• Economic and Environmental Geology
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• v.39 no.1 s.176
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• pp.39-51
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• 2006

Rare earth elements(REEs) in transgressive shelf core sediments were analysed to identify constraints of REE distribution patterns and sediment provenances in the northern East China Sea(ECS). Sediments of Chinese and Korean rivers, such as Huanghe and Yangtz rivers, Keum and Yeongsan rivers that supply sediments to the northern ECS, were also analysed to figure out their typical REE distribution patterns. The distribution patterns of Chinese and Korean river sediments, which are normalized with upper continental crust (UCC) REE values, appear to be enriched in middle rare earth elements (MREEs) in Chinese river sediments, whereas in light rare earth elements (LREEs) in Korean river sediments. We assign the MREE-enriched convex-type distribution pattern in Chinese river sediments as 'C-type', and the LREE-enriched linearly decreasing pattern in Korean river sediments as 'D-type'. A major constraint of the REE concentration in northern ECS core sediments is interpreted to be LREE-enriched monazite $((Ce,\;La)PO_4)$ that is ubiquitous in and around the study area. Meanwhile, the distribution pattern of northern ECS sediments appears to be between the C-type and the D-type. We suggest that the nothern ECS sediments are the mixture of China and Korea riverine sediments that have been accumulated in paleo-river mouth, paleo-coast, and present-day shelf environment as well.

• Ocean and Polar Research
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• v.36 no.4
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• pp.383-394
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• 2014

The surface sediments from the manganese nodule exploration area of Korea in the Clarion-Clipperton fracture zone were investigated to understand the resource potential of and emplacement mechanism for rare earth elements (REEs). The sediments are categorized into three lithological units (Unit I, II and III from top to bottom), but into two groups (Unit I/II and Unit III) based on the distribution pattern of REEs. The distribution pattern of REEs in Unit I/II is similar to that of Post-Archean Australian Shale (PAAS), but shows a negative Ce anomaly and enrichment in heavy REEs (HREEs). In Unit III, the HREE enrichment and Ce anomaly is much more remarkable than Unit I/II when normalized to PAAS, which are interpreted as resulting from the absorption of REEs from seawater by Fe oxyhydroxides that were transported along the buoyant plume from remotely-located hydrothermal vents. It is supported by the PAAS-normalized REE pattern of Unit III which is similar to those of seawater and East Pacific Rise sediments. Meanwhile, the PAAS-normalized REE pattern of Unit I/II is explained by the 4:1 mixing of terrestrial eolian sediment and Unit III from each, indicating the much smaller contribution of hydrothermal origin material to Unit I/II. The studied sediments have the potentiality of a low-grade and large tonnage REE resource. However, the mining of REE-bearing sediment needs a large size extra collecting, lifting and treatment system to dress and refine low-grade sediments if the sediment is exploited with manganese nodules. It is economically infeasible to develop low-grade REE sediments at this moment in time because the exploitation of REE-bearing sediments with manganese nodules increase the mining cost.

• Journal of the Korean earth science society
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• v.33 no.6
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• pp.481-496
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• 2012

REE, major and trace elements, and Sr-Nd isotopic ratios of surface sediments around Jeju Island were analyzed for identifying the origin of the sediments. The Chemical Index of Alteration (CIA) between 44.2 to 68.9 (av. 59.4) shows a similarity with the Huanghe sediment. The most sediments found within the study areas show a very similar chondrite-normalized REE pattern that has enriched LREE ($La_{(N)}/Sm_{(N)}$ >3) and small negative Eu anomaly, typically of average shales. The UCC-nornalized REE patterns of the southwestern offshore sediment samples show a very similar pattem with the Changjiang sediment with enriched in most REE and more convex REE pattern than those of the Huanghe and Keum rivers sediments, which indicates that the Changjiang River's suspended sediments have been transported into the western part of Jeju Island. The $^{87}Sr/^{86}Sr$ isotopic ratios vs ${\varepsilon}_{Nd}(0)$ values were thus used as a tracer to discriminate the provenance of sediments in the study area. Based on the discriminated diagram, it clearly showed that most sediments in the western and northwestern part were closely plotted with sediments of the Huanghe River. However, the sediments in the southwestern part near the Changjianf estuary were closely plotted with submerged delta sediments of the Changjiang River. In contrast, the sediment samples of the northeastern part showed discriminative figures from those of the Chinese rivers. It suggests that sediments around Jeju Island must be originated from diverse sources.

• Analytical Science and Technology
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• v.20 no.6
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• pp.468-473
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• 2007

The chemical composition distribution of the surface samples collected from the loess plateau in China were estimated. Major elements concentration distribution difference between 10 different sampling site were not found except sample 3. This sample had higher contents of Ca, Mg, LOI and lower contents of Si, Fe, P, Na, Ti. And also, minor element contents such as Ba, Cr, Nb, Pb, Rb, Zr, V were lower than other samples. UCC-normalized abundances of the most elements were within $0.5-1.5{\times}UCC$ and Cr showed enrichment aspect. Rare-earth element (REE) analysis results showed light REE enriched pattern compared to heavy REE with negative Eu anomaly in condrite-normalized REE pattern.

