• Title/Summary/Keyword: Reaction characteristics.

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The Effect of CVD Reaction Variable on SnO2 Powder Characteristics

  • Kim, Kyoo-Ho
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.235-239
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    • 1998
  • Ultrafine $SnO_2$ powder was prepared by the diffusion mixing gas-phase reaction of $SnCl_4$(g) and water vapor. The effects of reaction variables, such as the chloride partial pressure, the reaction temperature, and the residence time is the reactor, on the powder size were examined systematically. Calculated concentration and distribution of chemical species, using the Burke-Schumann diffusion mixing model, were compared with the experimetal results. The effects of the reaction variables on the powder size were also discussed qualitatively.

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Characteristics of Maltose Formation in Heterogeneous Enzyme Reaction System Utilizing Swollen Extrusion Starch as a Substrate (팽윤 Extrusion 전분을 기질로 한 불균일상 효소반응계에서의 Maltose 생성 반응 특성)

  • Kim, Dong-Sun;Park, Dong-Chan;Cho, Myung-Jin;Lee, Yong-Hyun
    • Microbiology and Biotechnology Letters
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    • v.22 no.3
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    • pp.283-289
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    • 1994
  • The production of maltose utilizing swollen extrusion starch seems to have many technical advantages, such as, high reaction rate and high yield, production of high purity concentrated maltose, and low energy consumption, over the conventional method utilizing liquefied starch. The characteristics of maltose formation in heterogeneous enzyme reaction system comtaining swollen extrusion starch was investigated using fungal $\alpha $-amylase. The influence of extrusion conditions on structure of extruded starch, such as, degree of gelatinization, water absorption index, and water solubility index was analyzed. The relationship between the structural features and maltose forming reaction was investigated, and the result was analyzed in terms of surface reaction of insoluble extruded swollen starch. The characteristics of maltose formation from swollen sxtrusion starch was compared using endo-type fungal $\alpha $-amylase and exo-type $\beta $anylase, and the structural trasformation of extruded starch was also observed to clarify the reaction mechanism.

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A Study on Driving Characteristics of the Elderly Driver using a Driving Simulator (운전모의장치를 이용한 고령자의 운전특성 연구)

  • Lee, Won-Young
    • Journal of the Korean Society of Safety
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    • v.21 no.5 s.77
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    • pp.103-111
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    • 2006
  • The purpose of this study was to analyse the relationships between cognitive abilities and driving characteristics of elderly drivers. Driving characteristics of elderly and younger drivers who were driving a fixed base driving simulator vehicle were examined. Participants consisted of 12 drivers over age 65 (the 'older' group) and 12 drivers between the ages of 25 and 55 (the "younger" group). As indices of cognitive ability, critical flicker fusion frequency (CFF) tests and cognitive reaction tests were given before the driving task. CFF was also tested after the simulated driving task for both groups. Cognitive reaction tests, which were composed of speed estimation tests, multiple choice reaction tests and obstacle avoidance tests, were developed by the Korean Road Traffic Safety Authority in 2003. CFF values between the two groups exhibited significant differences both before and after the task, with a p-value less than 0.01 and a t-value of -3.01 before the test and a p-value less than 0.031 and a t-value of -2.35 after the test. Older drivers' CFF values were lower than those of the younger. However, there was no difference in older or younger driver CFF values before and after the task within the same group. Except for the multiple choice reaction test, there was no difference in cognitive reaction test results between the two groups. The elderly drivers made more errors though they did not differ from the younger drivers in reaction times. At the simulated driving task the reaction time of the elderly driver was longer than that of the younger; however, the driving speed of the elderly was lower and the number of collisions greater. There was a positive correlation (r=.496) between the number of errors in the multiple choice reaction test and the number of collisions in the driving task. Therefore, it was identified that critical attributes contributing to automobile crashes involving elderly drivers included cognitive difficulty in judging and responding to complex situations.

