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http://dx.doi.org/10.5012/bkcs.2014.35.1.103

Preparation and Characterization of Sisal Fiber-based Activated Carbon by Chemical Activation with Zinc Chloride  

Lu, Xincheng (Institute of Chemical Industry of Forest Products, CAF)
Jiang, Jianchun (National Engineering Laboratory for Biomass Chemical Utilization)
Sun, Kang (Key and Open Laboratory of Forest Chemical Engineering, SFA)
Xie, Xinping (Key Laboratory of Biomass Energy and Material)
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Abstract
Sisal fiber, an agricultural resource abundantly available in china, has been used as raw material to prepare activated carbon with high surface area and huge pore volume by chemical activation with zinc chloride. The orthogonal test was designed to investigate the influence of zinc chloride concentration, impregnation ratio, activation temperature and activation time on preparation of activated carbon. Scanning electron micrograph, Thermo-gravimetric, $N_2$-adsorption isotherm, mathematical models such as t-plot, H-K equation, D-R equation and BJH methods were used to characterize the properties of the prepared carbons and the activation mechanism was discussed. The results showed that $ZnCl_2$ changed the pyrolysis process of sisal fiber. Characteristics of activated carbon are: BET surface area was $1628m^2/g$, total pore volume was $1.316m^3/g$ and ratio of mesopore volume to total pore volume up to 94.3%. These results suggest that sisal fiber is an attractive source to prepare mesoporous high-capacity activated carbon by chemical activation with zinc chloride.
Keywords
Sisal fiber; Chemical activation; Activated carbon; Surface characterization; Activation mechanism;
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1 Boppart, S.; Ingle, L.; Potwora, R. J.; Rester, D. O. Chem. Process 1996, 59, 19.
2 Lu, X. C.; Jiang, J. C.; Sun, K.; Xie, X. P.; Hu, Y. M. Appl. Surf. Sci. 2012, 258, 8247.   DOI   ScienceOn
3 Lu, X. C.; Jiang, J. C.; Sun, K.; Cui, D. D. Appl. Surf. Sci. 2011, 258, 1656.   DOI   ScienceOn
4 Sun, K.; Jiang, J. C. Biomass Bioenerg. 2010, 34, 539.   DOI   ScienceOn
5 Zhang, T. Y.; Walawender, W. P.; Fan, L. T.; Fan, M. H.; Daugaard, D.; Brown, R. C. Chem. Eng. J. 2004, 105, 53.   DOI   ScienceOn
6 Haykiri-acma, H.; Yaman, S.; Kucukbayrak, S. Energ. Convers. Manage. 2006, 47, 1004.   DOI   ScienceOn
7 Yang, T.; Lua, A. C. J. Colloid Interf. Sci. 2003, 267, 408.   DOI   ScienceOn
8 Hayshi, J.; Toshihide, H.; Isao, T.; Katsuhiko, M.; Fard, N. A. Carbon 2002, 13, 40.
9 Guo, Y. P.; Rockstraw, H. Micropor. Mesopor. Mat. 2007, 100, 12.   DOI   ScienceOn
10 Zhong, Z. Y.; Yang, Q.; Li, X. M.; Luo, K.; Liu, Y.; Zeng, G. M. Ind. Crop. Prod. 2012, 37, 178.   DOI   ScienceOn
11 Reinoso, F. R.; Buss, G. Y. European Patent EP0329251, 1993.
12 Molina-Sabio, M.; Rodriguez-Reinoso, F. Colloid Surface A. 2004, 241, 15.   DOI   ScienceOn
13 Rodriguez-Reinoso, F.; Lopez-Gonzalez, J. De. D.; Berenguer, C. Carbon 1982, 20, 513.   DOI   ScienceOn
14 Li, W.; Zhang, L. B.; Peng, J. H.; Li, N.; Zhu, X. Y. Ind. Crops. Prod. 2008, 27, 341.   DOI   ScienceOn
15 Zhang, H. P.; Ye, L. Y.; Yang, L. C. Materials Sci. Techn. 2006, 14, 43.
16 Arabovich, G.; Donohue, M. J. Colloid Interf. Sci. 1998, 200, 273.   DOI   ScienceOn
17 Gonzalez-Serano, E.; Cordero, T.; Rodriguez-Mirasol, J.; Rodriguez, J. J. Ind. Eng. Chem. Res. 1997, 36,4832.   DOI   ScienceOn
18 Gregg, S. J.; Sing, K. S. W. Academic Press: 1982; pp 257-283.
19 Ahmadpour, A.; Do, D. D. Carbon 1997, 35, 1723.   DOI   ScienceOn