• Bulletin of the Korean Chemical Society
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• v.2 no.3
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• pp.96-104
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• 1981

(1) The flow data of f (stress) and ${\dot{s}$ (strain rate) for Fe and Ti alloys were plotted in the form of f vs. -ln ${\dot{s}$ by using the literature values. (2) The plot showed two distinct patterns A and B; Pattern A is a straight line with a negative slope, and Pattern B is a curve of concave upward. (3) According to Kim and Ree's generalized theory of plastic deformation, pattern A & B belong to Case 1 and 2, respectively; in Case 1, only one kind of flow units acts in the deformation, and in Case 2, two kinds flow units act, and stress is expressed by $f={X_1f_1}+{X_2f_2}$where $f_1\;and\;f_2$ are the stresses acting on the flow units of kind 1 and 2, respectively, and $X_1,\;X_2$ are the fractions of the surface area occupied by the two kinds of flow units; $f_j=(1/{\alpha}_j) sinh^{-1}\;{\beta}_j{{\dot{s}}\;(j=1\;or\;2)$, where $1/{\alpha}_j\;and\;{\beta}_j$ are proportional to the shear modulus and relaxation time, respectively. (4) We found that grain-boundary flow units only act in the deformation of Fe and Ti alloys whereas dislocation flow units do not show any appreciable contribution. (5) The deformations of Fe and Ti alloys belong generally to pattern A (Case 1) and B (Case 2), respectively. (6) By applying the equations, f=$(1/{\alpha}_{g1}) sinh^-1({\beta}_{g1}{\dot{s}}$) and $f=(X_{g1}/{\alpha}_{g1})sinh^{-1}({\beta}_{g1}{\dot{s}})+ (X_{g2}/{\alpha}_{g2})\;shih^{-1}({\beta}_{g2}{\dot{s}})$ to the flow data of Fe and Ti alloys, the parametric values of $x_{gj}/{\alpha}_{gj}\;and\;{\beta}_{gs}(j=1\;or\;2)$ were determined, here the subscript g signifies a grain-boundary flow unit. (7) From the values of ($({\beta}_gj)^{-1}$) at different temperatures, the activation enthalpy ${\Delta}H_{gj}^{\neq}$ of deformation due to flow unit gj was determined, ($({\beta}_gj)^{-1}$) being proportional to , the jumping frequency (the rate constant) of flow unit gj. The ${\Delta}H_{gj}\;^{\neq}$ agreed very well with ${\Delta}H_{gj}\;^{\neq}$ (self-diff) of the element j whose diffusion in the sample is a critical step for the deformation as proposed by Kim-Ree's theory (Refer to Tables 3 and 4). (8) The fact, ${\Delta}H_{gj}\;^{\neq}={\Delta}H_{j}\;^{\neq}$ (self-diff), justifies the Kim-Ree theory and their method for determining activation enthalpies for deformation. (9) A linear relation between ${\beta}^{-1}$ and carbon content [C] in hot-rolled steel was observed, i.e., In ${\beta}^{-1}$ = -50.2 [C] - 40.3. This equation explains very well the experimental facts observed with regard to the deformation of hot-rolled steel..

• Economic and Environmental Geology
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• v.29 no.5
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• pp.545-559
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• 1996

Rare metal (Nb-Zr-REE) ore deposits are located in the Chungju area. Geotectonically, the rare metal ore deposits are situated in the transitional zone between Kyeonggi massif and Okcheon belt. The rare metal deposits are distributed in Kyemyeongsan Formation which consist of schist and alkaline igneous rocks. Alkali granite has suffered extensive post-magmatic metasomatism and hydrothermal processes. The ore contains mainly Ce-La, Ta-Nb, Y, Y-Nd, Nd-Th group minerals. More than 15 RE and REE minerals are found in the ore deposits. Allanite, one of the Ce-La rich REE minerals belonging to the epidote group, is the most common mineral in the studied area. The allanite- bearing rocks may be devided into seven types by features of occurrence and mineral associations; zircon type (ZT), allanite-vein type (AT), feldspar type (KT), fluorite type (FT), quartz-mica type (QT), iron-oxide type (MT), and amphibole type (HT). The allanite veins (AT) and zircon rich rocks (ZT) contain the highest total REE contents. Differences in REE abundance can be interpreted in terms of varying portions of magmatic hydrothermal fluid. Petrographical and chemical data are presented for allanites which were collected from different types. The allanites show wide variations in optical properties, due in part to differences in their chemical composition (depending on the types) and to the degree of crystallinity of the individual specimens. Allanite metamicts in biotite are generally surrounded by well developed pleochroic haloes. Usually, allanite is accompanied by zircon and other REE-bearing minerals. CaO and total REE contents $({\sum}RE_2O_3)$ range from 9.29 to 18.79% and 11.66 to 26.31%, respectively. Also, SiO, (28.87~32.61%), $Al_2O_3$ (8.30~16.88%), and $Fc_2O_3$ (16.74~24.38%) contents show varying contents from type to type. The ${\sum}RE_2O_3$ of allanite has positive relationships with $Fe_2O_3$ and negative relaton with CaO, $SiO_2$, and $Al_2O_3$ Backscattered electron microscope images (BEl) of allanite shows that the its mineral composition and texture is very complex. The allanite-bearing hosts show distinct light REE enrichment with strong negative Eu anomaly except for HI. The HT has an almost flat REE distribution pattern with a small negative Eu anomaly. The chemical variation of the allanites with occurrences and mineral association can be related to condition of temperature and oxidation states in precipitation environment.

