• Title/Summary/Keyword: Quantification II analysis

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A Study on Correlativity of the Regional Structure Change and Traffic Demand in Pusan (부산시 지역구조변화와 교통수요의 상관성에 관한 연구)

  • 오윤표;이원규
    • Journal of Korean Society of Transportation
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    • v.11 no.2
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    • pp.27-44
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    • 1993
  • The purpose of this study is to classify the regional structure of Pusan based on socio-economic phenomena in 1979 and 1991, and to analyze correlations between the regional structure change and traffic demend. To formalize the land-use by each zone, the Principal Component Analysis were performed by using 15 socio-sconomic variables. As a result of the analysis, five land-use factors(i.e., official, residential, commercial, manufactural, and other functions) in 1979 and four factors(i. e., residential, 3rd industrial, manufactural, and other functions) in 1991 were extracted as main regional structure components. It was proved that there is strong correlations between the regional structure change and traffic demand by using Quantification Theory II and also by testing correlation coefficient.

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Spectrophotometric Quantitatification of Fe(II) and Fe(III) Ions Using N,N'-bis(4-methoxysalicylidene) phenylendiamine (N,N'-bis(4-methoxysalicylidene) phenylendiamine를 이용한 Fe(II) 및 Fe(III) 이온의 분광학적 분석)

  • Kim, Sun-Deuk;Seol, Jong-Min
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.463-471
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    • 2011
  • A novel $N_2O_2$ Schiff base ligand, N,N'-bis(4-methoxysalicylidene)phenylendiamine(4-$CH_3O$-Salphen), has been synthesized. It has been revealed that the compound is very useful for the spectrophotometric quantification of Fe(II) and Fe(III) ions in aqueous solutions, such as mineral water, hot spring water, sea water, and waste water. The optimum conditions for the quantitative analysis are the followings; [4-$CH_3O$-Salphen]=$4.0{\times}10^{-4}\;M$, DMF/$H_2O$=70/30(v/v), pH=3.4~3.8, T= at $55^{\circ}C$, and prereaction time=1.0 hr. The sample of single valence state was prepared by the preliminary oxidation or reduction using $H_2O_2$ ($5.0{\times}10^{-4}\;M$) and $NH_2OH{\cdot}HCl$ ($5.0{\times}10^{-4}\;M$). The quantitative analyses of Fe(II) and Fe(III) ion were performed by measuring the absorbance at 434 nm and 456 nm, respectively. The estimated mean values agreed well with the standard values within the range of 2.00~6.90%. The limit of detection was 27.9 ng/mL for Fe(II) and 55.8 ng/mL for Fe(III).

Utility of solid phase extraction for colorimetric determination of lead in waters, vegetables, biological and soil samples

  • Al-Mallah, Zakia;Amin, Alaa S.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.461-468
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    • 2018
  • A highly sensitive, selective and rapid method for the determination of lead based on the reaction of lead (II) with 5-(4'-chlorophenylazo)-6-hydroxypyrimidine-2,4-dione (CPAHPD) and the solid phase extraction of the Pb(II)-CPAHPD complex with Amberlite XAD-2000 was developed, in the presence of pH 5.6 buffer solution and Triton X-114 medium. CPAHPD reacts with lead to form a violet complex with a molar ratio of 2:1 (CPAHPD to lead). This complex was enriched by the solid phase extraction with Amberlite XAD-2000. An enrichment factor of 500 was obtained by elution of the complex from the resin with a minimal amount of isopentyl alcohol(0.2 mL). In isopentyl alcohol medium,the molar absorptivity of the complex is $1.13{\times}10^6L\;mol^{-1}cm^{-1}$ at 647 nm. Beer's law is obeyed in the range of $5.0-160ng\;mL^{-1}$ in the measured solution. The relative standard deviation for 10 replicate samples of $50ng\;mL^{-1}$ level is 1.26%. The detection and quantification limits reaches 1.5 and $4.7ng\;mL^{-1}$ in the original samples. The presented procedure was successfully applied for determination of lead content in real samples such as vegetables, waters, biological and soil samples with satisfactory results.

Development of Cognition Character Model for Road Safety Facilities on Vertical Alignment Sections (종단선형구간에서의 도로안전시설물 인지특성 모형개발)

  • Lee, Soo-Beom;Kim, Jang-Wook;Kwon, Hyuk-Min
    • Journal of Korean Society of Transportation
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    • v.23 no.3 s.81
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    • pp.73-84
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    • 2005
  • Highway design criteria are considering roadway safety and smooth driving maneuver. However, a certain highway alignment within design criteria often leads drivers to undesirable situation due to the differences between the original intention of design criteria and the unintended result of drivers' cognition. The differences between them often result in traffic accidents. In order to reduce accident process, highway safety facilities are installed on those roadway sections. However, the relationship between highway environments and human factors has not been deeply studied in Korea. In this study. vertical roadway sections are constructed with 3-D graphical tools. This vertical roadway sections are simulated on a driving simulator in order to identify the differences of drivers' cognition on different roadway environments. Based upon the collected data from the driving simulator, canonical correlation analysis and canonical discriminant analysis of quantification theory II have been performed in order to figure out impacting factors on the degree of roadway safety. Also, based upon quantification theory I. the relationship between roadway safety facilities and the degree of safety has been analyzed.

