• Journal of Korean Society of Environmental Engineers
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• v.32 no.6
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• pp.547-554
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• 2010

In this study, new manganese oxide (i.e., black-birnessite) particles with nanostructures were prepared and its physico-chemical properties and oxidative-transformation efficiency on 1,4-naphthoquinine(1,4-NPQ) in the presence of reactive mediator was investigated. The results were also compared with that of the manganese oxide (i.e., brown-birnessite) particles synthesized by classical McKenzie method. Analysis of XRD and SEM data show that the particles are a single phase corresponding to a birnessite-based manganese oxide with cotton ball-like shapes containing nanofibers. In batch experiments, removals of 1,4-NPQ by the black-birnessite follows pseudo-first-order kinetics and the rate constant values obtained are greater about 2.3 times than that of the brown-birnessite in spite of its lower surface area (41.0 vs 19.80 $m^2/g$). The results can be explained by the higher crystallinity and nano structured features of the back-birnessite particles, which give higher reactivity for the removals of the quinone compound. HPLC analysis of the reaction products confirmed that the balck-birnessites removed 1,4-NPQ through cross-coupling reaction in the presence of catechol as a reactive mediator.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.11
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• pp.989-996
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• 2009

In this study, the effects of biofilter media type (three different activated carbons and anthracite), empty bed contact time (EBCT) and temperature on the removal of four aldehyde species (formaldehyde, acetaldehyde, glyoxal and methylglyoxal) in BAC filters were investigated. Experiments were conducted at three water temperature (5, 15 and $25^{\circ}C$) and four EBCTs (5, 10, 15, and 20 min). The experimental results indicated that the coal based BAC retained more bacterial biomass on the surface of the activated carbon than the other BACs, and increasing EBCT or increasing water temperature also increased the four aldehyde species removal in BAC filters. To achieve above 80% of removal efficiency for four aldehyde species in a BAC filter, above 15 min EBCT at $5^{\circ}C$ and 10 min EBCT at above $15^{\circ}C$ were required. The kinetic analysis indicated a first-order reaction rate for the biodegradation of four aldehyde species at various water temperatures. Data obtained from the BAC filters at various temperatures were also used to evaluate pseudo first-order rate constants for four aldehyde species. The half-lives evaluated for formaldehyde, acetaldehyde, glyoxal and methylglyoxal in the coal-based BAC ranging from 0.89 to 3.19 min, from 0.75 to 3.35 min, from 2.16 to 4.72 min and from 1.49 to 3.86 min, respectively, could be used to assist water utilities in designing and operating BAC filters.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.7
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• pp.714-721
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• 2010

This research was undertaken to evaluate the feasibility of lanthanum hydroxide for fluoride removal from aqueous solutions. A batch sorption experiments were conducted to study the influence of various factors such as pH, contact time, initial fluoride concentration and temperature on the sorption of fluoride on lanthanum hydroxide. The optimum fluoride removal was observed in the $pH_{eq}{\leq}8.8$. Sorption equilibrium of fluoride on lanthanum hydroxide was better described by the Freundlish isotherm model than by the Langmuir isotherm model. The adsorption energy obtained from D-R model was 9.21 kJ/mol indicating an ion-exchange process as primary adsorption mechanism. The pseudo-second-order kinetic model described well the experimental kinetic data. Thermodynamic parameters such as ${\Delta}Go^{\circ}$, ${\Delta}H^{\circ}$ and ${\Delta}S^{\circ}$ indicated that the nature of fluoride sorption is spontaneous and endothermic. The used lanthanum hydroxide could be regenerated by washing with NaOH solution. Also, the results applied to real ground water indicate that fluoride selectivity and removal capacity of lanthanum hydroxide were superior to those of PA anion-exchange resin.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.458-465
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• 2020

