• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.207-207
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• 2010

Both ZnO and GaN have excellent physical properties in optoelectronic devices such as blue light emitting diode (LED), blue laser diode (LD), and ultra-violet (UV) detector. The ZnO/GaN heterostructure, which has a potential to achieve the cost efficient LED technology, has been fabricated by using radio frequency (RF) sputtering, pyrolysis, metal organic chemical vapor deposition (MOCVD), direct current (DC) arc plasmatron, and pulsed laser deposition (PLD) methods. Among them, the PLD system has a benefit to control the composition ratio of the grown film from the mixture target. A 500-nm-thick ZnO film was grown by PLD technique on c-plane GaN/sapphire substrates. The post annealing process was executed at some varied temperature between from $300^{\circ}C$ to $900^{\circ}C$. The morphology and crystal structural properties obtained by using atomic force microscope (AFM) and x-ray diffraction (XRD) showed that the crystal quality of ZnO thin films can be improved as increasing the annealing temperature. We will discuss the post-treatment effect on film quality (uniformity and reliability) of ZnO/GaN heterostructures.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2002년도 제25회 KOSCI SYMPOSIUM 논문집
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• pp.123-128
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• 2002

이중동축류 버너를 사용하여 에틸렌/프로판 및 에틸렌/메탄 혼합 연료의 매연생성 상승효과와 관련된 매연생성 메커니즘을 이해하기 위한 실험을 수행하였다. 매연체적분율, 광산란신호 및 PAH 형광신호를 측정한 결과 다음을 알 수 있었다. 에틸렌/프로판 혼합연료에서 연료공급 위치의 변화에 따른 매연생성특성의 변화는 대부분 synergistic 효과와 관련되는 것임을 알 수 있었다. 그러나 에틸렌/메탄 혼합연료의 경우 연료공급의 위치변화가 매연생성에 크게 영향을 주지 않았다. PAH 분포는 synergistic 효과에 의한 매연 생성 특성의 변화와 일관성이 없는 것이 관찰되었다. 따라서 synergistic 효과에 대한 PAH의 역할에 대한 이해가 필요함을 알 수 있었다.

• 한국농공학회논문집
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• 제59권5호
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• pp.17-23
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• 2017

In South Korea, 25 % of annual agricultural residues (11.64 million tons) are unused. The hydrophilicity, low lower heating value (LHV), and low energy density of agricultural residues can be obstacles for efficient usage. Torrefaction, a low temperature pyrolysis process, can be a solution to overcome these disadvantage of agricultural residues. In this study, agricultural residues such as bean stem, pepper stem, perilla stem, sorghum stem, acorn shell, and ginkgo shell are torrefied at 200, 230, and $250^{\circ}C$ and evaluated energy properties, respectively. The torrefaction can increase the LHV and energy density rate of agricultural residues from 3,331~4,444 kcal/kg to 4,166~5,830 kcal/kg and 20~30 %, respectively.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.94.1-94.1
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• 2012

폴리페닐카보실란은 페닐그룹을 포함하고 있는 카보실란계 고분자로서 열분해 후 과량의 탄소를 함유할 수 있는 세라믹 전구체이다. 카보실란계열의 고분자는 산화특성이 있어 SiOC 코팅 용도에도 사용되고 있는데, 폴리페닐카보실란은 free 탄소를 함유하는 SiOC:C 필름을 형성할 수 있다. SiOC 코팅 전구체로는 일반적으로 실리카졸, 실라잔 계열의 고분자, 실록산 계열의 고분자가 사용되고 있으나, 폴리페닐카보실란의 경우 상기 전구체에 비하여 보관 안정성 및 뛰어난 부착특성을 나타낸다. 기존 연구에서는 폴리페닐카보실란으로부터 형성된 SiOC:C 필름의 저유전막, 산화방지막, 분진방지막 등의 응용성에 대하여 고찰한 바 있다. 폴리페닐카보실란은 열처리 온도 영역에 따라 응용 분야가 달라질 수 있는데, 이에 본 연구에서는 각 열처리 온도 영역에 따라 형성되는 SiOC:C 필름의 구조적 변화를 고찰하였다. 필름 형성은 20 % 폴리카보실란 용액을 스핀코팅하고 대기상에서 경화를 실시하였으며, 질소 분위기에서 400 ~ 1200 도 범위에서 열처리하였다. 이렇게 얻어진 300 nm 두께의 필름은 XPS 표면분석과 FT-IR, Solid-NMR을 이용하여 C-Si-O 네트워크 형성의 거동을 확인하였으며, 800 도 이상에서 나타나는 특징적인 free 탄소는 Raman을 이용하여 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제35권1호
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• pp.103-110
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• 2014

Sisal fiber, an agricultural resource abundantly available in china, has been used as raw material to prepare activated carbon with high surface area and huge pore volume by chemical activation with zinc chloride. The orthogonal test was designed to investigate the influence of zinc chloride concentration, impregnation ratio, activation temperature and activation time on preparation of activated carbon. Scanning electron micrograph, Thermo-gravimetric, $N_2$-adsorption isotherm, mathematical models such as t-plot, H-K equation, D-R equation and BJH methods were used to characterize the properties of the prepared carbons and the activation mechanism was discussed. The results showed that $ZnCl_2$ changed the pyrolysis process of sisal fiber. Characteristics of activated carbon are: BET surface area was $1628m^2/g$, total pore volume was $1.316m^3/g$ and ratio of mesopore volume to total pore volume up to 94.3%. These results suggest that sisal fiber is an attractive source to prepare mesoporous high-capacity activated carbon by chemical activation with zinc chloride.

