• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.487-495
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• 2023

Ammonia is either a crucial resource of fertilizer production for solving the food problem of mankind or an important energy source as both an eco-friendly hydrogen carrier and a carbon-free fuel. Therefore, nowadays ammonia synthesis and decomposition become promising. Then, a catalyst is required to effectively perform the ammonia synthesis and decomposition. In order to design high-performing as well as cheap novel catalysts for ammonia synthesis and decomposition, it is necessary to test huge amount of catalyst candidates, but it is inevitably time-consuming and expensive to search and analyze using only traditional approaches. Recently, new methods using machine learning which is one of the core technologies of the 4th industrial revolution that can quickly and accurately search high-performance catalysts has been emerging. In this paper, we investigate reaction mechanisms of ammonia synthesis and decomposition, and we described recent research and prospects of machine learning-driven methods that can efficiently find high-performing and economical catalysts for ammonia synthesis and decomposition.

• Proceedings of the Acoustical Society of Korea Conference
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• 1994.06a
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• pp.984-990
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• 1994

In this paper a new speech synthesis method in the time domain using mono-syllables is proposed. It is to overcome the degradation of the synthetic speech quality by the synthesis method in the frequency domain and to develop an algorithm in the time domain for the prosodic control. In particular when we use a method in a time domain with mono-syllable as a synthesis unit it will be the main issues which are to control th pitch period and to smooth the energy pattern. As a solution to the pitch control, a method using Lagrange interpolation is suggested. As a solution to the other problem, an algorithm which can control the amplitude envelop shape of mono-syllable is proposed. As the results of experiments it was possible to synthesize unlimited Korean speeches including the prosody control. Accoding to the MOS evaluation the quality and the naturality in them was improved to be a good level.

• The Journal of the Acoustical Society of Korea
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• v.38 no.5
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• pp.614-620
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• 2019

In this paper, we propose a method to effectively determine the representative style embedding of each emotion class to improve the global style token-based end-to-end speech synthesis system. The emotion expressiveness of conventional approach was limited because it utilized only one style representative per each emotion. We overcome the problem by extracting multiple number of representatives per each emotion using a k-means clustering algorithm. Through the results of listening tests, it is proved that the proposed method clearly express each emotion while distinguishing one emotion from others.

• ETRI Journal
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• v.44 no.1
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• pp.85-93
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• 2022

We propose an efficient method for synthesizing mesh-based realistic computer-generated hologram (CGH). In a previous nonanalytic mesh-based CGH synthesis, the angular spectrum of the two-dimensional (2D) plane is calculated using the fast Fourier transform (FFT) with the same size as the resolution of the final hologram. Because FFT increases the computation time as the size of the input matrix increases, the previous method has a problem: The higher the resolution of the hologram, the greater the computational load, thereby delaying synthesis time. In this study, when calculating the angular spectrum of the 2D plane in mesh-based CGH synthesis, we propose a method to calculate the angular spectrum by defining the 2D plane with an arbitrary size smaller than the resolution of the final hologram. The resolution adjustment method reduces the computation time and can be applied to occlusion culling and texturing for the realistic effect of mesh-based CGH. We describe the principle, error analysis, application of realistic effect, and experimental results of the proposed method.

• 제어로봇시스템학회:학술대회논문집
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• 1989.10a
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• pp.635-642
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• 1989

We formulated the multi-robot trajectory problem into a series of NLP problem, each of which is that of finding the optimal tip positions of the robots for the next time step. The NLP problem is composed of an objective function and three constraints, namely: a) Joint position limits, b) Joint velocity limits, and c) Collision-avoidance constraints. By solving a series of NLP problem, optimally coordinated trajectories can be determined without requiring any prior path information. This is a novel departure from the previous approach in which either all paths or at least one path is assumed to be given. Practical application of the developed method is for optimal synthesis of multiple robot trajectories in off-line. To test the validity and effectiveness of the method, numerical examples are illustrated.

• Journal of Institute of Control, Robotics and Systems
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• v.5 no.1
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• pp.1-10
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• 1999

We consider the problem of synthesizing an internally stabilizing linear time-invariant controller for a linear tune-Invariant plant such that a given closed loop transfer function is strictly sector bounded. We show that the standard $H{\infty}$ control problem and the $\tau$ -positive real control problem are special cases of sector bounded control problem. Necessary and sufficient conditions for the existence of a controller are obtained. The state-space representation for strictly proper controllers are given in terms of solutions to ARIs or AREs.

