• Title/Summary/Keyword: Rare earth material

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Comparative Analysis of STS contents on the Next Generation Science Textbook and High School Science Textbooks Focused on the Earth Science (차세대 과학 교과서와 기존 과학 교과서의 STS 교육내용 비교 분석 -지구과학 영역을 중심으로-)

  • Hyun, Jiyong;Park, Shingyu;Kim, Jungwook;Chung, Wonwoo
    • Journal of Science Education
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    • v.32 no.2
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    • pp.1-16
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    • 2008
  • The purpose of this study was to analyze about STS contents in the next generation science textbook for 10th grade according to curriculum revision 2007 and high school science textbooks focused on the Earth Science which were published according to the 7th curriculum. The contents of STS were analyzed by the STS topics of Yager(1989), Piel's standard(1981), and student activities by SATIS. The results of this study are the same as follows: 'The next generation science textbook' was shown that 20.9% is STS material amount in average by Yager's standard. 'High school science textbooks' were shown that 11.3% is STS material amount in average. Based on the STS topics by Yager's standard, most of STS content is focused on 'Relativity with local community', 'Application of science' and 'Cooperative work on real problems'. However, there is rare contents such as 'Multiple dimensions of science', 'Practice with decision-making strategies' and 'Evaluation concerned for getting and using information' in the next generation science textbook. In high school science textbooks were shown that 'Applicability of science' is the highest and 'Relativity with local community' is the next high contents. Based on the STS topics by Piel's standard, most of STS contents are focused on 'Environmental quality', 'Space research' and 'National defence' in the next generation science textbook. But high school science textbooks are focused on 'Natural resources' and 'Technology development'. The activities were analyzed by SATIS student activities. The major categories of activities included in the next generation science textbook were 'Investigation', 'Simulation' and 'Data analysis'. But, there were rare activities like 'Roleplaying', 'Research design' and 'Simulation' in high school science textbooks.

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Synthesis of Yba2Cu3O7-y Superconductor using a Low Purity BaCO3 Powder (저 순도 BaCO3 분말을 사용한 Yba2Cu3O7-y 초전도체의 합성)

  • Kim, Chan-Joong;Park, Soon-Dong;Choi, Jung-Suk;Jun, Byung-Hyuk;Moon, Jong-Baik;Lee, Sang-Heon;Sung, Tae-Hyun
    • Journal of Powder Materials
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    • v.15 no.1
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    • pp.6-12
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    • 2008
  • [ $YBa_2Cu_3O_{7-y}$ ](123) powders were synthesized by the solid state reaction method using two different purity $BaCO_3$ powders (99.75% and 99.7% purity) and $Y_2O_3$ (99.9%) and CuO (99.9%) powders. The effect of $BaCO_3$ purity on the formation of a 123 phase and the superconducting properties were investigated. The mixtures of raw powders were calcined at temperature ranges of $800^{\circ}C-880^{\circ}C$ in air and finally made into a single grain samples by a melt processing with top seeding. It was found that a 123 phase was well formed at temperature above $870^{\circ}C$, but the purity effect on the 123 formation was negligible. The single-grain 123 samples prepared from the different $BaCO_3$ powders showed the same $T_c$ value of 90.5 K and similar $J_c$ values about $10^4\;A/cm^2$ at 0 T and 77 K, and $10^3\;A/cm^2$ at 2 T and 77 K. This result indicates that the low purity, cheap price $BaCO_3$ powder can be used as a raw material for the fabrication of single-grain, high-$J_c$ superconducting levitator.

Geochemistry of Precambrian Metamorphic Rocks from Yongin-Anseong Area, the Southernmost Part of Central Gyeonggi Massif (경기육괴 중부 남단(용인-안성지역)에 분포하는 선캠브리아기 변성암류의 지구화학적 특징)

  • 이승구;송용선;증전창정
    • The Journal of the Petrological Society of Korea
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    • v.13 no.3
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    • pp.142-151
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    • 2004
  • The metamorphic rocks of Yongin-Anseong area in Gyeonggi massif are composed of high-grade gneisses and schists which are considered as Precambrian basement, and Jurassic granite which intruded the metamorphic rocks. In this paper, we discuss the geochemical characteristics of metamorphic rocks and granites in this area based on REE and Nd isotope geochemistry. And we also discuss the petrogenetic relationship between metamorphic rocks and granites in this area. Most of Nd model ages (T$\_$DM/$\^$Nd/) from the metamorphic rocks range ca. 2.6Ga~2.9Ga which are correspond to the main crustal formation stage in Gyeonggi massif by Lee et. al. (2003). And Nd model ages show that the source material of quartzofeldspathic gneiss is slightly older than that of biotite banded gneiss. In chondrite-normalized rare earth element pattern, the range of (La/Yb)$\_$N/ value from biotite banded gneiss is 37~136, which shows sharp gradient and suggests that biotite banded gneiss was originated from a strongly fractionated source material. However, that of amphibolite is 4.65~6.64, which shows nearly flattened pattern. Particularly, the chondrite normalized REE patterns from the high-grade metamorphic rocks show the REE geochemisoy of original source material before metamorphism. In addition, the values of (La/Yb)$\_$N/ and Nd model ages of granite are 32~40 and 1.69Ga~2.08Ga, respectively, which suggest that the source material of granite is different from that of Precambrian basement such as biotite banded gneiss and quartzofeldspthic gneiss in the area.