Isotherms, kinetics and thermodynamic properties for adsorption of acid fuchsin (AF) dye by activated carbon were carried out using variables such as dose of adsorbent, pH, initial concentration and contact time and temperature. The effect of pH on adsorption of AF showed a bathtub with high adsorption percentage in acidic (pH 8). Isothermal adsorption data were fitted to the Freundlich, Langmuir, and Dubinin-Radushkevich isotherm models. Freundlich isothem model showed the highest agreement and confirmed that the adsorption mechanism was multilayer adsorption. It was found that adsorption capacity increased with increasing temperature. Freundlich's separation factor showed that this adsorption process was an favorable treatment process. Estimated adsorption energy by Dubinin-Radushkevich isotherm model indicated that the adsorption of AF by activated carbon is a physical adsorption. Adsorption kinetics was found to follow the pseudo-second-order kinetic model. Surface diffusion at adsorption site was evaluated as a rate controlling step by the intraparticle diffusion model. Thermodynamic parameters such as activation energy, Gibbs free energy, enthalpy entropy and isosteric heat of adsorption were investigated. The activation energy and enthalpy change of the adsorption process were 21.19 kJ / mol and 23.05 kJ / mol, respectively. Gibbs free energy was found that the adsorption reaction became more spontaneously with increasing temperature. Positive entropy was indicated that this process was irreversible. The isosteric heat of adsorption was indicated physical adsorption in nature.

• Journal of the Korean Institute of Telematics and Electronics D
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• v.36D no.10
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• pp.51-60
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• 1999

For an effective phase-multiplexing in holographic memory system, four types of phase code used as reference beam are generated. In case of $32 {\times} 32$ address beam, a phase error with 0%, 5%, 10% 15%, 20%, and 25% error rate, is purposely added to the real phase values in order to consider the practical SLM's nonlinear characteristics of phase modulation in computer simulation, cross talks and SNRs are comparatively analysed for these phase-codes by the auto and cross-correlation. Pseudo-Random(PSR) Phase Code has the lowest cross-correlation mean value of 0.067 among four types of Phase Code, which means the SNR of the PSR is higher than other Phase Codes. Also, the standard deviation of the PSR phase code indicating the degree of recalled data degradation is the lowest value of 0.0113.

• Clean Technology
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• v.26 no.1
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• pp.30-38
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• 2020

The kinetic and thermodynamic parameters of Acid Red 66, adsorbed by granular activated carbon, were investigated on areas of initial concentration, contact time, and temperature. The adsorption equilibrium data were applied to Langmuir, Freundlich, Temkin, Redlich-Peterson, and Temkin isotherms. The agreement was found to be the highest in the Freundlich model. From the determined Freundlich separation factor (1/n = 0.125 ~ 0.232), the adsorption of Acid Red 66 by granular activated carbon could be employed as an effective treatment method. Temkin's constant related to adsorption heat (B_T = 2.147 ~ 2.562 J mol^-1) showed that this process was physical adsorption. From kinetic experiments, the adsorption process followed the pseudo-second order model with good agreement. The results of the intraparticle diffusion equation showed that the inclination of the second straight line representing the intraparticle diffusion was smaller than that of the first straight line representing the boundary layer diffusion. Therefore, it was confirmed that intraparticle diffusion was the rate-controlling step. From thermodynamic experiments, the activation energy was determined as 35.23 kJ mol^-1, indicating that the adsorption of Acid Red 66 was physical adsorption. The negative Gibbs free energy change (ΔG = -0.548 ~ -7.802 kJ mol^-1) and the positive enthalpy change (ΔH = +109.112 kJ mol^-1) indicated the spontaneous and endothermic nature of the adsorption process, respectively. The isosteric heat of adsorption increased with the increase of surface loading, indicating lateral interactions between the adsorbed dye molecules.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.18 no.10
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• pp.1142-1149
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• 2007

In this paper, the development of wideband MIMO channel sounder and a pilot measurement result is described for research on the multi antenna radio propagation characteristics considering urban environment at microwave frequencies. We developed $4{\times}4$ MIMO(BW:100 MHz) channel sounder using the high speed switching mechanism and periodic pseudo random binary signals method considering next generation mobile communication system. A pilot measurement campaign at the urban area of Bundang is presented for confirmation of system performance. From the analysis of measurement data, wideband path loss exponent of 3.7 and 8 GHz band is 1.79 and 1.76. Average RMS delay spread is 200 ns and 42 ns respectively. From the experiment results, operation of this measurement system is confirmed considering research for a coverage, SNR and channel capacity in urban environment at microwave frequencies.

