DOI QR코드

DOI QR Code

Composition of Rare Earth Elements in Northeast Pacific Surface Sediments, and their Potential as Rare Earth Elements Resources

북동태평양 Clarion-Clipperton 해역 표층 퇴적물의 희토류 조성 및 희토류 광상으로서의 잠재성

  • Seo, Inah (Deep-sea and Seabed Mineral Resources Research Center, KIOST) ;
  • Pak, Sang Joon (Deep-sea and Seabed Mineral Resources Research Center, KIOST) ;
  • Kiseong, Hyeong (Deep-sea and Seabed Mineral Resources Research Center, KIOST) ;
  • Kong, Gee-Soo (Marine Geology Department, Petroleum & Marine Research Division, KIGAM) ;
  • Kim, Jonguk (Deep-sea and Seabed Mineral Resources Research Center, KIOST)
  • 서인아 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 박상준 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 형기성 (한국해양과학기술원 심해저광물자원연구센터) ;
  • 공기수 (한국지질자원연구원 석유해저연구본부 해저지질연구실) ;
  • 김종욱 (한국해양과학기술원 심해저광물자원연구센터)
  • Received : 2014.09.30
  • Accepted : 2014.11.20
  • Published : 2014.12.30

Abstract

The surface sediments from the manganese nodule exploration area of Korea in the Clarion-Clipperton fracture zone were investigated to understand the resource potential of and emplacement mechanism for rare earth elements (REEs). The sediments are categorized into three lithological units (Unit I, II and III from top to bottom), but into two groups (Unit I/II and Unit III) based on the distribution pattern of REEs. The distribution pattern of REEs in Unit I/II is similar to that of Post-Archean Australian Shale (PAAS), but shows a negative Ce anomaly and enrichment in heavy REEs (HREEs). In Unit III, the HREE enrichment and Ce anomaly is much more remarkable than Unit I/II when normalized to PAAS, which are interpreted as resulting from the absorption of REEs from seawater by Fe oxyhydroxides that were transported along the buoyant plume from remotely-located hydrothermal vents. It is supported by the PAAS-normalized REE pattern of Unit III which is similar to those of seawater and East Pacific Rise sediments. Meanwhile, the PAAS-normalized REE pattern of Unit I/II is explained by the 4:1 mixing of terrestrial eolian sediment and Unit III from each, indicating the much smaller contribution of hydrothermal origin material to Unit I/II. The studied sediments have the potentiality of a low-grade and large tonnage REE resource. However, the mining of REE-bearing sediment needs a large size extra collecting, lifting and treatment system to dress and refine low-grade sediments if the sediment is exploited with manganese nodules. It is economically infeasible to develop low-grade REE sediments at this moment in time because the exploitation of REE-bearing sediments with manganese nodules increase the mining cost.