Geochemical Composition of the Continental Crust in Korean Peninsula (한반도 지각암류의 지구화학적 특성)

  • Lee, Seung-Gu;Kim, Dong-Yeon
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.113-128
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    • 2012
  • The chemical composition of the continental crust play an important role in understanding of crustal formation and evolution and quantifying other processes taking place within continental crust. We summarized geochemical data reported in the previous literature for the crustal rocks in the Korean Peninsula and divided their chemical composition into geologic time scale. In the variation diagram normalized by average composition of the upper crustal rocks, the geochemical characteristics of the upper crust during Triassic period is different from those of the upper crustal rocks after Jurassic period or before Precambrian. However, the geochemical characteristics of the Jurassic and Precambrian period are similar each other. Our summarized data indicate that the source material of Triassic upper crust may be different from that of Jurassic or Precambrian upper crust.

Adsorption Characteristic of Rare Earth Metal Ions on 1-Aza-15-Crown-5-Styrene (Hazardous Materials)-DVB Resin (1-Aza-15-Crown-5-Styrene (위험물)-DVB 수지에 의한 희토류 금속 이온들의 흡착 특성)

  • Roh, Gi-Hwan;Kim, Kwan-Chun;Kim, Sun-Hwa;Kim, Joon-Tae
    • Applied Chemistry for Engineering
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    • v.20 no.1
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    • pp.21-27
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    • 2009
  • Resins were synthesized by mixing 1-aza-15-crown-5 macrocyclic ligand attached to styrene (a hazardous material) divinylbenzene (DVB) copolymer with crosslink of 1%, 2%, 5% and 20% by a substitution reaction. The characteristic of these resins was confirmed by the content of chlorine, element analysis, thermogravimetric analysis (TGA), surface area (BET), and IR-spectroscopy. The effects of pH, time, dielectric constant of solvents and crosslink on adsorption of metal ions by the synthetic resin adsorbent were investigated. The metal ion was showed a fast adsorption on the resins above pH 3. The optimum equilibrium time for adsorption of metallic ions was about two hours. The adsorption selectivity determined in ethanol was in increasing order of uranium ($UO_2^{2+}$) > manganese ($Mn^{2+}$) > praseodymium ($Pr^{3+}$). The adsorption was in the order of 1%, 2%, 5%, and 20% crosslink resin and adsorption of resin decreased in proportion to the order of dielectric constant of solvents.

A study on the changes in attractive force of magnetic attachments for overdenture

  • Leem, Han-Wool;Cho, In-Ho;Lee, Jong-Hyuk;Choi, Yu-Sung
    • The Journal of Advanced Prosthodontics
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    • v.8 no.1
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    • pp.9-15
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    • 2016
  • PURPOSE. Although magnetic attachment is used frequently for overdenture, it is reported that attractive force can be decreased by abrasion and corrosion. The purpose of this study was to establish the clinical basis about considerations and long term prognosis of overdenture using magnetic attachments by investigating the change in attractive force of magnetic attachment applied to the patients. MATERIALS AND METHODS. Among the patients treated with overdenture using magnetic attachments in Dankook University Dental Hospital, attractive force records of 61 magnetic attachments of 20 subjects who re-visited from July 2013 to June 2014 were analyzed. Dental magnet tester (Aichi Micro Intelligent Co., Aichi, Japan) was used for measurement. The magnetic attachments used in this study were Magfit IP-B Flat, Magfit DX400, Magfit DX600 and Magfit DX800 (Aichi Steel Co., Aichi, Japan) filled with Neodymium (NdFeB), a rare-earth magnet. RESULTS. Reduction ratio of attractive force had no significant correlation with conditional variables to which attachments were applied, and was higher when the maintenance period was longer (P<.05, r=.361). Reduction ratio of attractive force was significantly higher in the subject group in which attachments were used over 9 years than within 9 years (P<.05). Furthermore, 16.39% of total magnetic attachments showed detachment of keeper or assembly. CONCLUSION. Attractive force of magnetic attachment is maintained regardless of conditional variables and reduction ratio increased as the maintenance period became longer. Further study on adhesive material, attachment method and design improvement to prevent detachment of magnetic attachment is needed.

