• Title/Summary/Keyword: Pure anisotropy

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Hydrogen Evolution Ability of Selected Pure Metals and Galvanic Corrosion Behavior between the Metals and Magnesium

  • Luo, Zhen;Song, Kaili;Li, Guijuan;Yang, Lei
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.323-329
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    • 2020
  • The cathodic hydrogen evolution ability of different pure metals and their long term galvanic corrosion behavior with pure Mg were investigated. The hydrogen evolution ability of pure Ti, Al, Sn and Zr is weak, while that of Fe, W, Cr, and Co is very strong. Initial polarization test could not completely reveal the cathodic behavior of the tested metals during long term corrosion. The cathodic hydrogen evolution ability may vary significantly in the long term galvanic tests for different metals, especially for Al whose cathodic current density reduced to 1/50 of the initial value. The anodic polarization shows that Al and Sn as alloying elements are supposed to provide relatively good passive effect for Mg alloy, while Ag can provide a slight passive effect and Zn has little passive effect.

A Study on Plastic Deformation Characteristics and Formability for Pure Titanium Sheet (순 티타늄 판재의 변형 특성 및 성형성 평가)

  • In, J.H.;Jeong, K.C.;Lee, H.S.;Kim, J.H.;Kim, J.J.;Kim, Young Su
    • Transactions of Materials Processing
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    • v.27 no.5
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    • pp.301-313
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    • 2018
  • In this paper, tensile test was performed on pure titanium sheet (CP Ti sheet) with HCP structure in each direction to evaluate mechanical and surface properties and analyze microstructural changes during plastic deformation. We also evaluated forming limits of Ti direction in dome-type punch stretching test using a non-contact three-dimensional optical measurement system. As a result, it was revealed the pure titanium sheet has strong anisotropic property in yield stress, stress-strain curve and anisotropy coefficient according to direction. It was revealed that twinning occurred when the pure titanium sheet was plastic deformed, and tendency depends differently on direction and deformation mode. Moreover, this seems to affect the physical properties and deformation of the material. In addition, it was revealed the pure titanium sheet had different surface roughness changes in 0 degree direction and 90 degree direction due to large difference of anisotropy, and this affects the forming limit. It was revealed the forming limit of each direction obtained through the punch stretching test gave higher value in 90 degree direction compared with forming limit in 0 degree direction.

Acoustical Anisotropy Evaluation of Pure Titanium plate Using Neural Network (신경회로망을 이용한 순 티타늄판재의 음향이방성 평가)

  • Park, Hee-Dong;Yun, In-Sik;Yi, Won
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.9
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    • pp.1103-1109
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    • 2011
  • This research quantitatively confirmed an acoustical anisotropy that exists in a pure titanium plate from the signal of ultrasonic flow detection and suggested a new way to evaluate the acoustical anisotropy by inputting acquired characteristic of ultrasound signal into the neutral network. Using the fact with the suggested method that the characteristic of ultrasound signal is shown differently depending on the pure titanium plate's rolling direction, the neural network was constructed by extracting the characteristic that can decide each direction of $0^{\circ}$, $45^{\circ}$, and $90^{\circ}$ with waveform analysis program. As a result of inputting the characteristic of ultrasound signal acquired from a random rolling direction into the neural network that was built like this, it showed a pattern recognition rate higher than 95% on directions of $0^{\circ}$, $45^{\circ}$, $90^{\circ}$.

A Study on Fatigue Crack Propagation Behavior with Pure-Ti Plate (순수 티타늄 판재의 피로균열 전파거동에 관한 연구)