• 제어로봇시스템학회:학술대회논문집
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• 1987.10b
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• pp.547-549
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• 1987

The purpose of this paper is to present an efficient and practical method for a Hissle autopilot design problem. The method emphasizes on the use of a modern design technique to classical flight control specifications and the trade-off between dynamic performance and robustness of the Missle autopilot control system.

• Journal of Environmental Health Sciences
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• v.33 no.4
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• pp.317-324
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• 2007

The sewage treatment sludge disposal has become a serious environmental problem because of restricted direct land-filling and oceandumping in spite of their large amounts discharged. So the recycling of sewage treatment sludge is very useful alternative for waste management. Here, we studied the feasibility of zeolite synthesis in open system from the sewage treatment sludge incinerator fly ash by means of hydrothermal synthesis. We considered the concentration of NaOH, reaction time, reaction temperature and reaction step as synthesis variables. The phase of zeolite products was identified by X-ray diffractometer(XRD) and ammonium ion exchange test was performed for the raw fly ash and two zeolite products(Z-3 and Z-5). In leaching test of the raw fly ash, hazard metal is detected very low level compared with regulatory leaching test standard. But in total recoverable test, the total contents of the fly ash were very high in terms of the standard for waste-derived fertilizer. Through hydrothermal reaction, small amount of zeolite P was synthesied in 1 N of NaOH solution and relatively large amount of hydroxysodalite was synthesied in 3 N and 5 N of NaOH solution with similar peak intensity. Addition of an aging step in the synthesis didn't increase the amount of zeolite phase. Maximum $NE_4^+-N$ exchange capacity is 1.49 mg $NH_4^+-N/g$ in Z-3 and 1.38 mg $NH_4^+-N/g$ in Z-5. Most of the ammonium ion is exchanged in 30 minutes and disorption did not occur until 5 hours.

• Journal of the Korean Ceramic Society
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• v.44 no.12
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• pp.696-702
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• 2007

The family of (Sr,Mg)-doped $LaGaO_3$ compounds, which exhibit high ionic conductivity at $600-800^{\circ}C$ over a wide range of oxygen partial pressure, appears to be promising as the electrolyte for intermediate temperature solid oxide fuel cells. Conventional synthesis routes of (Sr,Mg)-doped $LaGaO_3$ compounds based on solid state reaction have some problems such as the formation of impurity phases, long sintering time and Ga loss during high temperature sintering. Phase stability problem especially, the formation of additional phases at the grain boundary is detrimental to the electrical properties of the electrolyte. From this point of view, we focused to synthesize single phase (Sr,Mg)-doped $LaGaO_3$ electrolyte at the stage of powder synthesis and to apply relatively low heat-treatment temperature using novel synthesis route based on combustion method. The synthesized powder and sintered bulk electrolytes were characterized by XRD, TG-DTA, FT-IR and SEM. AC impedance spectroscopy was used to characterize the electrical transport properties of the electrolyte with the consideration of the contribution of the bulk lattice and grain boundary to the total conductivity. Finally, relationship between synthesis condition and electrical properties of the (Sr, Mg)-doped $LaGaO_3$ electrolytes was discussed with the consideration of phase analysis results.

• Journal of Microbiology and Biotechnology
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• v.28 no.11
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• pp.1859-1864
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• 2018

Synthesis of flavonoid glycoside is difficult due to diverse hydroxy groups in flavonoids and sugars. As such, enzymatic synthesis or biotransformation is an approach to solve this problem. In this report, we used stepwise biotransformation to synthesize two quercetin bisglycosides (quercetin 3-O-glucuronic acid 7-O-rhamnoside [Q-GR] and quercetin 3-O-arabinose 7-O-rhamnoside [Q-AR]) because quercetin O-rhamnosides contain antiviral activity. Two sequential enzymatic reactions were required to synthesize these flavonoid glycosides. We first synthesized quercetin 3-O-glucuronic acid [Q-G], and quercetin 3-O-arabinose [Q-A] from quercetin using E. coli harboring specific uridine diphopsphate glycosyltransferase (UGT) and genes for UDP-glucuronic acid and UDP-arabinose, respectively. With each quercetin 3-O-glycoside, rhamnosylation using E. coli harboring UGT and the gene for UDP-rhamnose was conducted. This approach resulted in the production of 44.8 mg/l Q-GR and 45.1 mg/l Q-AR. This stepwise synthesis could be applicable to synthesize various natural product derivatives in case that the final yield of product was low due to the multistep reaction in one cell or when sequential synthesis is necessary in order to reduce the synthesis of byproducts.