• Journal of the Korean Chemical Society
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• v.33 no.5
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• pp.468-476
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• 1989

Kineties for the reactions of pyridines with 1-anthracenesulfonyl chloride (1-ASC) and 3-phenanthrenesulfonyl chloride (3-PSC) was investigated in methanol as solvent. Structural variation in pyridine followed $Br{\o}$ nsted and Hammett relations for both 1-ASC and 3-PSC; the corresponding coefficients, {\beta}\;and\;{\rho}\;at\;20^{\circ}C$ were 0.55, -3.5 for 1-ASC, and 0.43, -2.6 for 3-PSC respectively. Reactivity-selectivity principle was checked in competition system 1-ASC/3-PSC. As a result, this principle was found to hold at experimental temperatures, whereas to break down over in the range of isoselective temperature ($34.3^{\circ}C$). Judging from the above results and activation parameters, we concluded that these reactions proceeded by synchronous $S_n2$ mechanism in rate-determining step.

• Korean Journal of Optics and Photonics
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• v.17 no.3
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• pp.285-289
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• 2006

A novel alignment-free micro-optic MZI filter has been demonstrated. The filter is composed of two fiber-pigtailed collimators and a beam-splittingplate with a periodically etched stripe pattern. We fabricated the plate through a standard lithographic formulation process by using a pyrex substrate glass with SU-8 resist coating on its one of the surfaces. The maximum insertion loss of the implemented filter was less than 2 dB over 1000 nm to 1600 nm and the extinction ratio was larger than 33 dB. The measured PDL within the 3-dB pass band of the filter was less than 0.15dB and the maximum extinction ratio variation was less than 2 dB even when the worst alignment error occured.

• Journal of Korea Water Resources Association
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• v.53 no.6
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• pp.417-425
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• 2020

In order to predict and prevent hydrological disasters such as flood, it is necessary to accurately estimate rainfall. In this paper, an areal average rainfall estimation method using multiple elevation observation data of an electromagnetic wave rain gauge is presented. The small electromagnetic rain gauge system is a very small precipitation radar that operates at K-band with dual-polarization technology for very short distance observation. The areal average rainfall estimation method is based on the assumption that the variation in rainfall over the observation range is small because the observation distance and time are very short. The proposed method has been evaluated by comparing with ground instruments such as tipping-bucket rain gauges and a Parsivel. The evaluation results show that the methodology works fairly well for the rainfall events which are shown here.

• Bulletin of the Korean Space Science Society
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• 2009.10a
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• pp.28.4-29
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• 2009

The 'Amon-Ra' instrument of the proposed 'EARTHSHINE' satellite is a dual (i.e. imaging and energy) channel instrument for monitoring the total solar irradiance (TSI) and the Earth's irradiance at around the L1 halo orbit. Earlier studies for this instrument include, but not limited to, design and construction of breadboard Amon-Ra imaging channel, stray light suppression and system performance computation using Integrated Ray Tracing (IRT) technique. The Amon-Ra instrument is required to produce 0.3% in uncertainty for both Sunlight and Earthlight measurement. In this study, we report accurate estimation of the output electric signal derived from the orbital variation of radiant exitance from the Sun and the Earth arriving at the aperture and detector plane of the Amon-Ra. For this, orbital irradiance are computed analytically first and then confirmed by simulation using Integrated Ray Tracing (IRT) model. Specially, the results show the arriving power at the bolometer detector surface is $1.24{\mu}W$ for the Sunlight and $1.28{\mu}W$ for the Earthlight, producing the output signal pulses of 34.31 mV and 35.47 mV respectively. These results demonstrate successfully that the arriving radiative power is well within the bolometer detector dynamic range and, therefore, the proposed detector can be used for the in-orbit measurement sequence. We discuss the computational details and implications as well as the simulation results.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.49 no.5
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• pp.37-42
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• 2012

In this paper, a new charge pump is proposed to reduce the timing mismatch in the conventional current-steering charge pumps. Conventional current-steering charge pumps used NMOS input stages both for UP and DOWN signals, which resulted in different numbers of stage for UP and DOWN delay paths. The proposed charge pump has equalized the numbers of stages for UP and DOWN signals by using a PMOS stage for the DOWN signal. The simulation results show that the conventional current-steering charge pump has 14ns and 6ns for optimized timing mismatches between UP and DOWN signals for turn-on and turn-off, respectively. On the other hand, the proposed charge pump has improved timing mismatches of 6ns and 5ns for turn-on and turn-off, respectively. As a result, the reference spurs are reduced from -26dBc to -39dBc for the proposed charge pump. The proposed charge pump was designed by using $0.18{\mu}m$ CMOS technology. The measurement results show that the maximum variation of the charging and discharging current over the charge pump output voltage range of 0.3~1.5V is approximately 1.5%.

