• 자원리싸이클링
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• 제11권6호
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• pp.47-54
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• 2002

내경 2.8cm, 높이 65cm의 반응관을 이용하여 1000∼1400 K에서 산소-질소 혼합 가스류 중을 낙하하는 동정광 입자의 1차원 비등온 산화반응의 초기거동에 대하여 검토하였다. 동 정광은 반응관을 낙하하면서 매우 빠르게 산화 용융되었다. 입자 온도는 미 반응핵 모델과 가스-입자간의 물질전달 및 가스-입자-관벽 사이의 열전달을 조합하여 계산하였다. 계산에 의한 입자 온도는 반응관 상단에서 20∼30cm의 위치에서 최고온도에 도달하였으며, 고 산소분압에서는 약 1700 K에 도달하였다. 산소분압이 0.2 atm 이상인 경우 대부분의 입자는 용융되었다.

• Journal of the Korean Wood Science and Technology
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• 제45권2호
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• pp.182-194
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• 2017

The optimum alkali pretreatment parameters (reaction time, reaction temperature and potassium hydroxide concentration) for facilitate the conversion into fermentable sugar (glucose) from steam exploded (severity log Ro 2.45) barley husk were determined using Response Surface Methodology (RSM) based on a factorial Central Composite Design (CCD). The prediction of the response was carried out by a second-order polynomial model and regression analysis revealed that more than 88% of the variation can be explained by the models. The optimum conditions for maximum cellulose content were determined to be 201 min reaction time, $124^{\circ}C$ reaction temperature and 0.9% potassium hydroxide concentration. This data shows that the actual value obtained was similar to the predicted value calculated from the model. The pretreated barley husk using acid hydrolysis resulted in a glucose conversion of 94.6%. This research of steam explosion and alkali pretreatment was a promising method to improve cellulose-rich residue for lignocellulosic biomass.

• 대한인간공학회지
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• 제25권4호
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• pp.23-33
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• 2006

The purpose of this study is to determine the economical standard of road signs by verifying the difference of driver's recognition and reaction time according to the space rate of letters on the road signs. For this reason, indoor simulations was conducted to confirm difference of recognition and reaction time on six sign-targets having different space rate. Also, a negative binomial regression model was used to find the main factors which could lower the rate of misreading. For this model, increasing of legibility of sign is not only simple enlargement of sign, but also suitable match of letters and sign. The result of this study is capable of verifying the importance of the space rate in road signs, and being utilized as a effective method to determine the standard of the road signs.

• 한국세라믹학회지
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• 제53권5호
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• pp.511-520
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• 2016

Electrolyte-supported symmetric Ni-YSZ cermet electrodes of ca. $23{\mu}m$ were prepared by screenprinting and the impedance was measured as a function of humidity from 2% to 90% balanced in $H_2$ at a total flow rate of 50 sccm. The Ni felt current collector of 1 mm thickness exhibited a Gerischer-like gas concentration impedance in the low frequency range, which was similarly observed in the cermet-supported solid oxide cells, while the Pt paste collector exhibited only electrochemical polarization. The electrochemical polarization of both samples was modeled by a non-ideal diffusion-reaction transmission line model including CPEs with ${\alpha}$= 0.5. In the case of the Pt paste collector, all the Bisquert parameters exhibited humidity dependence to the -1/2 power, supporting a non-faradaic chemical reaction mechanism at three phase boundaries. Consequently, the surface diffusivity and reaction rate increased linearly with humidity. Less pronounced humidity dependence and somewhat lower utilization length with an Ni felt collector can be attributed to the diffusion-limited gas flow through the collector.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.35-35
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• 2010

