• Title/Summary/Keyword: Pressure Exchange

Search Result 383, Processing Time 0.031 seconds

PERFORMANCE CHARACTERISTICS OF A PROTON EXCHANGE MEMBRANE FUEL CELL(PEMFC) WITH AN INTERDIGITATED FLOW CHANNEL

  • Lee, P.H.;Cho, S.A.;Han, S.S.;Hwang, S.S.
    • International Journal of Automotive Technology
    • /
    • v.8 no.6
    • /
    • pp.761-769
    • /
    • 2007
  • The configuration of the flow channel on a bipolar plate of a proton exchange membrane fuel cell(PEMFC) for efficient reactant supply has great influence on the performance of the fuel cell. Recent demand for higher energy density fuel cells requires an increase in current density at mid voltage range and a decrease in concentration overvoltage at high current density. Therefore, an interdigitated flow channel where mass transfer rate by convection through a gas diffusion layer is greater than the mass transfer by a diffusion mechanism through a gas diffusion layer was recently proposed. This study attempts to analyze the i-V performance, mass transfer and pressure drop in interdigitated flow channels by developing a fully three dimensional simulation model for PEMFC that can deal with anode and cathode flow together. The results indicate that the trade off between performance and pressure loss should be considered for efficient design of flow channels. Although the performance of the fuel cell with interdigitated flow is better than that with conventional flow channels due to a strong mass transfer rate by convection across a gas diffusion layer, there is also an increase in friction due to the strong convection through the porous diffusion layer accompanied by a larger pressure drop along the flow channel. It was evident that the proper selection of the ratio of channel and rib width under counter flow conditions in the fuel cell with interdigitated flow are necessary to optimize the interdigitated flow field design.

Magnetoresistive heads with dual exchange bias using $NiFe/TbCo/Si_3N_4$ thin films (자기 저항 헤드의 이중 자기 교환 바이어스를 위한 $NiFe/TbCo/Si_3N_4$ 박막제조)

  • 김영채;오장근;조순철
    • Journal of the Korean Magnetics Society
    • /
    • v.4 no.3
    • /
    • pp.239-243
    • /
    • 1994
  • $NiFe/TbCo/Si_3N_4$ thin films were fabricated, which can be employed as dualOongitudinal and transverse) biased magnetoresistive elements utilizing surface magnetic exchange at the interface of NiFe/TbCo films. When Tb area percent was 36 % and substrate bias was not applied, magnetic exchange fields of 100~180 Oe were obtained. The thicknesses of NiFe, TbCo and $Si_3N_4$(Protective layer) were $470\;{\AA},\;2400\;{\AA}\;and\;600\;{\AA}$, respectively. Magnetoresistance ratio of 1.45 % was obtained using NiFe films fabricated with 1000 W power and 2.5 mTorr of Ar pressure. The MR ratio of microstructured elements was reduced to 1.31 % and the MR response curves were shown not to saturate due to demagnetizing fields of the elements. When elements were fabricated with $36^{\circ}$ of misalignment with respect to the exchange field direction using films having 150 Oe exchange field, MR response curve was shifted by 85 Oe, and the operating point of the device shifted to the linear region of the response. Also, the Barkhausen noise was eiminated due to longitudinal bias field originating from the exchange field.

  • PDF

High Efficiency Hybrid Ion Exchange Chemical Filter for Removal of Acidic Harmful Gases (산성유해가스 제거를 위한 고효율 음이온교환 복합 폼 화학필터의 제조)

  • Jung, Youn Seo;Kim, In Sik;Hyeon, Seung Mi;Hwang, Taek Sung
    • Applied Chemistry for Engineering
    • /
    • v.28 no.5
    • /
    • pp.539-546
    • /
    • 2017
  • In this study, an outstanding anion exchange chemical filter was prepared for acidic gas removal. Commercial anion exchange resin was attached to polyurethane (PU) foam by using different types of pressure sensitive adhesive (PSA). The water and chemical resistance and also adhesive elongation were investigated. Also, the behavior of HCl and HF adsorption was evaluated as functions of the initial concentration and flow rate. ATE-701, AT-4000C and HCA-1000 showed 900, 1,500% and 2,400% of the elongation, respectively. It was confirmed that the desorption ratio of HCA-1000 was less than 6% and had excellent durability in water and chemical resistance tests. The adsorption occurred faster as the concentration and flow rate of HCl and HF increased. But 100% adsorption equilibrium occurred after 110 minutes, regardless of the concentration and flow rate. In addition, SEM morphology showed that the adhesive was uniformly dispersed, while the porous structure of the ion exchange resin was maintained, and the chemical filter exhibited excellent durability for the adsorption/desorption process.