  • 오세욱;김태형;김득진;임만배
    • Journal of Ocean Engineering and Technology
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    • v.9 no.1
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    • pp.92-100
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    • 1995
  • The effect of different anisotropy and stress ratio on fatigue crack propagation behavior was investigated under various stress ratio(R=-0.4, -0.2, 0.2, 0.2, 0.4) using pure titanium sheet used in aerospace, chemical and food industry. The rack closure behavior under constant load amplitude fatigue crack propagation test was examined. Fatigue crack propagation rate da/dN was estimated in terms of effective stress intensity factor range, $\Delta$K$_{eff}$, regardless of various stress ratio but was influenced by anisotropy. Also, it was found that the effect of anisotropy was considerably decreased but still not negligible when he da/dN was evaluated by a conventional parameter, $\Delta$$K_{eff}$/E and when the modified da/dN.$\sqrt{\varepsilon}_f$ was evaluated by $\Delta$$K_{eff}$/E. On the other hand, da/dN could be evaluated uniquely by effective new parameter, $\Delta$K$_{eff}$/$sigma_{ys}$, regardless of anisotropy, as int he following equation da/dN=C''[\frac{{\Delta}K_{eff}}{{\sigma}_{ys}}]^{n''}. And effective stress intensity factor range ratio, U was estimated by the following equation with respect to the ratio of reversed plastic zone size, $\Delta r_{p}$ to monotonic plastic zone size, $r_p$ regardless of stress ratio and anisotropy. U=-4.45$(\Delta r_{p}/r_{p})^{2}$+4.1$(\Delta r_{p}/r_{p})$+0.245_{p})$+0.245

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The Anisotropy of the London Penetration Depth and the Upper Critical Field in C-doped $MgB_2$ Single Crystals from Reversible Magnetization

  • Kang, Byeong-Won;Park, Min-Seok;Lee, Hyun-Sook;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.36-40
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    • 2010
  • We have studied the anisotropy of the London penetration depth of carbon doped $MgB_2$ single crystals, which was obtained from reversible magnetization measurements with the magnetic field both parallel and perpendicular to the c-axis. Similar to the pure $MgB_2$, the anisotropy of the upper critical field ${\gamma}_H$ decrease with temperature while the anisotropy of the London penetration depth ${\gamma}_{\lambda}$ slowly increases with temperature. However, the temperature dependence of ${\gamma}_H$ is drastically reduced and the value of ${\gamma}_{\lambda}$ becomes nearly ~1 as C is introduced. These results indicate that C substitution increases impurity scattering mainly in the $\sigma$ bands. The temperature dependence of the anisotropies agree well with the theoretical predictions with impurity scattering.

COLLINEARITY AND SPIN FREEZING

  • Vincze, I.;Kemeny, T.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.343-350
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    • 1995
  • An overview will be given on recent Mossbauer and magnetization investigation of the applied field dependence of the magnetic properties of typical systems without strong magnetic anisotropy and showing the absence of magnetic saturation in high fields (including iron-rich spin glass (amorphous $Fe_{93}Zr_{7}$, soft ferromagnets (amorphous $Fe_{88}Zr_{12}$, $Fe_{70}Ni_{20}Zr_{10}$ and $Fe_{88}B_{12}$) and pure Fe). The results emphasize that shape anisotropy due to surface irregularities causes misalignment between the magnetization and the applied field in the otherwise collinear magnetic structure.

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Effect of Al Doping on the Anisotropy of $MgB_2$ Single Crystals (Al 첨가가 $MgB_2$ 단결정의 비등방성에 미치는 영향에 대한 연구)

  • Kang, Byeong-Won;Lee, Hyun-Sook;Park, Min-Seok;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.9 no.2
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    • pp.183-187
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    • 2008
  • We have studied superconducting properties of $Mg_{1-x}Al_xB_2$ single crystals from reversible magnetization measurements. It was found that the upper critical fields $H_{c2}$ were decreased for both H // c and H // ab as Al is substituted for Mg. As a result, the large anisotropy of $H_{c2}$ observed in pure $MgB_2$, which is considered as one of the characteristics of two-gap superconductor, was decreased with Al doping. On the other hand, the irreversibility fields $H_{irr}$ were increased for x = 0.1 and were significantly decreased for x = 0.2. In contrary to the anisotropy of $H_{c2}$, the anisotropy of $H_{irr}$ was increased as Al concentration increases.

