 본 논문에서는 이중 필터를 이용하여 고장 검출에 효과적인 파라미터를 구성하고, 인공위성의 반작용 휠 각각이 정지 고장을 일으킬 경우를 가정하여 이중 필터와 다중 가설 필터를 이용하여 반작용 휠의 고장분리기를 설계하였다. 또한 이를 4개의 반작용 휠로 자세제어가 이루어지는 인공위성 시스템에 적용한 시뮬레이션으로 고장 검출 및 분리 성능이 향상되는 것을 검증하였다.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.963-970
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• 2012

We review novel chemical kinetics proposed for quantitative description of fluctuations in reaction times and in the number of product molecules in a heterogeneous biological system, and discuss quantitative interpretation of randomness parameter data in enzymatic turnover times of ${\beta}$-galactosidase. We discuss generalization of renewal theory for description of chemical fluctuation in product level in a multistep biopolymer reaction occurring in a dynamically heterogeneous environment. New stochastic simulation results are presented for the chemical fluctuation of a dynamically heterogeneous reaction system, which clearly show the effects of the initial state distribution on the chemical fluctuation. Our stochastic simulation results are found to be in good agreement with predictions of the analytic results obtained from the generalized master equation.

• 한국식품영양학회지
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• 제16권4호
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• pp.321-327
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• 2003

The reaction rates of 4-ethyl pyridine with p-methyl benzylbromide have been measured by conductometry in acetonitrile, and the rate constants of these reactions are determined in accordance with various temperatures (20, 25, 30$^{\circ}C$) and pressures (1, 200, 500, 1000 bar). The rate constants increased with the higher pressure and temperature. The activation energies and activation parameter values of these reactions are calculated by determination of the rate constants the same. The activation volume, activation compressibility coefficient and the activation entropy are all negative. The result of kinetic studies for the pressure show that this reaction proceeds in typical bimolecular nucleophilic substitution reaction.

• 한국환경과학회지
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• 제23권4호
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• pp.615-623
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• 2014

The groundwater level varies according to the characteristics and composite materials of aquifer. In this study, specific yield and reaction factor which are the major two hydrogeological parameters in the WTF(Water Table Fluctuation) method were estimated and analyzed spatial characteristics. 8 groundwater level stations which have enough measuring period and high correlation with rainfall in the Hancheon watershed were used. The results showed that specific yield was randomly distributed and reaction factor showed inverse trend with altitude. If the enough data were collected, reaction factor according to altitude in ungauged points could be estimated by using these parameter characteristics.

• Bulletin of the Korean Chemical Society
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• 제11권1호
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• pp.65-69
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• 1990

The nucleophilic substitution reactions of naphthalene-1,5-disulfonyl chloride and 4-fluorosulfonylbenzenesulfonyl chloride with p-substituted anilines and methyl substituted pyridines in methanol-acetonitrile mixtures and hydrolyses of those disulfonyl halides have been studied by means of conductometric and polarographic methods. A large difference in the selective parameter, ${\rho}_N$ between mono-sulfonyl chloride and disulfonyl halide can be taken as an evidence that the second $SO_2Cl$ grolup of naphthalene-1,5-disulfonyl chloride also takes part in the reaction in contrast to sulfonyl fluoride in 4-fluorosulfonylbenzenesulfonyl chloride, which only acts as a substituent in the nucleophilic substitution reaction.

• 대한토목학회논문집
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• 제34권5호
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• pp.1409-1420
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• 2014

지하수위 변동 해석모델을 이용하여 제주지역의 대수층 수리지질 매개변수인 반응계수와 배수가능공극을 추정하고 고도에 따른 분포특성 및 민감도분석을 실시하였다. 대수층 매질의 특성치인 배수가능공극은 고도에 대해 일정한 경향성을 보이지 않으며 지하수의 흐름 특성치인 반응계수는 고도가 높아질수록 낮아지는 뚜렷한 경향성을 보였다. 매개변수들에 대한 민감도를 알아보기 위해 매개변수의 평균 및 관계식을 이용하여 추정함양량을 비교한 결과, 전 유역(강정천, 외도천, 천미천, 한천)에 대한 매개변수 관계식을 적용하여도 미계측 유역내 매개변수의 추정이 가능할 것으로 판단된다. 따라서 본 연구의 결과를 통해 대표적인 수리지질 매개변수의 분포특성을 파악하여 미계측지역에서 매개변수를 추정함으로써 지하수모델링의 기초자료로도 활용 가능할 것으로 기대한다.

