• Title/Summary/Keyword: Rate Dependence

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Two-dimensional Nature of Center-of-mass Excitons Confined in a Single CdMnTe/CdTe/CdMnTe Heterostructure

  • Lee, Woojin;Kim, Minwoo;Yang, Hanyi;Kyhm, Kwangseuk;Murayama, Akihiro;Kheng, Kuntheak;Mariette, Henri;Dang, Le Si
    • Current Optics and Photonics
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    • v.2 no.6
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    • pp.589-594
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    • 2018
  • We have investigated the dimensional nature of center-of-mass exciton confinement states in a CdMnTe/CdTe/CdMnTe heterostructure, where the CdTe well is too wide (144 nm) to confine both electrons and holes but able to confine whole excitons in the center-of-mass coordinate. Fine multiple photoluminescence spectra with a few meV separation were observed at 6 K. From the thickness dependence of the transition rate, they were attributed to even numbered center-of-mass exciton confinement states (N = 2, 4, 6, ${\cdots}$, 18). Dimensionality of the center-of-mass exciton confinement states was also investigated in terms of temperature dependence of radiative decay time. At low temperatures (${\leq}12K$), we found that the ground state excitons are likely localized possibly due to the barrier interface fluctuation, resulting in a constant decay time (~350 ps). With increased temperature (${\geq}12K$), localized excitons are thermally released, giving rise to a linear temperature dependence of radiative decay time as an evidence of two-dimensional nature.

COMMON RAIL INJECTOR MODIFIED TO ACHIEVE A MODULATION OF THE INJECTION RATE

  • FICARELLA A.;GIUFFRIDA A.;LANZAFAME R.
    • International Journal of Automotive Technology
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    • v.6 no.4
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    • pp.305-314
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    • 2005
  • Injection rate shape control is one feature of a diesel fuel injection system that is strongly desired at this time. In the conventional common rail system, it is difficult to control the injection rate since the fuel pressure is constant during the injection period, resulting in a nearly rectangular rate shape. In order to look into possible injection modulations, injectors equipped with standard and geometrically modified control valves were investigated in detail by means of computer modelling and simulation. Experiments were carried out to validate the feasibility of such a shaping. The results of this study show a noteworthy dependence of the fuel rate on geometrical modifications in the piloting stage of the injector.

The Improved Success Rate of Integer Ambiguity Resolution by Using Many Visible GPS/GNSS Satellites

  • Kondo, Kentaro
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • v.2
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    • pp.243-246
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    • 2006
  • This study investigates the improvement in the theoretical success rate of the integer ambiguity resolution in GPS/GNSS carrier-phase positioning by using many visible satellites. It estimates the dependence of the rate on the baseline length in relative positioning under the condition of the use of double/triple-frequency navigation signals. The calculation results show that the use of 14 navigation satellites (i.e., seven GPS and seven Galileo ones) remarkably improves the success rate under the condition of very short baseline length, compared with the use of seven GPS ones. The numerical reliability of the calculated success rates is strictly tested by examining the tightness of the union and minimum-distance bounds to the rate. These bounds are also shown to be effective to investigate the realization of the high success rates.

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Studies on the Polycondensation Rate of Poly(ethylene 2,6-naphthalate). 2. Polycondensation by Antimony Catalysts

  • 박상순;임승순
    • Bulletin of the Korean Chemical Society
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    • v.16 no.11
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    • pp.1099-1104
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    • 1995
  • The catalyzed polycondensations of bis(2-hydroxyethyl) naphthalate were kinetically investigated in the presence of various antimony compounds as a catalyst. The polymerization were investigated with various ligand types of antimony oxides, various concentrations of antimony triacetate and titanium/antimony mixed catalysts. The time to reach the maximum molecular weight was remarkably changed in each case. With increasing the concentration of antimony acetate, the propagation rate was largely increased, while the degradation rate was slightly decreased. It also can be seen that the propagation and degradation rate were larger influenced by the equimolecular titanium/antimony mixed catalyst than other mixed catalysts. The temperature dependence of bis(2-hydroxyethyl) naphthalate with antimony triacetate also has been studied. From the results, it was found that the propagation rate was less influenced by a temperature change than the degradation rate.

