• Title/Summary/Keyword: Rate equation

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Kinetics and Mechanism of the Hydrolysis of Phenylvinylsulfone (Phenylvinylsulfone의 가수분해 반응메카니즘과 그의 반응속도론적 연구)

  • Kim, Tae Rin;Choi Choon-Chuel
    • Journal of the Korean Chemical Society
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    • v.19 no.2
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    • pp.123-129
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    • 1975
  • The rate constants of the hydrolysis of phenylvinylsulfone were determined by ultraviolet spectrophotometry at various pH and a rate equation which can be applied over wide pH range was obtained. The reaction mechanism of hydrolysis of phenylvinylsulfone and especially the catalytic contribution of hydroxide ion which did not study carefully before in acidic media, can be fully explained by the rate equation obtained. The rate equation reveals that: below pH 7, the reaction is initiated by the addition of water molecule to phenylvinylsulfone. At above pH 9, the overall rate constant is only dependent upon the concentration of hydroxide ion.

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Application of the EPU Constitutive Equation to expanded Polypropylene under Dynamic Loading (동하중을 받는 발포 폴리프로필렌에 대한 EPU 구성 방정식 적용)

  • Jeong, Kwang Young;Kim, Byeong-Jun;Cheon, Seong S.
    • Composites Research
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    • v.27 no.4
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    • pp.135-140
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    • 2014
  • A constitutive equation, which was suggested for describing the compressive deformation behaviour of the expanded polyurethane, was applied to the expanded polypropylene under dynamic loading. This equation consists of seven parameters, five of which are obtained by fitting the stress strain curve obtained from the quasi-static compression test at the lowest base strain rate. The remaining two parameters are able to be determined by fitting the curve from the compression test at different two stage strain rates. In order to check the eligibility of the equation at high strain rate, the impact test was performed and the results were compared to the analytical constitutive equation results for the expanded polypropylene with expansion ratios of 30 and 40 times, respectively.

Derivation of Empirical Method to Enhance the Accuracy of Cannon Tube Erosion Rate (포신 마모 예측의 정확도 향상을 위한 실험적 방법 유도)

  • 정동윤;오명호
    • Journal of the Korea Institute of Military Science and Technology
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    • v.5 no.3
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    • pp.23-32
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    • 2002
  • We predict the erosion rate of unknown cannon tubes by substituting measured values of the standard cannon, 155㎜ Howitzer M185 and ballistic data for the erosion equation. We know ten measured erosion values of the standard cannon at every 400 rounds. An approximate formula is derived to interpolate six values up to 2,000 rounds. Numerical example is presented and its results are analyzed. The new erosion equation is also suggested. This equation produces more accurate cannon tube erosion rate than the Rauf Imam's empirical approaches. Computer simulations are presented.

Analysis of Temperature Effect on Activated Sludge Process at Cheong-Gye Cheon Sewage Treatment Plant (활성오니공법에 있어서 수온이 처리효율에 미치는 영향에 관한 분석 -청계천 하수종말처리장에 대하여-)

  • 이은경
    • Journal of Environmental Health Sciences
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    • v.7 no.1
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    • pp.9-20
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    • 1981
  • This study was performed to determine the correlationship between temperature and overall removals of BOD, SS and to demonstrate the effect of temperature on treatment performance. These data for a period from February 1, 1977 to January 31, 1980 were obtained from the Cheong-Gye Cheon Sewage Treatment plant. The results of correlation and stepwise multiple regression analysis were as follows. 1) Secondary effluent BOD and SS showed negative correlationship with water temperature, with correlation coefficient of -0.1710, and -0.1654 respectively. 2) Correlation coefficient of BOD, SS removal rate and water temperature were 0.1823 and 0.0429 respectively. 3) Regresion equation for estimate of BOD removal rate was as follows $\widehat{Y}_1$ (BOD removal rate)=63.9994+0.5442X(water temperature). And BOD removal rate showed non significant change according to the water temperature. 4) Regression equation for estimate of SS removal rate was as follows $\widehat{Y}_2$ (SS removal rate)=61.6881+0.1514X(Water temperature). And SS removal rate showed non significant change according to the water temperature. 5) According to the Stepwise Multiple Regression analysis, water temperature ranked second order in the BOD removal rate estimation and the equation was as follows $\widehat{Y}_1$ (BOD removal rate)=69.7398+0.2665 $X_1$ (Primary effluent BOD)+0.3562 $X_2$ (Water temperature)-0.0122 $X_3(Flow)+4413.271X_4$ (Organic Loading).