Keywords

References

  1. 박상준, 문재운, 이경용, 지상범 (2010) 한국이 탐사 중인 해저광물자원의 희유금속 함량과 의미. 자원환경지질 43:455-466(Pak SJ, Moon JW, Lee KY, Chi SB (2010) Rare metal contents and their implications of seabed mineral resources explored by Korea. Econ Environ Geology 43(5):455-466 (in Korean))
  2. Banerjee R (2004) Manganese nodules as a possible source of precious metals. Curr Sci India 87:278-279
  3. Bostrom K, Peterson MNA (1969) The origin of aluminumpoor ferromanganoan sediments in areas of high heatflow on the East Pacific Rise. Mar Geol 7(5):427-447
  4. Castor SB, Hedrick JB (2006) Rare earth elements. In : Kogel, J. E., Trivedi NC, Barker JM (eds) Industrial Minerals and Rocks. 7th Edition. Society for Mining, Metallurgy and Exploration. Littleton, Colorado, pp 769-792
  5. Dickens GR, Owen RM (1995) Rare earth element deposition in pelagic sediment at the Cenomanian-Turonian boundary, Exmouth Plateau. Geophys Res Lett 22(3):203-206 https://doi.org/10.1029/94GL03047
  6. Elderfield H, Hawkesworth CJ, Greaves MJ, Calvert SE (1981) Rare earth element geochemistry of oceanic ferromanganese nodules and associated sediments. Geochim Cosmochim Ac 45(4):513-528 https://doi.org/10.1016/0016-7037(81)90184-8
  7. German CR, Klinkhammer GP, Edmond JM, Mura A, Elderfield H (1990) Hydrothermal scavenging of rareearth elements in the ocean. Nature 345(6275):516-518 https://doi.org/10.1038/345516a0
  8. Hein JR, Koschinsky A, Halliday AN (2003) Global occurrence of tellurium-rich ferromanganese crusts and a model for the enrichment of tellurium. Geochim Cosmochim Ac 67(6):1117-1127 https://doi.org/10.1016/S0016-7037(02)01279-6
  9. Hein JR, Koschinsky A, Bau M, Manheim FT, Kang JK, Roberts L (2000) Cobaltrich ferromanganese crusts in the Pacific. In: Cronan DS, (ed.) Handbook of Marine Mineral Deposits. CRC Press, Boca, pp 239-279
  10. Humphries M (2010) Rare earth elements: The global supply chain. CRS Report for Congress R41347, Congressional Research Service, Library of Congress
  11. Hyeong K, Park SH, Yoo CM, Kim KH (2005) Mineralogical and geochemical compositions of the eolian dust from the northeast equatorial Pacific and their implications on paleolocation of the Intertropical Convergence Zone. Paleoceanography 20:PA1010
  12. Kato Y, Fujinaga K, Nakamura K, Takaya Y, Kitamura K, Ohta J, Toda R, Nakashima T, Iwamori H (2011) Deepsea mud in the Pacific Ocean as a potential resource for rare-earth elements. Nat Geosci 4(8):535-539 https://doi.org/10.1038/ngeo1185
  13. Kawamoto H (2008) Japan's Policies to be adopted on Rare Metal Resources. Quart Rev 27:57-76
  14. KIGAM (2001) Mineralization and feasibility study of Fe-REE deposits in Hongcheon area, South Korea. 2000-RTI02-P-01, 257 p
  15. Lupton JE (1995) Hydrothermal Plumes: Near and Far Field. In: Susan EH, Robert AZ, Lauren SM, Richard ET (eds) Seafloor Hydrothermal Systems: Physical, Chemical, Biological, and Geological Interactions. American Geophysical Union, Washington, DC, pp 317-346
  16. Metal-Pages http://www.metal-pages.com/ Accessed 13 August 2014
  17. Mills RA, Elderfield H, Thomson J (1993) A dual origin for the hydrothermal component in a metalliferous sediment core from the Mid-Atlantic Ridge. J Geophys Res-Sol Ea 98(B6):9671-9681 https://doi.org/10.1029/92JB01414
  18. Mills RA, Elderfield H (1995) Hydrothermal Activity and the Geochemistry of Metalliferous Sediment. In: Susan EH, Robert AZ, Lauren SM, Richard ET (eds) Seafloor Hydrothermal Systems: Physical, Chemical, Biological, and Geological Interactions. American Geophysical Union, Washington, DC, pp 392-407
  19. Nikolaev AI, Larichkin FD, Nikolaeva OA (2008) Choosing the technology of combined processing of titanium-raremetal raw materials. Theor Found Chem Eng 42:675-679 https://doi.org/10.1134/S0040579508050333
  20. Owen RM, Olivarez AM (1988) Geochemistry of rare earth elements in pacific hydrothermal sediments. Mar Chem 25(2):183-196 https://doi.org/10.1016/0304-4203(88)90063-1
  21. Ruhlin DE, Owen RM (1986) The rare earth element geochemistry of hydrothermal sediments from the East Pacific Rise: Examination of a seawater scavenging mechanism. Geochim Cosmochim Ac 50(3):393-400 https://doi.org/10.1016/0016-7037(86)90192-4
  22. Taylor SR, McLennan SM (1995) The geochemical evolution of the continental crust. Rev Geophys 33(2):241-265 https://doi.org/10.1029/95RG00262
  23. Wu C, Yuan Z, Bai G (1996) Rare earth deposits in China. In Jones AP, Wall F, Williams CT (eds) Rare earth minerals: Chemistry, origin and ore deposits. Mineralogical Society Series, No. 7, Chapman and Hall, London, pp 281-310