Optimization of fabrication and process conditions for highly uniform and durable cobalt oxide electrodes for anion exchange membrane water electrolysis (음이온 교환막 수전해 적용을 위한 고균일 고내구 코발트 산화물 전극의 제조 및 공정 조건 최적화)

  • Hoseok Lee;Shin-Woo Myeong;Jun-young Park;Eon-ju Park;Sungjun Heo;Nam-In Kim;Jae-hun Lee;Jae-hun Lee;Jae-Yeop Jeong;Song Jin;Jooyoung Lee;Sang Ho Lee;Chiho Kim;Sung Mook Choi
    • Journal of the Korean institute of surface engineering
    • /
    • v.56 no.6
    • /
    • pp.412-419
    • /
    • 2023
  • Anion exchange membrane electrolysis is considered a promising next-generation hydrogen production technology that can produce low-cost, clean hydrogen. However, anion exchange membrane electrolysis technology is in its early stages of development and requires intensive research on electrodes, which are a key component of the catalyst-system interface. In this study, we optimized the pressure conditions of the hot-pressing process to manufacture cobalt oxide electrodes for the development of a high uniformity and high adhesion electrode production process for the oxygen evolution reaction. As the pressure increased, the reduction of pores within the electrode and increased densification of catalytic particles led to the formation of a uniform electrode surface. The cobalt oxide electrode optimized for pressure conditions exhibited improved catalytic activity and durability. The optimized electrode was used as the anode in an AEMWE single cell, exhibiting a current density of 1.53 A cm-2 at a cell voltage of 1.85 V. In a durability test conducted for 100 h at a constant current density of 500 mA cm-2, it demonstrated excellent durability with a low degradation rate of 15.9 mV kh-1, maintaining 99% of its initial performance.

Performance Characteristics of PEMFC by flow Configurations and Operating Condition (유로형상 및 운전조건에 따른 고분자 전해질 연료전지의 성능 특성)

  • Lee, Pil-Hyong;Cho, Son-Ah;Han, Sang-Seok;Hwang, Sang-Soon
    • Proceedings of the KSME Conference
    • /
    • 2007.05b
    • /
    • pp.3440-3445
    • /
    • 2007
  • For proton exchange membrane fuel cell, it is very important to design the flow channel on separation plate optimally to maximize the current density at same electrochemical reaction surface and reduce the concentration polarization occurred at high current density. In this paper, three dimensional computation model including anode and cathode domain together was developed to examine effects of flow patterns and operation conditions such as humidity and operating temperature on performance of fuel cell. Results show that voltage at counter flow condition is higher than that at coflow condition in parallel and interdigitated flow pattern. And fuel cell with interdigitated flow pattern which has better mass transport by convection flow through gas diffusion layer has higher performance than with parallel flow pattern but its pressure drop is increased such that the trade off between performance and pressure drop should be considered for selection of flow pattern of fuel cell.

  • PDF

Aluminum and Plastic Heat Exchange Element : A Performance Comparison for Cooling of Telecommunication Cabinet (통신 함체 냉각용 알루미늄과 플라스틱 열교환 소자의 성능 비교)

  • Kim, Nae-Hyun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.29 no.6
    • /
    • pp.279-288
    • /
    • 2017
  • Heat generation rate in a telecommunication cabinet increases due to the continued usage of mobile devices. Insufficient removal of heat intensifies the cabinet temperature, resulting in the malfunction of electronic devices. In this study, we assessed both aluminum and plastic heat exchangers used for cooling of the telecommunication cabinet, and compared the results against theoretical predictions. The aluminum heat exchanger was composed of counter flow parallel channels of 4.5 mm pitch, and the plastic heat exchangers were composed of cross flow triangular channels of 2.0 mm pitch. Samples were made by installing two plastic heat exchangers in both series and parallel. Results showed that the heat transfer rate was highest for the series cross flow heat exchanger, and was least for the aluminum heat exchanger. The temperature efficiency of the series cross flow heat exchanger was 59% greater than that of the aluminum heat exchanger, and was 4.3% greater than that of the parallel cross flow heat exchanger. In contrast, the pressure drop of the parallel cross flow heat exchanger was significantly lower than other samples. The heat exchange efficiency was also the largest for the parallel cross flow heat exchanger. The theoretical analysis predicted the temperature efficiency to be within 3.3%, and the pressure drop within 6.1%.