• Bulletin of the Korean Chemical Society
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• 제28권9호
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• pp.1463-1466
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• 2007

Single phases of multi-component oxides films, ZrTiO4 and Ta2Zr6O17, could be synthesized by using the combinatorial approach through surface sol-gel route, coating the appropriate mole ratio of 100 mM zirconium butoxide, tantalum butoxide and titanium butoxide precursors on Pt/Ti/SiO2/Si (100) substrate, following pyrolysis at 450 oC, and annealing them at 770 oC. Both the films and bulks of ZrTiO4 and Ta2Zr6O17 showed very stable dielectric properties in temperature range, ?140 to 60 oC, and frequency range, 100 Hz to 1 MHz, promising their applications in wide range of temperatures and frequencies. The dielectric constants of the films were lower and a little more dependent on frequency than those of the bulks. The reduction of dielectric property in the film was mainly due to the interfacial effects that worked as series and parallel-connected capacitances toward the substantial film capacitance.

• 한국분말재료학회지
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• 제17권3호
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• pp.223-229
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• 2010

Iron(Fe)-Molybdenum(Mo) alloyed nanoparticles and nanowires were produced by the chemical vapor condensation(CVC) process using the pyrolysis of iron pentacarbonyl($Fe(CO)_5$) and Molybdenum hexacarbonyl($Mo(CO)_6$). The influence of CVC parameter on the formation of nanoparticle, nanowire and size control was studied. The size of Fe-Mo alloyed nanoparticles can be controlled by quantity of gas flow. Also, Fe-Mo alloyed nanowires were produced by control of the work chamber pressure. Moreover, we investigated close correlation of size and morphology of Fe-Mo nanoparticles and nanowires with atomic quantity of inflow precursor into the electric furnace as the quantitative analysis. Obtained nanoparticles and nanowires were investigated by field emission scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction.

• 한국분말재료학회지
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• 제11권2호
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• pp.124-129
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• 2004

Nanosized WC and WC-Co powders were synthesised by chemical vapor condensation(CVC) process using the pyrolysis of tungsten hexacarbonyl(W(CO)$_6$) and cobalt octacarbonyl(Co$_2$(CO)$_8$). The microstructural changes and phase evolution of the CVC powders during post heat-treatment were studied using the XRD, FE-SEM, TEM, and ICP-MS. CVC powders were consisted of the loosely agglomerated sub-stoichimetric WC$_{1-x}$ and the long-chain Co nanopowders. The sub-stochiometric CVC WC and WC-Co powders were carburized using the mixture gas of CH$_4$-H$_2$ in the temperature range of 730-85$0^{\circ}C$. Carbon content of CVC powder controlled by the gas phase carburization at 85$0^{\circ}C$ was well matched with the theoretical carbon sioichiometry of WC, 6.13 wt％. During the gas phase carburization, the particle size of WC increased from 20 nm to 40 nm and the long chain structure of Co powders disappeared.

• Fibers and Polymers
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• 제1권2호
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• pp.97-102
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• 2000

Pitch precursors were synthesized from coal tar(CT) and pyrolysis fuel oil(PFO, petroleum residue oil) at relatively low temperature of $250^{\circ}$, in the presence of horontrifluorideidiethyletherate complex(BFDE) as a catalyst and nitrobenzene(NB) as a co-catalyst. The softening point, nitrogen content and carbon yield increased with an increase of concentration of NB. The pitch precursors with good spinnability were prepared by removing the volatile components through $N_2$ blowing. The precursor pitches were spun through a circular nozzle, stabilized at $310^{\circ}$ and finally carbonized at $1000^{\circ}$. The optically anisotropic structure formed at the absence of NB was changed into isotropic structure, showing a decrease in size of the flow domain. The hollow carbon fiber could be prepared in the process of stabilization. The results proposed that the morphology of carbon materials could be controlled by changing the concentration of catalyst and/or co-catalyst and/or stabilization condition that affect on the mobility of molecules during carbonization.

• 한국세라믹학회지
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• 제20권2호
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• pp.166-172
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• 1983

In this study the sillicon-alloyed isotropic pyrolytic carbon was deposited in the tumbling bed from the pyrolysis of propane and silicon tetrachloride and investigated whether the silicon-alloyed isotropic pyrolytic carbon deposited in this study was usable as bionaterial or not. The silicon-allyed isotropic pyrolytic carbon was varied by controlling the process variables such as propane con-concentration and the argon flow rate flowing in to the silicon tetrachloride bubbler at a fixed reaction bed tempera-ture of 120$0^{\circ}C$ a rotation of reaction tube of 40 rpm a bed particle weight of 7.5 g and a total flow rate of 21/min; the propane concentration was varied from 10 to 70 and the argon flow rate flowing into the silicon tetrachloride bubble from 0 to 1000 cc/min. The results show that the silicon-alloyed isotropic pyrolytic carbon was obtained at all conditions investigated, . And then the alloyed silicon content is rangion from 7 to 14.5 wt%. The density and deposition rate of deposited silicon-alloyed isotropic carbon increased axxording to silicon content and propane concentration. And the apparent crystal-size(Lc) of pyrolytic carbon is not changed with silicon content. The density and apparant crystallite size are respec-tively in the range of 1.94 to 2.06 and 20 to 25$\AA$ It is shown that the silicon-alloyed isotropic pyrolytic carbon ob-tained in this experiment is usable as biomaterial.