• Journal of the Korean Vacuum Society
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• v.17 no.4
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• pp.341-345
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• 2008

The SiOC film of carbon centered system was prepared using bistrimethylsilylmethane and oxygen mixed precursor by the chemical vapor deposition. The chemical properties of the SiOC film were analyzed by the contact anlge and FTIR spectra. The dielectric constant of the deposited films decreased after annealing process, and the correlation between the increasing the BTMSM/$O_2$ flow rate ratio and the dielectric constant did not exist. However, the trend of increasing or decreasing of the dielectric constant repeated and there is the correlation ship between the dielectric constant and the Si-O-C bond in the range of $950{\sim}1200\;cm^{-1}$. The dielectric constant decreased between samples with the chemical shift. The lowest dielectric constant was 1.65 at the sample, which was observed the chemical shift.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.6 no.1
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• pp.89-98
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• 2002

Optical current sensor and optical voltage sensor modules were designed and fabricated to improve measurement error and insulation in automatic power distributor By using Faraday effect, optical current sensor with an $\alpha$-iron core was designed and fabricated to minimize current induction of the other phase and was optimized to maintain linearity. Optical voltage sensor was fabricated owing to the pockets effect and adopted spatial electric field type because of small room in an automatic power distributor. To connect a distributor with an external terminal for signal processing, optical multi connector was designed, fabricated and tested for coupling loss and gas leakage. The linearity of optical current sensor for applied current maintains variation of smaller than 2.5% for applied current range from 20A to 700A. The linearity of optical voltage sensor was smaller than 1% for appling voltage from 6.6kV to 19.8kV. Since the measured characteristics are good, these devices can be considered as being applicable in practice.

• Fire Science and Engineering
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• v.24 no.1
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• pp.40-45
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• 2010

Asymmetric Slimflor Beam had been unveiled with Thor beam (Hat beam) in Sweden since the late 1970s and had been developed by British Steen and SCI. In the major advanced countries in Europe after the early 1990s have interested in and developed this method, it has been concrened as the absence of hot-rolled section steel in the United Kingdom and welded of asymmetric section steel in Finland in the 2000s. It can be increase total floor area about 10%, save the interior and exterior materials, reduce the waste through reduction of the floor height. And it has more excellent fire resistance performance because less exposed than a regular composite steel beam in fire. This study is purpose that, a fire resistance performance of the Asymmetric Slimflor Beam in fire, it compared the temperature range with deflection of structure by fire behavior and load ratio of structure through change the shape of the steel cross-section in standard fire condition.

• Korean Journal of Remote Sensing
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• v.23 no.6
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• pp.501-506
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• 2007

Basic research is conducted to identify a target using corner reflectors which are commonly used in calibration of synthetic aperture radar (SAR) systems. At first, an omni-directional reflector is fabricated by combining four 15-cm rectangular trihedral corner reflectors. Then, its radar cross section (RCS) characteristics are measured at C-band (5.3 GHz) for vv-, hh-, hv-, and vh- polarizations at a range of horizontal angle, $-90^{\circ}{\le}{\phi}{\le}90^{\circ}$. The measured RCS angular variation of the omni-directional reflector is much smaller for vv-polarization than other polarizations, and the difference between the maximum and minimum RCSs for vv-polarization is about 8 dB. Peak RCS values are shown at $0^{\circ}$ (normal to plates) and $45^{\circ}$ (direction of bore sight). It is shown that the measurements agree quite well with numerical simulation and theoretical computation results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.30 no.1B
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• pp.81-87
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• 2010

On the SSang-chi gauging station, the discharge had been measured by the rod float method for the past twelve years. However the shifts of the rating curves are too big to be accepted. The major factors of rating curve variation were reviewed for shift analysis. To estimate the discharge measured by rod float method, two cross sections and their stages are generally required. But, the rating curves had been derived only with the observed depth of gauging station since the cross sections were not available. To correct the errors, the reference rating curve was developed. In this study, the water surface slopes of the curve were simulated by RMA2 model. The historical rating curves were re-developed by the calculated discharges on the base of the water surfaces. The results show that the range of fluctuation decreased and rating curves in recent years are physically reasonable.