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New Empirical Approach to Enhance The Accuracy of Cannon Tube Erosion Rate

  • Chung, Dong-Yoon;Oh, Myoung-Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.231-232
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    • 2002
  • Various methods that utilize erosion rate measurement of standard cannon, 155mm Howitzer M185, as reference, are being used to calculate erosion rate of an interested unknown cannon tubes. We know ten measured erosion values of the standard cannon from 391 rounds to 4.000. An approximate function fitting these value s is derived. The new erosion equation is also suggested and computer simulations arc presented.

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EXPONENTIAL DECAY FOR THE SOLUTION OF THE VISCOELASTIC KIRCHHOFF TYPE EQUATION WITH MEMORY CONDITION AT THE BOUNDARY

  • Kim, Daewook
    • East Asian mathematical journal
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    • v.34 no.1
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    • pp.69-84
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    • 2018
  • In this paper, we study the viscoelastic Kirchhoff type equation with a nonlinear source for each independent kernels h and g with respect to Volterra terms. Under the smallness condition with respect to Kirchhoff coefficient and the relaxation function and other assumptions, we prove the uniform decay rate of the Kirchhoff type energy.

STABILIZATION FOR THE VISCOELASTIC KIRCHHOFF TYPE EQUATION WITH A NONLINEAR SOURCE

  • Kim, Daewook
    • East Asian mathematical journal
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    • v.32 no.1
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    • pp.117-128
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    • 2016
  • In this paper, we study the viscoelastic Kirchhoff type equation with a nonlinear source $$u^{{\prime}{\prime}}-M(x,t,{\parallel}{\bigtriangledown}u(t){\parallel}^2){\bigtriangleup}u+{\int}_0^th(t-{\tau})div[a(x){\bigtriangledown}u({\tau})]d{\tau}+{\mid}u{\mid}^{\gamma}u=0$$. Under the smallness condition with respect to Kirchhoff coefficient and the relaxation function and other assumptions, we prove the uniform decay rate of the Kirchhoff type energy.

Application of Reaction Path Smoluchowski Equation Formalism to the Photoisomerization of Trans-Stilbene

  • Kim, Dong-Sup;Lee, Sang-Youb
    • Bulletin of the Korean Chemical Society
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    • v.12 no.6
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    • pp.692-698
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    • 1991
  • The reaction path Smoluchowski equation approach developed in a recent work to calculate the rate constant for a diffusive multidimensional barrier crossing process is extended to incorporate the configuration-dependent diffusion matrix. The resulting formalism is then applied to the investigation of stilbene photoisomerization dynamics. Adapting a model two-dimensional potential and a model diffusion matrix proposed by Agmon and Kosloff [J. Phys. Chem.,91 (1987) 1988], we derive an eigenvalue equlation for the relaxation rate constant of the stilbene photoisomerization. This eigenvalue equation is solved numerically by using the finite element method. The advantages and limitations of the present method are discussed.

NEWTON'S METHOD FOR SOLVING A QUADRATIC MATRIX EQUATION WITH SPECIAL COEFFICIENT MATRICES

  • Seo, Sang-Hyup;Seo, Jong-Hyun;Kim, Hyun-Min
    • Honam Mathematical Journal
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    • v.35 no.3
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    • pp.417-433
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    • 2013
  • We consider the iterative solution of a quadratic matrix equation with special coefficient matrices which arises in the quasibirth and death problem. In this paper, we show that the elementwise minimal positive solvent of the quadratic matrix equations can be obtained using Newton's method if there exists a positive solvent and the convergence rate of the Newton iteration is quadratic if the Fr$\acute{e}$chet derivative at the elementwise minimal positive solvent is nonsingular. Although the Fr$\acute{e}$chet derivative is singular, the convergence rate is at least linear. Numerical experiments of the convergence rate are given.

The Energy Release Rate for Cracks in a Rotating Continuum (균열을 내재한 회전체의 에너지방출률)

  • 이태원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.330-337
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    • 1995
  • For a rotating body with cracks, the new energy release rate equation is presented. The derived equation is different from the other researcher's results. It is a path-independent integral which excluded the derivatives of displacements near the crack tip, thereby improving the numerical accuracy of the energy release rate computation. Moreover, as the equation was derived on basis of the energy principle and non-linear elasticity without assumptions, it can applied to the cracked body with arbitrary shape under elastic-plastic deformation. Several examples are treated to demonstrate the efficiency and accuracy of the proposed method compared to existing methods.