• 반도체디스플레이기술학회지
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• 제20권4호
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• pp.72-77
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• 2021

The radial distribution of etch rate was analyzed using the ion energy flux model in VHF-CCP. In order to exclude the effects of polymer passivation and F radical depletion on the etching. The experiment was performed in Ar/SF6 plasma with an SF6 molar ratio of 80% of operating pressure 10 and 20 mTorr. The radial distribution of Ar/SF6 plasma was diagnosed with RF compensated Langmuir Probe(cLP) and Retarding Field Energy Analyzer(RFEA). The radial distribution of ion energy flux was calculated with Bohm current times the sheath voltage which is determined by the potential difference between the plasma space potential (measured by cLP) and the surface floating potential (by RFEA). To analyze the etch rate uniformity, Si coupon samples were etched under the same condition. The ion energy flux and the etch rate show a close correlation of more than 0.94 of R² value. It means that the etch rate distribution is explained by the ion energy flux.

• 유통과학연구
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• 제12권10호
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• pp.5-9
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• 2014

Purpose - This paper aims to critically examine capital market developments in India before and after liberalization. Research design, data, and methodology - The paper examines the Indian capital market from its inception to the latest developments related to both primary and secondary markets, and also discusses recent initiatives of capital markets to enhance the expected level of services to the investor community. It also sheds light on the regulatory framework for investor protection. Results - The study further highlights the future roadmap for the radical development of the Indian capital market. The paper identifies the various initial obstacles and intricacies that affect the smooth functioning of the Indian capital markets. Hence, the paper articulates that these concerns should be addressed by the regulatory authorities and at the policy level at the earliest for further strengthening the capital markets in the interests of the economy in general and retail investors in particular. Conclusion - This is a topic of utmost contemporary importance to worldwide national economies, and calls for novel methods and techniques in dealing effectively with the menace facing capital markets.

• Macromolecular Research
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• 제17권12호
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• pp.1003-1009
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• 2009

Copolymers of N-vinylpyrrolidone (NVP) comonomer with styrene (St), hydroxypropyl methacrylate (HPMA) and carboxyphenyl maleimide (CPMI) were synthesized by free radical polymerization using 2,2'-azobisisobutyronitrile (AIBN) initiator in 1,4-dioxane solvent. The copolymers formed were characterized by FTIR, $^1H$ NMR and $^{13}C$ NMR techniques and their thermal properties were studied by DSC and TGA. Copolymer composition was determined by $^1H$ NMR and/or by elemental analysis and monomer reactivity ratios (MRR) were estimated by the linear methods of Kelen-Tudos (K-T) and extended Kelen-Tudos (EK-T) and the non-linear approach. Copolymers of St and HPMA with NVP formed blocks of one of the monomer units, whereas alternating copolymers were obtained in CPMI-NVP, depending upon the side chain substitution. The MRR values are discussed in terms of monomer structural properties such as electronegativity and electron delocalization. The sequence distribution of monomers in the copolymers was studied by statistical method based on the average reactivity ratios obtained by EK-T method.

• Journal of the Korean Wood Science and Technology
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• 제42권2호
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• pp.119-129
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• 2014

This work undertook to prepare nanofibers of cellulose nanofibrils (CNF)/polyvinyl alcohol (PVA) composite by electrospinning, and characterize the electrospun composite nanofibers. Different contents of CNFs isolated from hardwood bleached kraft pulp (HW-BKP) by 2,2,6,6-tetramethylpiperidine-1-oxy radical (TEMPO)-mediated oxidation were suspended in aqueous polyvinyl alcohol (PVA) solution, and then electrospun into CNF/PVA composite nanofibers. The morphology and dimension of CNFs were characterized by transmission electron microscopy (TEM), which revealed that CNFs were fibrillated form with the diameter of about $7.07{\pm}0.99$ nm. Morphology of the electrospun nanofiber observed by field-emission scanning electron microscopy (FE-SEM) showed that uniform CNF/PVA composite nanofibers were manufactured at 1~3% CNF contents while many beads were observed at 5% CNF level. Both the viscosity of CNF/PVA solution and diameter of the electrospun nanofiber decreased with an increase in CNF content. The diameter and its distribution of the electrospun nanofibers helped explain the differences observed in their morphology. These results show that the electrospinning method was successful in preparing uniform CNF/PVA nanofibers, indicating a great potential for manufacturing consistent and reliable cellulose-based nanofibrils for scaffolds in future applications.