Loading Frequency Dependencies of Cyclic Shear Strength and Elastic Shear Modulus of Reconstituted Clay (재구성 점토의 반복전단강도 및 전단탄성계수의 재하 주파수 의존성)

  • Ishigaki, Shigenao;Yeon, Kyu-Seok;Kim, Yong-Seong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.52 no.3
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    • pp.73-79
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    • 2010
  • In the present study, the loading frequency dependencies of cyclic shear strength and elastic shear modulus of reconstituted clay were examined by performing undrained cyclic triaxial tests and undrained cyclic triaxial tests to determine deformation properties. The result of undrained cyclic triaxial test of reconstituted and saturated clay shows that a faster frequency leads to higher stress amplitude ratio, but when the frequency becomes fast up to a certain point, the stress amplitude ratio will reach its maximum limit and the frequency dependence becomes insignificant. And also, the result of undrained cyclic triaxial deformation test shows a fact that a faster loading frequency leads to higher equivalent shear modules and smaller hysteresis damping ratio, and confirms the frequency dependence of cohesive soil. Meanwhile, the result of the creep test shows that continuing creep is created in the undrained cyclic triaxial test with slow loading frequency rate, and since loading rate becomes slower at the vicinity of the maximum and the minimum deviator stress due to sine wave loading, the vicinity of the maximum and the minimum deviator stress shall be more influenced by creep.

Temperature Dependence of the Deposition Behavior of Yttria-stabilized Zirconia CVD Films: Approach by Charged Cluster Model

  • Hwang, Nong-Moon;Jeon, In-Deok;Latifa Gueroudji;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.38 no.3
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    • pp.218-224
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    • 2001
  • Yttria-stabilized zirconia (YSZ) films were deposited with varying temperatures of ZrCl$_4$between 250~55$0^{\circ}C$ with YCl$_3$and the substrate at 100$0^{\circ}C$. Nanoamperes per square centimeter of the electric current were measured in the reactor during deposition and the current increased with increasing evaporation temperature of ZrCl$_4$. The zirconia nanometer size clusters were captured on the grid membrane near the substrate during the CVD process and observed by transmission electron microscopy (TEM). The deposition rate decreased with increasing evaporation temperature of ZrCl$_4$. A cauliflower-shaped structure was developed at 25$0^{\circ}C$ then gradually changed to a faceted-grain structure above 35$0^{\circ}C$. Dependence of the growth rate and the morphological evolution on the evaporation temperature of ZrCl$_4$was approached by the charged cluster model.

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X-ray Induced Unscheduled DNA Synthesis in Relation to Chromosome Exchange and Mitotic Activity in Established Mammalian Cells (哺乳動物細胞에 있어서 X-線에 의한 回復複製와 染色體交換 및 分裂活動과의 聯關性)

  • Park, Sang-Dai
    • The Korean Journal of Zoology
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    • v.15 no.3
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    • pp.95-100
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    • 1972
  • Dose response and time dependence of unscheduled DNA synthesis induced by X-rays were measured to determine if any correlation exists between unscheduled DNA synthesis, modal chromosome number, chromosome exchange and mitotic activity in four mammalian cell strains. Unscheduled DNA synthesis occurred in all strains studied. The rate was dose-dependent and strain-specific. Only HeLa $S_3$ showed a staturated dose response after 4, 000 R, other cells were linearly proportional to dose increases. Time dependence of unscheduled DNA synthesis was completed within 2 hours after irradiation regardless of cell strains. Unscheduled DNA synthesis was not directly related to modal chromosome number, total exchange rate and mitotic activity. Mitotic activity and chromosome exchange were both dose-dependent, but the rates of them were inversely related.