Optimization Technology of Thermomechanical Pulp Made from Pinus densiflora (II) - Quantification of Pitch Contents in TMP - (국내산 소나무로 제조되는 열기계펄프 제조 기술 최적화 연구 (II) - TMP 펄프의 피치 정량 연구 -)

  • Nam, Hyegeong;Kim, Chul-Hwan;Lee, Ji-Young;Park, Hyunghun;Kwon, Sol
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.5
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    • pp.33-42
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    • 2015
  • Pitches contained in thermomechanical pulp negatively influence paper qaulity and pulp and papermaking process. Without controlling TMP pitches suitably, it is hard to make a certain quality of paper. In order to control pitches in TMP, they must be quantitatively recognized by proper tools. One of the most widely used way to detecting TMP pitches is a staining method using a hydrophobic dye such as Sudan IV. Sudan IV could be used with three different protocols including different application of its dissolution, washing, dyeing time, etc. The dyeing protocols were classified into three categories including Stain I, Stain II, and Stain III. In dyeing time, Stain I required more than 24 hours to dye pitches. On the other hand, Stain III could stain TMP pitches with the most brief way. The images of red-stained pitches could be captured by a stereomicroscope with ${\times}35$ and ${\times}45$ magnifications, and then quantitatively analysed measuring their numbers and areas by Carl Zeiss AxioVision (ver. 4.8.2) program. Among three protocols, both Stain I and Stain III were the most ideal methods to detect TMP pitches because they detected more pitches and bigger pitch areas compared to Stain II against the same specimen. In particular, it was recognized that Stain III could be used as the most useful tool to detect TMP pitches accurately within several minutes.

Development of Analytical Method for Polychlorinated Biphenyls and Organochlorine Pesticides in Air (대기 중 PCBs와 유기염소계 살충제의 정량을 위한 분석 방법 개발)

  • 최민규;여현규;김태욱;천만영;선우영
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.6
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    • pp.475-485
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    • 2002
  • An analytical method was investigated for the meaiiurement of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) concentrations in air samples. Procedures required for column chromatographic clean up. silicagel (stage I) and gel permeation chromatography (stage II), were discussed. Identification and quantification of PCBs and OCPs were performed using a combination of gas chromatography/mass spectrometry/ selected ion monitoring. Recovery tests calculated from six samples are 68∼137% for PCBs and 58∼130% for OCPs except for endrin aldehyde. Instrumental detection limits determined for the PCBs and OCPs varied from 0.05 to 0.18 pg/m3 and from 0.71 to 16.82 pg/㎥, respectively. The method has been applied to the analysis of air samples collected at Ansung city, Kyonggi province, Korea. This method may serve as a screening protocol for the simultaneous determination of PCBs and OCPs in air.

Analysis of Traffic Noise Propagation around Main Roads in Kwang-ju City

  • Choi, Hyung-II;Cheong, Kyung-Hoon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.1-9
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    • 2000
  • This paper describes an analysis of various factors affecting traffic noise propagation, including the distance from the road, existence of a direct path of noise propagation, density and height of buildings, and procedure for predicting the attenuation of noise levels from roads. The analysis is based on a multiple number of regression models, utilizing the quantification theory of the first kind. This study incorporates a large amount of survey data concerning traffic noise propagation. The survey of the traffic noise propagation around main roads was carried out in several residential areas, mainly in Kwangju. The attenuation of noise levels measured provided 691 usable data samples. A multiple regression analysis demonstrated that the distance from the road makes the most significant contribution to the attenuation of the noise level. The second contributor was found to be the existence of a direct path of noise propagation. The building density and average height of the buildings also affected the attenuation of the noise level considerably. Other factors, such as the height of the building behind the receiver microphone and the number of traffic lanes on the noise-source roads, did not contribute as much to the attenuation of the noise level as the factors mentioned avove.