Understanding the mechanistic details of heterogeneous catalytic reactions will provide a way to tune the selectivity between various competing reaction channels. In this regard, catalytic decomposition of alcohols over the rutile $TiO_2$(110) surface as a model oxide catalyst has been studied to understand the reaction mechanism employing the temperature-programmed desorption (TPD) technique. The $TiO_2$(110) model catalyst is found to be active toward alcohol dehydration. We find that the active sites are bridge-bonded oxygen vacancies where RO-H heterolytically dissociates and binds to the vacancy to produce alkoxy (RO-) and hydroxyl (HO-). Two protons adsorbed onto the bridge-bonded oxygen atoms (-OH) readily react with each other to form a water molecule at ~500 K and desorb from the surface. The alkoxy (RO-) undergoes decomposition at higher temperatures into the corresponding alkene. Here, the overall desorption kinetics is limited by a first-order decomposition of intermediate alkoxy (RO-) species bound to the vacancy. We show that detailed analysis on the yield and the desorption temperatures as a function of the alkyl substituents provides valuable insights into the reaction mechanism. After the catalytic role of the oxygen vacancies has been established, we employed x-ray photoelectron spectroscopy to further study the surface electronic structure related to the catalytically active defective sites. The defect-related state in valence band has been related to the chemically reduced $Ti^{3+}$ defects near the surface region and are found to be closely related to the catalytic activity of the $TiO_2$(110) surface.

• 대한화학회지
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• 제19권5호
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• pp.294-303
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• 1975

直線 衝突모형을 써서 三原子 置換反應 $A+B-C{\to}A-B+C$의 反應確率을 全體 에너지의 函數로 計算하였다. 使用한 포텐셜 에너지 亦是 極히 單純한 理想的인 것이다. 세原子의 質量이 모두 같은 경우에 대하여 數値로 結果를 얻어서 더욱 더 간단한 모형을 쓴 다른 硏究者들의 結果와 比較하여 定性的으로 더 나음을 알았다.

• Bulletin of the Korean Chemical Society
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• 제35권5호
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• pp.1403-1408
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• 2014

The cycloaddition reactions of the N-heterocyclic carbene boryl azide with methyl acrylate, butenone, and hexafluoropropene have been investigated theoretically. Solvent effects on these reactions have been explored by calculation that included a polarizable continuum model (PCM) for the solvent (C6H6). The title reaction could produce 4- and 5-substituted 1,2,3-triazolines, respectively. The reaction systems have the higher chemical reactivity with the low barriers and could be favored. Yet the smaller differences have been found to occur in energetics, and the cycloaddition reactions occur for s-trans conformations over s-cis conformations. The calculations indicated that the cycloaddition reaction of the alkenes have certain regioselectivity.

• 한국마이크로전자및패키징학회:학술대회논문집
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• 한국마이크로전자및패키징학회 2001년도 추계 기술심포지움
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• pp.134-137
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• 2001

The cure kinetics of a cycloalipatic epoxy / anhydride / Co(II) system for a no-flow underfill encapsulant, has been studied by using a differential scanning calorimetry(DSC) under isothermal and dynamic conditions over the temperature range of $160^{\circ}C ~220^{\circ}C$. The kinetic analysis was carried out by fitting dynamic/isothermal heating experimental data to the kinetic expressions to determine the reaction parameters, such as order of reaction and reaction constants. Diffusion-controlled reaction has been observed as the cure conversion increases and successfully analyzed by incorporating the diffusion control term into the rate equation. The prediction of reaction rates by the model equation corresponded well to experimental data at all temperature.

• 제어로봇시스템학회:학술대회논문집
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• 제어로봇시스템학회 2001년도 ICCAS
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• pp.117.5-117
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• 2001

This paper presents the key idea of handlebar reaction force and pedal resistance force generation in creating life-like feeling in KAIST bicycle simulator. Also, it provides methods to evaluate its reality level with given reaction force profile. In KAIST bicycle simulator, the pedal resistance force and the handlebar reaction force are calculated using the bicycle dynamic model. With the information handlebar angle, rider´s pedaling torque and road profile transmitted from the handlebar system, the pedal system and the visual part, the bicycle dynamics engine calculates the handlebar reaction force and the pedal velocity. The handlebar system and the pedal resistance system generate reaction force and resistance force transmitted from dynamics engine. However to make more realistic riding feeling ...

• 한국해양공학회지
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• 제19권3호
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• pp.11-17
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• 2005

The effect of frequency and amplitude of the OWC (Oscillating Water Column) motion on the nonlinear reaction forces in an air duct are studied experimentally. Experimental owe model is idealized as a simple circular cylinder with an orifice type air duct located at the middle oj the top rid. Reaction forces due to forced heave oscillation are measured and analyzed. By subtracting the effect of inertia forces and restoring forces, pneumatic damping force and added spring force are deduced. The effects of the frequency and amplitude of the heave motion are discussed. Also, the effects of solidity of the duct on the reaction forces are discussed.