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Application of a General Gas Electrode Model to Ni-YSZ Symmetric Cells: Humidity and Current Collector Effects

  • Shin, Eui-Chol;Ahn, Pyung-An;Seo, Hyun-Ho;Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.53 no.5
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    • pp.511-520
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    • 2016
  • Electrolyte-supported symmetric Ni-YSZ cermet electrodes of ca. $23{\mu}m$ were prepared by screenprinting and the impedance was measured as a function of humidity from 2% to 90% balanced in $H_2$ at a total flow rate of 50 sccm. The Ni felt current collector of 1 mm thickness exhibited a Gerischer-like gas concentration impedance in the low frequency range, which was similarly observed in the cermet-supported solid oxide cells, while the Pt paste collector exhibited only electrochemical polarization. The electrochemical polarization of both samples was modeled by a non-ideal diffusion-reaction transmission line model including CPEs with ${\alpha}$= 0.5. In the case of the Pt paste collector, all the Bisquert parameters exhibited humidity dependence to the -1/2 power, supporting a non-faradaic chemical reaction mechanism at three phase boundaries. Consequently, the surface diffusivity and reaction rate increased linearly with humidity. Less pronounced humidity dependence and somewhat lower utilization length with an Ni felt collector can be attributed to the diffusion-limited gas flow through the collector.

Reaction Kinetics with Hydrogen and Temperature Dependence of the Hydriding Rate for a Magnesium-Based Nickel Iron Oxide Alloy

  • Song, Myoung Youp;Baek, Sung Hwan;Park, Hye Ryoung
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.463-468
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    • 2012
  • A 71.5 wt%Mg-23.5 wt%Ni-5 wt%$Fe_2O_3$ (Mg-23.5Ni-$5Fe_2O_3$) sample was prepared by a quite simple process, reactive mechanical grinding, and its hydriding and dehydriding properties were then investigated. The reactive mechanical grinding of Mg with Ni and $Fe_2O_3$ is considered to facilitate nucleation and shorten the diffusion distances of the hydrogen atoms. After the hydriding-dehydriding cycling, the Mg-23.5Ni-$5Fe_2O_3$ sample contained $Mg_2Ni$ phase. Expansion and contraction of the hydride-forming materials (Mg and $Mg_2Ni$) with the hydriding and dehydriding reactions are also considered to increase the hydriding and dehydriding rates of the mixture by forming defects and cracks leading to the fragmentation of the particles. The temperature dependence of the hydriding rate of the sample is discussed.

Effective Blocking of Microbial Transcriptional Initiation by dCas9-NG-Mediated CRISPR Interference

  • Kim, Bumjoon;Kim, Hyun Ju;Lee, Sang Jun
    • Journal of Microbiology and Biotechnology
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    • v.30 no.12
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    • pp.1919-1926
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    • 2020
  • CRISPR interference (CRISPRi) has been developed as a transcriptional control tool by inactivating the DNA cleavage ability of Cas9 nucleases to produce dCas9 (deactivated Cas9), and leaving dCas9 the ability to specifically bind to the target DNA sequence. CRISPR/Cas9 technology has limitations in designing target-specific single-guide RNA (sgRNA) due to the dependence of protospacer adjacent motif (PAM) (5'-NGG) for binding target DNAs. Reportedly, Cas9-NG recognizing 5'-NG as the PAM sequence has been constructed by removing the dependence on the last base G of PAM through protein engineering of Cas9. In this study, a dCas9-NG protein was engineered by introducing two active site mutations in Cas9-NG, and its ability to regulate transcription was evaluated in the gal promoter in E. coli. Analysis of cell growth rate, D-galactose consumption rate, and gal transcripts confirmed that dCas9-NG can completely repress the promoter by recognizing DNA targets with PAM of 5'-NGG, NGA, NGC, NGT, and NAG. Our study showed possible PAM sequences for dCas9-NG and provided information on target-specific sgRNA design for regulation of both gene expression and cellular metabolism.