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Development of a Prediction Technique for Debris Flow Susceptibility in the Seoraksan National Park, Korea (설악산 국립공원 지역 토석류 발생가능성 평가 기법의 개발)

  • Lee, Sung-Jae;Kim, Gil Won;Jeong, Won-Ok;Kang, Won-Seok;Lee, Eun-Jai
    • Journal of Korean Society of Forest Science
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    • v.110 no.1
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    • pp.64-71
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    • 2021
  • Recently, climate change has gradually accelerated the occurrence of landslides. Among the various effects caused by landslides,debris flow is recognized as particularly threatening because of its high speed and propagating distance. In this study, the impacts of various factors were analyzed using quantification theory(I) for the prediction of debris flow hazard soil volume in Seoraksan National Park, Korea. According to the range using the stepwise regression analysis, the order of impact factors was as follows: vertical slope (0.9676), cross slope (0.6876), altitude (0.2356), slope gradient (0.1590), and aspect (0.1364). The extent of the normalized score using the five-factor categories was 0 to 2.1864, with the median score being 1.0932. The prediction criteria for debris flow occurrence based on the normalized score were divided into four grades: class I, >1.6399; class II, 1.0932-1.6398; class III, 0.5466-1.0931; and class IV, <0.5465. Predictions of debris flow occurrence appeared to be relatively accurate (86.3%) for classes I and II. Therefore, the prediction criteria for debris flow will be useful for judging the dangerousness of slopes.

Identification and quantification of glucosinolates in rocket salad (Eruca sativa) (Rocket salad(Eruca sativa) 중 glucosinolate 동정 및 정량)

  • Kim, Cho-Rok;Lim, Young-Sil;Lee, Sang-Won;Kim, Sun-Ju
    • Korean Journal of Agricultural Science
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    • v.38 no.2
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    • pp.285-294
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    • 2011
  • Glucosinolate (GSL) contents were investigated (i) at 1~7 days after sowing (DAS) in seed sprouts and (ii) at 3-7 weeks after sowing for the time-course. Moreover, (iii) They were compared with five different cultivars of rocket salad (Eruca sativa). Seventeen GSLs were separated by HPLC analysis, and 10 GSLs among them were identified as glucoraphanin, sinigrin, glucoalyssin, diglucothiobeinin, glucobrassicanapin, glucoerucin, glucobrassicin, dimeric, 4-mercaptobutyl GSL, 4-methoxy glucobrassicin, gluconasturttin by using LC-APCI-MS analysis, but 7 compounds were not identified. (i) The total GSL content in seed sprouts initially increased up to 3 DAS and then decreased according to their seedling growth. In particular, glucoraphanin known as a strong anti-cancer reagent was found the highest level (5.05 ${\mu}mol/g$ dry wt.) at 3 DAS. The most abundant GSL was glucoerucin ranged from 26.0~49.6 ${\mu}mol/g$ dry wt. (ii) In the time-course, the total GSL contents increased dramatically from 3-week (5.91 ${\mu}mol/g$ dry wt.) to 7-week after sowing (32.2 ${\mu}mol/g$ dry wt.). The major GSLs were glucoraphanin, glucoerucin and 4-methoxy glucobrassicin. (iii) By comparing GSL contents with five different cultivars, the total GSL contents increased from 4-week to 6-week after sowing, regardless of cultivar. In 4-week-old, the order with the total GSL content was "Rucola" > "Rocket Herbs" ${\geqq}$ "Odyssey" > "Takii" > "Herb", but in 6-week-old it is changed as "Takii" > "Herb" > "Odyssey" > "Rucola" > "Rocket Herbs" even there was almost no significantly difference between them.

Development of Assessment Model for the Optimal Site Prediction of Evergreen Broad-leaved Trees in Warm Temperate Zone according to Climate Change (기후변화에 따른 난대상록활엽수의 적지예측 평가 모델 개발)

  • Kang, Jin-Teak;Kim, Jeong-Woon;Kim, Cheol-Min
    • Journal of agriculture & life science
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    • v.46 no.3
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    • pp.47-58
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    • 2012
  • This study was carried out to develop assessment model for the optimal site prediction of Dendropanax morbifera, Evergreen broad-leaved trees in warm temperate zone according to climate change. It was created criterion for assessment model of the optimal site prediction by quantification method to possible analysis of quantitative and qualitative data, through study relationship between growth of tree and site environmental factors. A program of the optimal site prediction was developed using program version 3.2, an Avenue and Dialog Designer tool of ESRI as GIS(geographic information system) engine. Developed program applied to test accuracy of the optimal site prediction in study area of Wando, Jeollanam-do, having a various evergreen broad-leaved trees of warm temperate zone. In the results from analysis of the optimal site prediction on Dendropanax morbifera, the characteristics of optimal site were analyzed site environmental features with 401~500m of altitude, $15^{\circ}$ of slope, hillside of local topography, alluvium of deposit type, convex of slope type and south of aspect. The mapping area per grade of the optimal site prediction in the Dendropanax morbifera showed 1,487.2ha(25.4%) of class I, 1,020.3ha(17.4%) of class II, 2,231.8ha(38.2%) of class III and 1,110.5ha(19.0%) of class IV.