• Journal of the Korean Operations Research and Management Science Society
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• v.5 no.1
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• pp.53-59
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• 1980

An order level inventory model is developed for deteriorating items. The demand during prescribed scheduling period is constant and deterministic in which the demand follows power pattern. Deterioration is assumed to be a constant fraction of the on hand inventory. The expression for the optimal order level is developed and an example is given to illustrate the model.

• Korean Journal of Community Nutrition
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• v.9 no.3
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• pp.285-291
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• 2004

The purpose of this study was to compare the energy expenditure and energy intake of normal-weight and overweight Korean adults. We recruited 242 adults to determine resting energy expenditure, physical activity and energy intake. Resting energy expenditure was measured by indirect calorimetry. Energy intake for consecutive two days was assessed by 24 hour recall method. Daily activity pattern for 24 hour was collected from each subject. Body weight, lean body mass and percentage body fat were measured by INBODY 3.0. The subject were divided into normal ($20\leqBMI$ ＜ 25) and overweight ($BMI \geq 25$) groups by BMI. There was no significant difference in intake of energy between two groups. Energy intake of each group was lower than the 7th Korean RDA of energy. Overweight subjects showed significantly lower REE/kg body weight. However, REE/kg lean body mass (LBM) did not differ between the two groups. Total activity energy was significantly higher in the overweight group compared to the normal group. Daily activity coefficient of overweight group in male was lower than that of normal group. Daily activity coefficient was almost same in two female groups. LBM was highly correlated with REE and total energy expenditure. We concluded that the overweight group consumed more energy than the normal group due to the heavier body weight.

• The Journal of the Petrological Society of Korea
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• v.3 no.1
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• pp.20-33
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• 1994

Some of the seven types of subgrain boundaries (Means and Ree, 1988) in octachloropropane samples show distinctive deformation patterns during their development. Type II subgrain boundaries migrate to accommodate the deformation difference between adjacent grains. The formation of Type III requires a rigid-body roation of grains to reduce misorientation of adjacent grains. Type I, IV, V and VI develop either in static or dynamic condition. Type VII form only in static environments after deformation. Ribbon grains can develop via Type III or Type IV process. The orientation pattern and density of subgrain boundaries are more or less stable through a post-deformation heating. Subgrain boundary orientations are symmetric with respect to the grain-shape foliation in pure shear. In simple shear, their maximum inclines toward the direction of shear.

• The Journal of the Petrological Society of Korea
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• v.13 no.3
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• pp.142-151
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• 2004

The metamorphic rocks of Yongin-Anseong area in Gyeonggi massif are composed of high-grade gneisses and schists which are considered as Precambrian basement, and Jurassic granite which intruded the metamorphic rocks. In this paper, we discuss the geochemical characteristics of metamorphic rocks and granites in this area based on REE and Nd isotope geochemistry. And we also discuss the petrogenetic relationship between metamorphic rocks and granites in this area. Most of Nd model ages (T$\_$DM/$\^$Nd/) from the metamorphic rocks range ca. 2.6Ga～2.9Ga which are correspond to the main crustal formation stage in Gyeonggi massif by Lee et. al. (2003). And Nd model ages show that the source material of quartzofeldspathic gneiss is slightly older than that of biotite banded gneiss. In chondrite-normalized rare earth element pattern, the range of (La/Yb)$\_$N/ value from biotite banded gneiss is 37～136, which shows sharp gradient and suggests that biotite banded gneiss was originated from a strongly fractionated source material. However, that of amphibolite is 4.65～6.64, which shows nearly flattened pattern. Particularly, the chondrite normalized REE patterns from the high-grade metamorphic rocks show the REE geochemisoy of original source material before metamorphism. In addition, the values of (La/Yb)$\_$N/ and Nd model ages of granite are 32～40 and 1.69Ga～2.08Ga, respectively, which suggest that the source material of granite is different from that of Precambrian basement such as biotite banded gneiss and quartzofeldspthic gneiss in the area.