• Nuclear Engineering and Technology
• /
• 제49권7호
• /
• pp.1423-1430
• /
• 2017

Detonation cell width is an important parameter in hydrogen explosion assessments. The experimental data on gas detonation are statistically analyzed to establish a universal method to numerically predict detonation cell widths. It is commonly understood that detonation cell width, ${\lambda}$, is highly correlated with the characteristic reaction zone width, ${\delta}$. Classical parametric regression methods were widely applied in earlier research to build an explicit semiempirical correlation for the ratio of ${\lambda}/{\delta}$. The obtained correlations formulate the dependency of the ratio ${\lambda}/{\delta}$ on a dimensionless effective chemical activation energy and a dimensionless temperature of the gas mixture. In this paper, support vector regression (SVR), which is based on nonparametric machine learning, is applied to achieve functions with better fitness to experimental data and more accurate predictions. Furthermore, a third parameter, dimensionless pressure, is considered as an additional independent variable. It is found that three-parameter SVR can significantly improve the performance of the fitting function. Meanwhile, SVR also provides better adaptability and the model functions can be easily renewed when experimental database is updated or new regression parameters are considered.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• 제33권11호
• /
• pp.1202-1208
• /
• 2009

An inverse finite element (FE) model parameter estimation algorithm can be used to characterize mechanical properties of biological tissues. Using this algorithm, we can consider the influence of material nonlinearity, contact mechanics, complex boundary conditions, and geometrical constraints in the modeling. In this study, biomechanical experiments on macro and micro samples are conducted and characterized with the developed algorithm. Macro scale experiments were performed to measure the force response of porcine livers against mechanical loadings using one-dimensional indentation device. The force response of the human liver cancer cells was also measured by the atomic force microscope (AFM). The mechanical behavior of porcine livers (macro) and human liver cancer cells (micro) were characterized with the algorithm via hyperelastic and linear viscoelastic models. The developed models are suitable for computing accurate reaction force on tools and deformation of biomechanical tissues.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• 제26권1호
• /
• pp.133-140
• /
• 2002

This article presents an application of a large-scale structural mixing model(Broadwell et at. 1984) to the blowout of turbulent reacting cross flow jets. Experimental observations, therefore, aim to identify the existence of large-scale vortical structure exerting an important effect upon the flame stabilization. In the analysis of common stability curve, it is seen that the phenomenon of blowout are only related to the mixing time scale of the two flows. The most notable observation is that the blowout distance is traced at a fixed positions according to the velocity ratio at all times. Measurements of the lower blowout limits in the liftable flame are qualitatively in agreement with the blowout parameter $\xi$, proposed by Broadwell et al. Good agrement between the results calculated by a modified blowout parameter $\xi$'and the present experimental results confirms the important effect of large-scale structure in the stabilization feature of blowout.

• Proceedings of the KSR Conference
• /
• 한국철도학회 2008년도 춘계학술대회 논문집
• /
• pp.158-167
• /
• 2008

The quality control of compacted fills has been carried out by evaluating relative densities and coefficients of soil reaction. These measures have several limitations regarding repeatability and reliability of field measurements, and difficulties to use in the fills including large grain size as gravels and boulders. Also, the density is not directly related to the design parameter such as resilient modulus. A preliminary investigation for the usage of the stiffness as a control measure has been carried out. In the laboratory, the stiffness (P-wave velocity) was measured during compaction tests. The stiffness at the optimal moisture content was proposed to use a target control parameter likewise maximum dry density. A field method to match the target stiffness was also proposed by considering easiness of the method and availability of equipment. The most phenomenal feature of the method is that the control parameter (stiffness) is closely related to resilient modulus and can be consistently used from the design stage to the field control during construction.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• 제13권4호
• /
• pp.163-176
• /
• 1993

A methodology based on the influence coefficient algorithm was established for the optimal calibration of QUAL2E reaction coefficients. It was applied to the stream sections from the Chungju Dam to the downstream end of the South Han River. A water budget analysis using the monthly records of reservoir inflows and outflows in 1990 was made to determine tributary inflows. Estimated tributary inflows were used, together with the monthly records of water quality measurements in 1990, for the calibration of reaction coefficients. Simulated quality constituents were chl.a. nitrogen cycles, phosphorus cycles. BOD and DO. A sensitivity analysis was made to determine significant reaction coefficients, and as a result 11 reaction coefficients were selected as calibration parameters. The influence coefficient algorithm applied to the calibration of QUAL2E reaction coefficients proved to be a useful one yielding a rapid convergence. Each calibration parameter converged to an optimum value within 3 iterations.