• Journal of Korean Society for Geospatial Information Science
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• v.10 no.4 s.22
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• pp.41-50
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• 2002

RPM is the one of the sensor models which is proposed by Open GIS Consortium (OGC) as image transfer standard. And it is the sensor model for end-users using IKONOS, a commercial pushbroom satellite, imagery which provide about 1m ground resolution. Parameters called RPC which is IKONOS RFM coefficients are serviced to end-users. But if some users try to make additional effort to get rigorous geo-spatial information, it is necessary to apply mathematic or abstract sensor models, because vendors don't offer any ancillary data for physical sensor models such as satellite orbit and navigation. Abstract sensor models such as pushbroom Direct Linear Transform (DLT) require many GCPs well distributed in imagery, and mathematic sensor model such as RFM, polynomials need much more GCPs. Therefore RPC modification using additional a few GCPs is the best solution. In this paper, two methods are proposed to modify RPC. One is method to use pseudo GCPs generated in normalized cubic, and another method uses parameters observations and a few GCPs. Through two methods, we get improvement of accuracy 50% and over.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.6
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• pp.649-656
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• 2011

A model for the numerical simulation of lithium-ion batteries (LIBs) is developed for use in battery cell design, with a view to improving the performances of such batteries. The model uses Newman-type electrochemical and transfer $theories^{(1,2)}$ to describe the behavior of the lithium-ion cell, together with the Levenberg-Marquardt optimization scheme to estimate the performance or design parameters in nonlinear problems. The mathematical model can provide an insight into the mechanism of LIB behavior during the charging/discharging process, and can therefore help to predict cell performance. Furthermore, by means of least-squares fitting to experimental discharge curves measured at room temperature, we were able to obtain the values of transport and kinetic parameters that are usually difficult to measure. By comparing the calculated data with the life-test discharge curves (SB LiMotive cell), we found that the capacity fade is strongly dependent on the decrease in the reaction area of active materials in the anode and cathode, as well as on the electrolyte diffusivity.

• Journal of the Institute of Electronics Engineers of Korea CI
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• v.43 no.1 s.307
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• pp.1-8
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• 2006

This thesis proposes Arithmetic Shift Register(ASR) which can be used as pseudo random number generator. Arithmetic Shift. Register is defined as progression that multiplies random number D , not 0 or 1 at initial value which is not 0, and it is represented as ASR-D in this thesis. Irreducible polynomial that t which makes $'D^k=1'$ satisfies uniquely as $'t=2^n-1'$ over. $GF(2^n)$ is the characteristic polynomial of ASR-D , and the cycle of Arithmetic Shift Register has maximum cycle as $'2^n-1'$. Galois Linear Feedback Shift Register corresponds to ASR-2-1. Therefore, Arithmetic Shift Register proposed in this thesis generalizes Galois Linear Feedback Shift Register. Linear complexity of ASR-D over$GF(2^n)$ is $'n{\leq}LC{\leq}\frac{n^2+n}{2}'$ and in comparison with existing Linear Feedback Shift Register stability is high. The Software embodiment of arithmetic shift register proposed in this thesis is efficient than that of existing Linear Shift Register and hardware complexity is equal. Arithmetic shift register proposed in this thesis can be used widely in various fields such as cipher, error correcting codes, Monte Carlo integral, and data communication etc along with existing linear shift register.