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Magnetocrystalline Anisotropy of α''-Fe16N2 (α''-Fe16N2의 자기결정이방성)

  • Khan, Imran;Son, Jicheol;Hong, Jisang
    • Journal of the Korean Magnetics Society
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    • v.26 no.4
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    • pp.115-118
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    • 2016
  • We investigated the magnetocrystalline anisotropy of pure ${\alpha}^{{\prime}{\prime}}-Fe_{16}N_2$ by using full-potential linearized augmented plane wave method (FLAPW). A very high magnetic moment was obtained for Fe (4d) site due to the lattice expansion in the z-direction, while the magnetic moment of Fe (4e) and (8h) site were suppressed due to hybridization with neighboring N atom. The calculated spin magnetic moments for different Fe sites (4d, 4e and 8h) were in good agreement with previously reported values. Due to the tetragonal distortion, we found a very large uniaxial anisotropy constant of $0.58MJ/m^3$. Besides, a high value of magnetization of 1.76MA/m was obtained. In additon, the estimated coercive field and maximum energy product of 6.51 kOe and 71.7 MGOe were obtained for pure ${\alpha}^{{\prime}{\prime}}-Fe_{16}N_2$. This may suggest that the ${\alpha}^{{\prime}{\prime}}-Fe_{16}N_2$ can be utilized for potential rare-earth free permanent magnet material.

Membrane-Ordering Effects of Barbiturates on Pure Phospholipid Model Membranes

  • Knag, Jung-Sook;Chung, Young-Za;Cho, Goon-Jae;Byun, Won-Tan;Yun, Il
    • Archives of Pharmacal Research
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    • v.15 no.3
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    • pp.196-203
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    • 1992
  • Intramolecular excimer formation of 1, 3-di(1-pyrenyl)propane (Py-3-Py) and fluorescence polarization of 1, 6-diphenyl-1, 3, 5-hexatriene (DPH) were used to investigate the effects of barbiturates on the fluidity of model membranes of phosphatidycholine (SPMVPC), phosphatidylserine (SPMVPS), and phosphatidylinositol (SPMVPI) fractions of synaptosomal plasma membrane vesicles (SPMV) isolated from bovine cerebral cortex. In a dose-dependent manner, barbiturates decreased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py and increased the anisotropy(r), rotational relaxation time (P), limiting anisotropy $(r_infty)$, and order parameter (S) of DPH in SPMVPC, SPMVPS and SPMVPI. This indicates that barbiturates decreased both the lateral and rotational diffusion of the probes in SPMVPC, SPMVPS and SPMVPI. The relative potencies of barbiturates in ordering the membranes were in the order: pentobarbital > hexobarbital > amobarbital > phenobarbital. This order correlates well with the anesthetic potencies of barbiturates and the potencies for enhancement of $\gamma$-aminobutyric acid-stimulated chloride uptake. Thus, it is strongly suggested that a close relationship might exist between the membrane ordering effects of barbiturates and the chloride fluxes across SPMV.

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Grain Boundary Microcracking in ZrTiO4-Al2TiO5 Ceramics Induced by Thermal Expansion Anisotropy

  • Kim, Ik-Jin;Kim, Hyung-Chul;Lee, Kee-Sung;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.40 no.2
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    • pp.109-112
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    • 2003
  • The grain-boundary microcracking materials in the system $Al_2$TiO$_{5}$ -ZrTiO$_4$(ZAT) is influenced by the thermal expansion anisotropy. The range of ZAT compositions investigated had showed very low thermal expansions of 0.3~1.3$\times$10$^{-6}$ K loin compared to 8.29$\times$10$^{6}$ K of pure ZrTiO$_4$and 0.68$\times$10$^{6}$ K of polycrystalline $Al_2$TiO$_{5}$ , respectively, compared with the theoretical thermal expansion coefficient for a single crystal of $Al_2$TiO$_{5}$ , 9.70$\times$10$^{6}$ K. The low thermal expansion and microcraking temperature are apparently due to a combination of thermal contraction and expansion caused by the large thermal expansion anisotropy of the crystal a ies of the $Al_2$TiO$_{5}$ phase.