Characteristics of Transesterification Reaction of Soy Bean Oil by Acid Catalysts (산촉매에 의한 대두유의 전이에스테르화 반응 특성)

  • Shin, Yong-Seop
    • Journal of Environmental Science International
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    • v.18 no.2
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    • pp.231-238
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    • 2009
  • Characteristics of the transesterification reaction between triglycerides in soy bean oil and methanol were investigated in the presence of acid catalysts. such as sulfuric acid and PTS (p-toluene sulfonic acid). Concentrations of diglyceride and monoglyceride which were intermediates in the reaction mixtures, were far below 10% of triglyceride under any reaction conditions. Thus, conversion of the reaction could be determined from the concentration of triglyceride. Dried PTS had more superior catalytic power than sulfuric acid for transesterification reaction between soy bean oil and methanol. When transesterification reaction of soy bean oil was catalyzed by 1 wt% of PTS at methanol stoichiometric mole ratio of 2 and $65^{\circ}C$, final conversion reached 95% within 48 hours. If FAME (fatty acid methyl ester) was added into reaction mixture of soy bean oil, methanol and PTS catalyst, it converted reaction mixture into homogeneous phase, and substantially increased reaction rate. When reaction mixture was freely boiling which had equal volumetric amount of FAME to soy bean oil, methanol stoichiometric mole ratio of 2 and 1 wt% of PTS, final conversion achieved value of 94% and temperature approached to $110^{\circ}C$ within 2 hours.

Novel Heterogeneous Carbohydrase Reaction Systems for the Direct Conversion of Insoluble Carbohydrates: Reaction Characteristics and their Applications

  • Lee, Yong-Hyun;Park, Dong-Chan
    • Journal of Microbiology and Biotechnology
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    • v.9 no.1
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    • pp.1-8
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    • 1999
  • Most carbohydrates exist in nature in an insoluble state, which reduces their susceptibility towards various carbohydrases. Accordingly, they require intensive pretreatment for structural modification to enhance an enzyme reaction. The direct conversion of insoluble carbohydrates has distinct advantages for special types of reaction, especially exo-type carbohydrase; however, its application is limited due to structural constraints. This paper introduces two novel heterogeneous enzyme reaction systems for direct conversion of insoluble carbohydrates; one is an attrition coupled enzyme reaction system containing attrition-milling media for enhancing the enzyme reaction, and the other is a heterogeneous enzyme reaction system using extruded starch as an insoluble substrate. The direct conversion of typically insoluble carbohydrates, including cellulose, starch, and chitin with their corresponding carbohydrases, including cellulase, amylase, chitinase, and cyclodextrin glucanotransferase, was carried out using two proposed enzyme reaction systems. The conceptual features of the systems, their reaction characteristics and mechanism, and the industrial applications of the various carbohydrates are analyzed in this review.

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Influence of Combustor Pressure on Combustion Characteristics and Local Flame Reaction in the Partially Premixed Flames with $CH_4$, $C_2H_4$ and $C_3H_8$ (부분 예혼합 화염의 연소실 압력이 연료별(메탄, 에틸렌, 프로판) 연소특성과 국소 화염 반응에 미치는 영향)

  • Kim, Jong-Ryul;Son, Je-Ha;Noh, Young-Gu;Kim, Yun-Dong;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.29-36
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    • 2010
  • An experimental study was conducted for three different fuels($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the combustion characteristics and the local reaction intensity with combustor pressure(-30kpa~30kpa). Regardless of fuel composition, EINOx decreased with reducing pressure decreased. Structure and combustion characteristics were also largely affected by the combustor pressure. In addition, reaction intensity in terms of the changing combustor pressure and equivalence ratio was investigated. Combustion reaction in higher than atmospheric pressure was very active than the lower combustor pressure. When the combustor pressure is lower than the atmospheric pressure, the overall reactivity is noticeably enhanced due to the elevated diffusion process of unburned mixture. It was found that the combustion characteristics of the methane and propane flames are considerably influenced by the pressure while those of ethylene flame are less sensitive to the combustor pressure.

A Study on the Characteristics of Parameters in Groundwater Table Fluctuation Model (지하수위 변동 해석모델의 매개변수 특성 연구)

  • Kim, Nam-Won;Kim, Youn-Jung;Chung, Il-Moon
    • Journal of Environmental Science International
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    • v.23 no.4
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    • pp.615-623
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    • 2014
  • The groundwater level varies according to the characteristics and composite materials of aquifer. In this study, specific yield and reaction factor which are the major two hydrogeological parameters in the WTF(Water Table Fluctuation) method were estimated and analyzed spatial characteristics. 8 groundwater level stations which have enough measuring period and high correlation with rainfall in the Hancheon watershed were used. The results showed that specific yield was randomly distributed and reaction factor showed inverse trend with altitude. If the enough data were collected, reaction factor according to altitude in ungauged points could be estimated by using these parameter characteristics.