Thermal and Flow Analysis in a Proton Exchange Membrane Fuel Cell

  • Jung, Hye-Mi;Koo, Ja-Ye
    • Journal of Mechanical Science and Technology
    • /
    • v.17 no.9
    • /
    • pp.1358-1370
    • /
    • 2003
  • The effects of anode, cathode, and cooling channels for a Proton Exchange Membrane Fuel Cell (PEMFC) on flow fields have been investigated numerically. Continuous open-faced fluid flow channels formed in the surface of the bipolar plates traverse the central area of the plate surface in a plurality of passes such as a serpentine manner. The pressure distributions and velocity profiles of the hydrogen, air and water channels on bipolar plates of the PEMFC are analyzed using a two-dimensional simulation. The conservation equations of mass, momentum, and energy in the three-dimensional flow solver are modified to include electro-chemical characteristics of the fuel cell. In our three-dimensional numerical simulations, the operation of electro-chemical in Membrane Electrolyte Assembly (MEA) is assumed to be steady-state, involving multi-species. Supplied gases are consumed by chemical reaction. The distributions of oxygen and hydrogen concentration with constant humidity are calculated. The concentration of hydrogen is the highest at the center region of the active area, while the concentration of oxygen is the highest at the inlet region. The flow and thermal profiles are evaluated to determine the flow patterns of gas supplied and cooling plates for an optimal fuel cell stack design.

Operating Conditions of Proton Exchange Membrane Fuel Cell Using Grafoil$^{TM}$ as Bipolar Plates (그라포일 분리판을 이용한 고분자 전해질 연료전지의 운전 조건에 관한 연구)

  • Park, Taehyun;Chang, Ikwhang;Lee, Yoon Ho;Lee, Juhyung;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2011.11a
    • /
    • pp.85.1-85.1
    • /
    • 2011
  • In this study, Grafoil$^{TM}$ which has comparable electric resistance and chemical stability but is flexible, fragile, and cheap material was adopted as bipolar plates for proton exchange membrane fuel cell(PEMFC) having only one straight line flow channel. Because of its flexibility, pressurizations of cell with various pressures showed different operating characteristics compared to ordinary graphite-used PEMFC. While performances of both cells decreased as these were pressurized, investigation of ohmic and faradaic resistance by electrochemical impedance measurement indicated different tendency of change. Ohmic resistance of graphite-used cell increased with increasing pressure, which is reversed in Grafoil$^{TM}$-used cell. It is speculated that effective chemical reaction area is decreased with increasing pressure in case of graphite-used one, but because of flexible property of Grafoil$^{TM}$, gas diffusion layer in Grafoil$^{TM}$-used cell was well-activated. Different rate of change of faradaic resistances in both cells support this supposition. However, although optimum point of pressurization is found, it is required to investigate other operating conditions because of low performance compared to graphite-used cell.

  • PDF

Condensing Performance Evaluation in Smooth and Micro-Fin Tubes for Natural Mixture Refrigerant (Propane/Butane) (프로판/부탄 혼합자연냉매의 평활관과 마이크로핀관 내의 응축성능평가)

  • Lee Sang-Mu;Lee Joo-Dong;Park Byung-Duck
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.17 no.9
    • /
    • pp.816-823
    • /
    • 2005
  • This paper deals with the heat exchange performance prediction of a counter flow type double-tube condenser for natural refrigerant mixtures composed of Propane/n-Butane or Propane/i-Butane in a smooth tube and a micro-fin tube. The local characteristics of heat transfer, mass transfer and pressure drop are calculated using a prediction method developed by the authors. The total pressure drop and the overall heat transfer coefficient are also evaluated on various heat exchange conditions. The calculated results of the natural refrigerant mixtures are compared with HCFC22. In conclusion, natural refrigerant mixtures composed of Propane/n-Butane or Propane/i-Butane are appropriate candidates for alternative refrigerant from the viewpoint of heat transfer characteristics.