• Bulletin of the Korean Chemical Society
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• 제35권10호
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• pp.3001-3004
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• 2014

A series of hydroxyl-derivatized quaternized polymers were successfully synthesized by atom transfer radical polymerization (ATRP) and Cu(I)-catalyzed 1,3-dipolar cycloaddition of azide and alkynes (click chemistry), followed by quaternization reactions. ATRP was employed to synthesize poly(2-hydroxyethyl methacrylate) (PHEMA), followed by introduction of alkyne groups using pentynoic acid, leading to HEMA-Alkyne. 2-Azido-1-ethanol and 3-azido-1-propanol were combined with the HEMA-Alkyne backbone via click reaction, resulting in triazole-ring containing hydroxyl-derivatized polymers. Quaternization reactions with methyl iodide were conducted on the triazole ring of each polymer. Molecular weight, molecular weight distribution, and the degree of quaternization (DQ) were determined by gel permeation chromatography (GPC) and $^1H$ NMR spectroscopy. The average molecular weight ($M_n$) of the resulting polymers ranged from $5.9{\times}10^4$ to $1.05{\times}10^5g/mol$ depending on the molecular architecture. The molecular weight distribution was low ($M_w/M_n$ = 1.26-1.38). The transmission spectra of the 0.1 wt % aqueous solutions of the resulting quaternized polymers at 650 nm were measured as a function of temperature. Results showed that the upper critical solution temperature (UCST) could be finely controlled by the level of DQ.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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• pp.91-96
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• 2004

Simultaneous CH and OH planar laser induced fluorescence(PLIF) and stereoscopic particle image velocimetry (PIV) measurements have been developed to investigate the local flame structure of turbulent premixed flames. The developed simultaneous two radical concentrations and three component velocity measurements on a two-dimensional plane was applied for relatively high Reynolds number turbulent premixed flames in a swirl stabilized combustor. All measurements were conducted for methane-air premixed flames in the corrugated flamelets regime. Strong three-dimensional fluctuation implies that misunderstanding of the flame/turbulent interactions would be caused by the analysis of two-component velocity distribution in a cross section. Furthermore, comparisons of CH-OH PLIF and three-component velocity field show that the burned gases not always have high-speed velocity in relatively high Reynolds number turbulent premixed flame. The Reynolds number dependence of the flame front was clearly captured by the simultaneous CH-OH PLIF and stereoscopic PIV measurements.

• 한국연소학회지
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• 제14권1호
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• pp.19-24
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• 2009

A novel low NOx oil burner of 0.7 MW (for a 1 ton steam/hr industrial boiler) was designed and tested to investigate the combustion characteristics through in-flame measurement and flue gas analysis. Flame shape was observed by CCD camera and $CH^*/{C_2}^*$ radical distribution in the flame were observed, along with measurement of flue gas composition such as NOx and CO, for various heat inputs, excess airs and pressure of the fuel spary nozzles. The flame showed the two-zone structure: fuel-rich and fuel-lean zone, which was very favorable for the low-NOx combustion, and the NOx emission for haevy oil combustion was significantly reduced to < 150 ppm at 4 % $O_2$, compared with the NOx level of a conventional heavy oil burner.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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• pp.7-14
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• 2004

The lift-off characteristics of the triple flame have been studied experimentally with various mean velocities and concentration gradients using a multi-slot burner, which can control the concentration gradient and the mean velocity independently, Lift-off height, axial maximum velocity, flame temperature, and some other characteristics were examined for methane and propane flame, It was found that minimum values of the lift-off heights exist at a certain concentration gradient for constant mean velocity, and this result implies that the propagation velocity has a maximum value at this condition, OH radical distribution was measured with LIF method and velocity variation along streamline was measured with PlV system. In addition maximum temperature along streamline was measured with CARS system. The intensity of the diffusion flame affects on the propagation velocity of triple flame in the region of very weak concentration gradient.

• 한국멀티미디어학회논문지
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• 제10권7호
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• pp.827-837
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• 2007

기존의 색상 기반의 Mean Shift 알고리즘을 이용한 객체추적 알고리즘은 초기 색상 정보가 사라질 경우 정확한 객체추적을 수행할 수 없다. 본 논문은 객체의 색상이 변할 때 색상 정보를 변경하여 정확히 추적하는 알고리즘을 제안한다. 제안 알고리즘은 현재의 위치를 중심으로 다음 객체 위치에 해당하는 밀도가 가장 높은 위치를 Mean Shift알고리즘으로 구하고, 바꿔 색상 정보를 변경하는 반복적인 기법을 사용한다. 이를 통해 처음 설정한 객체의 색상이 바뀌거나 사라지더라도 정확한 객체추적을 할 수 있게 되었다. 본 논문에서는 제안 알고리즘을 구현하고, 실험 결과로 성능을 입증한다.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 추계학술대회 논문집
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• pp.102-103
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• 2004

Simultaneous CH and OH planar laser induced fluorescence(PLIF) and stereoscopic particle image velocimetry(PIV) measurements have been developed to investigate the local flame structure of turbulent premixed flames. The developed simultaneous two radical concentrations and three component velocity measurements on a two-dimensional plane was applied for relatively high Renolds number turbulent premixed flames in a swirl stabilized combustor. All measurements were conducted for methane-air premixed flames in the corrugated flamelets regime. Strong three-dimensional fluctuation implies that misunderstanding of the flame/turbulent interactions would be caused by the analysis of two-component velocity distribution in a cross section. Furthermore, comparisons of CH-OH PLIF and three-component velocity field show that the burned gases not always have high-speed velocity in relatively high Renolds number turbulent premixed flame.