Analysis of phase formation behavior of YSZ-based composites according to rare earth and other oxide doping amounts (희토류 및 기타 산화물 Doping 양에 따른 YSZ 기반 복합소재의 상형성 거동 분석)

  • Choi, Yong Seok;Lee, Gye Won;Jeon, Chang Woo;Nahm, Sahn;Oh, Yoon Suk
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.368-375
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    • 2022
  • YSZ (Yttria Stabilized Zirconia) is used as a thermal barrier coating material for gas turbines due to its low thermal conductivity and high fracture toughness. However, the operating temperature of the gas turbine is rising according to the market demand, and the problem that the coating layer of YSZ is peeled off due to the volume change due to the phase transformation at a high temperature of 1400℃ or higher is emerging. To solve this problem, various studies have been carried out to have phase stability, low thermal conductivity, and high fracture toughness in a high temperature environment of 1400℃ or higher by doping trivalent and tetravalent oxides to YSZ. In this study, the monoclinic phase formation behavior and crystallinity were comparatively analyzed according to the total doping amount of oxides by controlling the doping amounts of Sc2O3 and Gd2O3, which are trivalent oxides, and TiO2, which are tetravalent oxides, in YSZ. Through comparative analysis of monoclinic phase formation and crystallinity, the thermal conductivity of the thermal barrier coating layer according to the amount of doping was predicted.

Economic evaluation of thorium oxide production from monazite using alkaline fusion method

  • Udayakumar, Sanjith;Baharun, Norlia;Rezan, Sheikh Abdul;Ismail, Aznan Fazli;Takip, Khaironie Mohamed
    • Nuclear Engineering and Technology
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    • v.53 no.7
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    • pp.2418-2425
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    • 2021
  • Monazite is a phosphate mineral that contains thorium (Th) and rare earth elements. The Th concentration in monazite can be as high as 500 ppm, and it has the potential to be used as fuel in the nuclear power system. Therefore, this study aimed to conduct the techno-economic analysis (TEA) of Th extraction in the form of thorium oxide (ThO2) from monazite. Th can be extracted from monazite through an alkaline fusion method. The TEA of ThO2 production studied parameters, including raw materials, equipment costs, total plant direct and indirect costs, and direct fixed capital cost. These parameters were calculated for the production of 0.5, 1, and 10 ton ThO2 per batch. The TEA study revealed that the highest production cost was ascribed to installed equipment. Furthermore, the highest return on investment (ROI) of 21.92% was achieved for extraction of 1 ton/batch of ThO2, with a payback time of 4.56 years. With further increase in ThO2 production to 10 ton/batch, the ROI was decreased to 5.37%. This is mainly due to a significant increase in the total capital investment with increasing ThO2 production scale. The minimum unit production cost was achieved for 1 ton ThO2/batch equal to 335.79 $/Kg ThO2.

Effects of surface-roughness and -oxidation of REBCO conductor on turn-to-turn contact resistance

  • Y.S., Chae;H.M., Kim;Y.S., Yoon;T.W., Kim;J.H., Kim;S.H., Lee
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.4
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    • pp.40-45
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    • 2022
  • The electrical/thermal stabilities and magnetic field controllability of a no-insulation (NI) high-temperature superconducting magnet are characterized by contact resistance between turn-to-turn layers, and the contact resistance characteristics are determined by properties of conductor surface and winding tension. In order to accurately predict the electromagnetic characteristics of the NI coil in a design stage, it is necessary to control the contact resistance characteristics within the design target parameters. In this paper, the contact resistance and critical current characteristics of a rare-earth barium copper oxide (REBCO) conductor were measured to analyze the effects of surface treatment conditions (roughness and oxidation level) of the copper stabilizer layer in REBCO conductor. The test samples with different surface roughness and oxidation levels were fabricated and conductor surface analysis was performed using scanning electron microscope, alpha step surface profiler and energy dispersive X-ray spectroscopy. Moreover, the contact resistance and critical current characteristics of the samples were measured using the four-terminal method in a liquid nitrogen impregnated cooling environment. Compared with as-received REBCO conductor sample, the contact resistance values of the REBCO conductors, which were post-treated by the scratch and oxidation of the surface of the copper stabilizer layer, tended to increase, and the critical current values were decreased under certain roughness and oxidation conditions.

Occurrence of Radioactive Minerals and U-Th Geochemistry of the Weolaksan and Sokrisan Granite in the Central Ogcheon Belt (중부 옥천대 월악산과 속리산 화강암의 방사성 광물 산출상태와 U-Th 지구화학)

  • Hwang, Jeong
    • The Journal of Engineering Geology
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    • v.32 no.2
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    • pp.295-310
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    • 2022
  • The Weolaksan and Sokrisan granites yield high SiO2 and alkali (Na2O+K2O) contents and low CaO and P2O5 contents. The Al saturation index is ≥1.3, which indicates that the granites are peraluminous. The mean U and Th contents are 8.3 and 39.3 ppm, respectively, higher than typical Mesozoic granites in South Korea and about twice the global mean for granitic rocks. The causes of such high radioelement contents are related to high degrees of fractionation and the crustal origin of the granites. U- and Thbearing radioactive minerals occur in the granites include zircon, thorite, monazite, xenotime, fergusonite and uraninite. The fact that the mean Th/U ratio of the granites (5.4) is similar to the global average crustal value suggests that the radioelement contents of granite were controlled by the crustal source material. Given the correlation of Zr, Y, and heavy rare earth elements for U and Th, radioelements are more likely hosted by xenotime than zircon and monazite.