• 대한전기학회논문지:시스템및제어부문D
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• 제55권1호
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• pp.35-41
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• 2006

Although reachers have studied for a long time, they don't make criteria for anesthesia depth. anesthetists can't make a prediction about patient's reaction. Therefor, patients have potential risk such as poisonous side effect late-awake, early-awake and strain reaction. EEG are received from twenty-five patients who agreed to investigate themselves during operation with Enflurane-anesthesis in progress of anesthesia. EEG are divided pre-anesthesia, before incision of skin, operation 1, operation 2, awaking, post-anesthesia by anesthesia progress step. EEG is applied pre-processing, base line correct, linear detrend to get more reliable data. EEG data are handled by electronic processing and the EEG data are calculated by bicoherence. During pre-anesthesia and post anesthesia, appearance rate of bicoherence value is observed strong appearance rate in high frequency range($15\~30Hz$). During the anesthesia of patient, a strong appearance rate is revealed the low frequency area(0~10Hz). After bicoherence is calculated by percentage of a appearance rate, that is, Bicpara$\#$1, Bicpara$\#$2, Bicpara$\#$3 and Bicpara$\#$4 parameter are extracted. In result of bicoherence analysis, Bicpara$\#$2 and Bicpara#4 are considered that the best parameter showed progress of anesthesia effectively. And each separated bicoherence are calculated by average bicoherence's numerical value, divide by 2 area, appear by each BicHz$\#$1, BicHz$\#$2, and observed BicHz$\#$1/BicHz$\#$2's change. In result of bicoherence analysis, BicHz$\#$1, BicHz$\#$2 and BicHz$\#$1/BicHz$\#$2 are considered that the best parameter showed progress of anesthesia effectively. In conclusion, I confirmed the anesthesia progress phase, concluded to usefulness of parameter on bispectrum and bicoherence analysis and evaluated the depth of anesthesia. In the future, it is going to use for doctor's diagnosis and apply to protect an medical accident owing to anesthesia.

• 한국식품과학회지
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• 제21권2호
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• pp.307-312
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• 1989

삼투압 건조중 설탕용액의 농도와 온도 및 침지시간에 따른 내부물질 이동을 당근 내부의 수분손실, 설탕흡수, 몰랄농도 및 속도 매개변수로써 조사하였다. 또한, 삼투압 건조와 데치기가 3% 수분(wet basis)까지 진공건조시 각 공정의 갈색화 반응에 미치는 효과를 평가하였다. 용액 농도와 온도가 증가함에 따라 수분손실, 설탕흡수, 몰랄농도 및 속도 매개변수가 증가하였다. 수분손실과 설탕흡수는 초기 4분간 침지과정에서 빠르게 이루어진 후 증가현상이 둔화되었다. 용액에 따른 설탕 흡수율과 몰랄농도율 변화는 고농도 $(60^{\circ}\;Brix)$보다 저농도$(20^{\circ}\;Brix)$에서 현저하였다. 속도 매개변수, K는 설탕용액의 온도요인 보다 농도에 더 영향이 컸으며, 설탕용액$(60^{\circ}\;Brix,\;80^{\circ}C)$에서 20분간 침지후 55.7%의 수분손실이 되었다. 3% 수분(wet basis)로 진공건조시 갈색화 반응에 대한 삼투압 건조와 데치기의 효과는 현저하였다. 대조구 (O.D.=1.59)와 비교하여 최소 갈색화 반응은 전처리 공정으로써 설탕용액$(40^{\circ}\;Brix,\;80^{\circ}C)$에서 16분간 삼투압 건조 후 진공건조시 O.D.=0.09이었으며, $80^{\circ}C$에서 12분간 브랜칭 후 진공건조시 O.D.=0.31 이었다.

• Earthquakes and Structures
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• 제14권1호
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• pp.85-94
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• 2018

The paper focuses on the seismic responses of a hyperbolic cooling tower resting on soil foundation represented by the three-parameter Vlasov elastic soil model. The three-parameter soil model eliminates the necessity of field testing to determine soil parameters such as reaction modulus and shear parameter. These parameters are calculated using an iterative procedure depending on the soil surface vertical deformation profile in the model. The soil and tower system are modeled in SAP2000 structural analysis program using a computing tool coded in MATLAB. The tool provides a two-way data transfer between SAP2000 and MATLAB with the help of Open Application Programming Interface (OAPI) feature of SAP2000. The response spectrum analyses of the tower system with circular V-shaped supporting columns and annular raft foundation on elastic soil are conducted thanks to the coded tool. The shell and column forces and displacements are presented for different soil conditions and fixed raft base condition to investigate the effects of soil-structure interaction. Numerical results indicate that the flexibility of soil foundation leads to an increase in displacements but a decrease in shell membrane and column forces. Therefore, it can be stated that the consideration of soil-structure interaction in the seismic response analysis of the cooling tower system provides an economical design process.