• Journal of the Korean Chemical Society
• /
• 제39권7호
• /
• pp.572-577
• /
• 1995

The reaction rates of aryl substituted(Z)-benzoates with amines were determined by a spectro-photometric method in acetonitrile at various temperatures. Hammett $\rho$, Bronsted ${\beta}$ values, and activation parameters were evaluated from the kinetic data. Linear free energy relationships, activation parameters, and the interpretation of M-O-F-J diagram suggested that these reactions were probably enforced an $S_AN$ mechanism.

• Journal of Environmental Science International
• /
• 제8권3호
• /
• pp.287-292
• /
• 1999

This study was performed to investigate the characteristics of nocturnal maxiumu ozone occurrence and the meteorological relevance using to hourly ozone data and meteorological data for 1995~1996 in Pusan coastal area. Kwangbokdong showed the highest occurrence of nocturnal maximum ozone as 36.9%, and Deokcheondong showed the lowest occurrence(9.2%) for research period in Pusan. The occurrence rates of nocturnal maximum ozone concentration were decreased toward land area. The low maximum temperature, high minimum temperature, low diurnal range, high relative humidity, high wind speed, high could amount, low sunshine and low radiation were closely related to the main meteorological characteristics occuring the nocturnal maximum concnetration of ozone. It was shown that normal daily variation of ozone concentration by strong photochemical reaction at the before day of nocturnal maximum ozone. The concnetration of nocturnal maximum ozone were occured by entrainment of ozone from the upper layer of developed mixing layer. There are no ozone sources near the ground at night, so that the nighttime ozone should be entrained from the upper layer by forced convection.

• Journal of Powder Materials
• /
• 제18권1호
• /
• pp.73-77
• /
• 2011

$Y(OH)_3$ nanowires were synthesized by a hydrothermal reaction of metallic Y with aqueous solution of LiOH. The morphology and the size of the nanowires changed with varying the volume of the LiOH solution inside the autoclave. $Y(OH)_3$ nanowires transformed to $Y_2O_3$ by a subsequent heat-treatment without morphological change. By a proper control of hydrothermal reaction parameter and heat-treatment, the yield of pure $Y_2O_3$ nanowires up to 97% was attained.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 한국윤활학회 1998년도 제27회 춘계학술대회
• /
• pp.180-189
• /
• 1998

This paper was undertaken to do shape analysis of wear debris on oiliness agent and extreme pressure agent. The lubricating wear test was performed under different experimental conditions using the wear test device was made in our laboratory and were- specimens of the pin on disk type was rubbed in paraffine series base oil by materials, varying applied load, sliding distance, oil additives such as stearine acid, DBDS, TCP. The four shape parameters (50% volumetric diameter, aspect, roundness and reflectivity) on a kind of the additives are different on applied load and sliding distance and Its are affected by absorbed film and reaction film. DBDS and TCP have a role of extreme pressure agent but a role of absorbed film of stearic acid decrease in high load. The maximum wear volume on applied load be in existence in three kinds of the specimens because of reaction characteristics of the additives.

• Bulletin of the Korean Chemical Society
• /
• 제34권12호
• /
• pp.3811-3816
• /
• 2013

Nucleophilic substitution reactions of ethyl methyl (2), ethyl propyl (4) and diisopropyl (7) chlorothiophosphates with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. A concerted mechanism is proposed based on the selectivity parameters. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are secondary inverse ($k_H/k_D=0.66-0.99$) with 2, primary normal and secondary inverse ($k_H/k_D=0.78-1.19$) with 4, and primary normal ($k_H/k_D=1.06-1.21$) with 7. The primary normal and secondary inverse DKIEs are rationalized by frontside attack involving hydrogen bonded, four-center-type transition state, and backside attack involving in-line-type transition state, respectively. The anilinolyses of ten chlorothiophosphates are examined based on the reactivity, steric effect of the two ligands, thio effect, reaction mechanism, DKIE and activation parameter.