The Effects of the Tempered Materials on the Thermal Runaway Characteristics in the Resol Resin Synthesis Reaction (레졸수지 합성반응에서 온도조절 물질이 열폭주 특성에 미치는 영향)

  • Lee, Jung-Suk;Lee, Keun-Won
    • Journal of the Korean Institute of Gas
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    • v.18 no.4
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    • pp.27-34
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    • 2014
  • In this study, we evaluated an effect of the tempered materials on the thermal runaway characteristics in the resol resin synthesis reaction using the adiabatic calorimetry of vent sizing package 2(VSP2). The kinetic parameters, such as an activation energy and heat of reaction, were estimated using the test results. As the results, the instantaneous characteristics to express the intensity of runaway reaction decreased at the low solid content. However, the sudden loss of the tempered materials triggered the second runaway reaction rapidly. In this condition, the heat of reaction and the activation energy of phenol and p-formaldehyde were about 157 kJ/mol and 60 kJ/mol, respectively.

Torque and Force Measurement of a Prototype HAU Reaction Wheel and the Effect of Disturbance on the Attitude Stability of Spacecraft

  • Oh, Hwa-Suk;Kwon, Jae-Wook;Lee, Hyunwoo;Nam, Myung-Ryong;Park, Dong-Jo
    • Journal of Mechanical Science and Technology
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    • v.15 no.6
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    • pp.743-751
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    • 2001
  • A Prototype reaction wheel, named the Hankuk Aviation University (HAU) reaction wheel, has been developed for KAISTSAT satellite series. Torque and force disturbances are inherent in reaction wheels, and thus the force and torque characteristics should be examined for every newly developed reaction wheel. The torque and force disturbance noises in the prototype HAU reaction wheel are measured with a torque-measuring table developed for the present study. A new measuring procedure based on a simple principle is applied for the measurements. The frequency characteristics of the torque and force noises are analyzed by examining the power spectral density. The effect of the torque noise on the attitude stability is also examined through numerical simulations with a single-axis attitude model. The noise-induced attitude error and jitter and found to be well below the specified error limits for the KAISTSAT satellite series.

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Cure Properties of Novel Epoxy Resin Systems for WLP (Wafer Level Package) According to the Change of Hardeners (경화제 변화에 따른 WLP(Wafer Level Package)용 신규 Epoxy Resin System의 경화특성)

  • Kim, Whan Gun
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.2
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    • pp.57-67
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    • 2022
  • The curing characteristics of naphthalene type epoxy resin systems according to the change of curing agent were investigated to develop a new next-generation EMC(Epoxy Molding Compound) with excellent warpage characteristics, low thermal expansion, and excellent fluidity for WLP(Wafer Level Package). As epoxy resins, DGEBA, which are representative bisphenol type epoxy resins, NE-16, which are the base resins of naphthalene type epoxy resins, and NET-OH, NET-MA, and NET-Epoxy resins newly synthesized based on NE-16 were used. As a curing agent, DDM (Diamino Diphenyl Methane) and CBN resin with naphthalene moiety were used. The curing reaction characteristics of these epoxy resin systems with curing agents were analyzed through thermal analysis experiments. In terms of curing reaction mechanism, DGEBA and NET-OH resin systems follow the nth curing reaction mechanism, and NE-16, NET-MA and NET-Epoxy resin systems follow the autocatalytic curing reaction mechanism in the case of epoxy resin systems using DDM as curing agent. On the other hand, it was found that all of them showed the nth curing reaction mechanism in the case of epoxy resin systems using CBN as the curing agent. Comparing the curing reaction rate, the epoxy resin systems using CBN as the curing agent showed a faster curing reaction rate than them with DDM as a hardener in the case of DGEBA and NET-OH epoxy resin systems following the same nth curing reaction mechanism, and the epoxy resin systems with a different curing mechanism using CBN as a curing agent showed a faster curing reaction rate than DDM hardener systems except for the NE-16 epoxy resin system. These reasons were comparatively explained using the reaction rate parameters obtained through thermal analysis experiments. Based on these results, low thermal expansion, warpage reduction, and curing reaction rate in the epoxy resin systems can be improved by using CBN curing agent with a naphthalene moiety.