• Bulletin of the Korean Chemical Society
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• v.13 no.5
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• pp.486-491
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• 1992

The rate constants for the reactions of p-nitrophenyl acetate with 6 different aryloxides and 2 benzohydroxamates have been measured spectrophotometrically in water containing various concentrations of cetyltrimethylammonium bromide (CTAB). The reactivity of the nucleophiles has been demonstrated to be significantly enhanced as the concentration of the surfactant increases up to a certain point. When the basicities of the aryloxides are comparable, the rate enhancement is more prominent for the aryloxide having larger binding constant to the micellar aggregate. Benzohydroxamates exhibitis significantly large ${\alpha}$-effect in the absence of the surfactant, although, the ${\alpha}$-effect nucleophiles are considered to be more solvated in water than the corresponding normal nucleophile. Thus, the solvation effect does not appear to be solely responsible for the ${\alpha}$-effect. Interestingly, the large ${\alpha}$-effect disappears in the presence of the surfactant. Therefore, one might attribute the disappearance of the ${\alpha}$-effect to solvent effect. However, a structural change of the reactive ${\alpha}$ -effect nucleophile into unreactive ones would also be considered to be responsible for the absence of the ${\alpha}$-effect in the present system.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.2
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• pp.58-63
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• 2000

The dynamics of spindle-bearing-workpiece system significantly affects the cutting condition and stability in milling process. The present paper investigates the chatter stability of milling process due to the change in the dynamics of spindle-bearing-workpiece systems. In particular, the present paper focuses on chatter stability due to the presence of gyroscopic effect. An eigenvalue problem approach to the stability of milling process is extensively used in this paper. To incorporate the rotational speed dependent gyroscopic effect, an iterative algorithm is proposed. A numerical example is provided for examining the chatter stability problem in the presence of gyroscopic effects.

• International Journal of Industrial Entomology and Biomaterials
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• v.27 no.2
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• pp.326-328
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• 2013

Sericin undergoes gelation by the structural transition from random coil to b-sheet transition. In the present study, the gelation time of sericin solution was investigated in the presence of NaCl, KCl and $CaCl_2$. The addition of salts delayed the gelation time, and $CaCl_2$ had the most pronounced effect, which delayed about 8 h at maximum. The gelation time increased with the concentration of salt. The transition of secondary structure of sericin was retarded in the presence of salt. The effect of salts on the gelation time of sericin might be due to the solvation effect of relevant cation.

• Journal of Digital Convergence
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• v.10 no.10
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• pp.139-146
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• 2012

The emotional factor has not been focused in e-learning studies. But the emotions of student are very important in e-learning because it is a self-regulated learning. This study is focused on the emotional factor in e-learning. This study examines the effect of perceived customer orientation to emotional presence, commitment and customer satisfaction in e-learning. The results of this study showed that the perceived customer orientation effect to the commitment about the learning and the customer satisfaction in e-learning.

• Environmental Engineering Research
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• v.16 no.3
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• pp.149-157
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• 2011

Nanofiltration (NF) experiments were conducted to investigate fouling of Al-hydroxide precipitate and the influence of organic compound, inorganic compound, and their combination, i.e., multiple foulants. $CaCl_2$ and $MgSO_4$ were employed as surrogates of inorganic compounds while humic acid was used as surrogate of organic compound. The flux attained from NF experiments was fitted with the mathematical fouling model to evaluate the potential fouling mechanisms. Al-hydroxide fouling with a cake formation mechanism had little effect on the NF membrane fouling regardless of the Al concentration. The NF fouling by Al-hydroxide precipitate was deteriorated in presence of inorganic matter. The effect of Mg was more critical in increasing the fouling than Ca. This is because the Mg ions enhanced the resistances of the cake layer accumulated by the Al-hydroxide precipitate on the membrane surfaces. However, the fouling with Mg was dramatically mitigated by adding humic acid. It is interesting to observe that the removal of the conductivity was enhanced to 61.2% in presence of Mg and humic acid from 30.9% with Al-hydroxide alone. The influence of dissolved matter (i.e., colloids) was more negative than particulate matter on the NF fouling for Al-hydroxide precipitate in presence of inorganic and organic matter.

• Carbon letters
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• v.11 no.4
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• pp.325-331
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• 2010

This study investigates the effect of filler content (wt%), presence of interphase and agglomerates on the effective Young's modulus of polypropylene (PP) based nanocomposites reinforced with exfoliated graphite nanoplatelets ($xGnP^{TM}$) and carbon nanotubes (CNTs). The Young's modulus of the composites is determined using tensile testing based on ASTM D638. The reinforcement/polymer interphase is characterized in terms of width and mechanical properties using atomic force microscopy which is also used to investigate the presence and size of agglomerates. It is found that the interphase has an average width of ~30 nm and modulus in the range of 5 to 12 GPa. The Halpin-Tsai micromechanical model is modified to account for the effect of interphase and filler agglomerates and the model predictions for the effective modulus of the composites are compared to the experimental data. The presented results highlight the need of considering various experimentally observed filler characteristics such as agglomerate size and aspect ratio and presence and properties of interphase in the micromechanical models in order to develop better design tools to fabricate multifunctional polymer nanocomposites with engineered properties.

• YAKHAK HOEJI
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• v.59 no.5
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• pp.201-206
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• 2015

The aim of the present study was to optimize in vitro method for the prediction of drug-induced liver injury using human liver microsomes (HLM). Cytotoxicity test of cyclophosphamide and acetaminophen in HepG2 cells cultured with HLM showed that the newly established condition using 0.375 mg/ml HLM for 24 hr incubation was comparable or more sensitive than the previously established condition using 0.75 mg/ml HLM for 12 hr incubation. Although the cytotoxic effect of troglitazone was completely attenuated by 0.75 mg/ml HLM, it was augmented by 0.375 mg/ml HLM in the presence of the NADPH-generating system. The cytotoxic effect of chlormezanone, a withdrawn drug due to hepatotoxicity in human, was increased by HLM in the presence of the NADPH-generating system. In contrast, the cytotoxic effect of methapyrilene, a withdrawn drug due to hepatotoxicity in rats, was decreased by HLM in the presence of the NADPH-generating system. The present study suggests that the optimized in vitro method using HLM can be useful for the prediction of drug-induced hepatotoxicity.

• Macromolecular Research
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• v.14 no.3
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• pp.261-266
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• 2006

Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared using a melt blending technique in the presence and absence of glass fiber and coupling agents. The effect of glass fiber and coupling agents on the thermal, dynamic mechanical, morphological pro-perties and cure characteristics of VMQ/LCP blends were studied. The vinyl silane coupling agent showed a significant effect on the above mentioned properties of VMQ/LCP blends by reacting at the interface between VMQ and LCP. The viscosity of the VMQ/LCP blends decreased with the addition of a coupling agent. A substantial improvement in storage modulus of VMQ/LCP blends was observed in the presence of glass fiber and coupling agents. However, as a coupling agent vinyl silane proved to be better than amine for the VMQ/LCP-glass-containing blends. The thermal stability of the pure silicone rubber was higher than those of the blends. This high thermal stability of silicone rubber was attributed to the Si-O-Si bonds. However, the thermal stability of the blends decreased further in the presence of a coupling agent, possibly due to a decrease in blend crystallinity.

• Journal of the Korean Society of Clothing and Textiles
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• v.47 no.2
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• pp.371-391
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• 2023

This study examines the impact of live commerce characteristics on customer responses in the ELM perspective. Based on ELM, the central route is composed of information completeness, accuracy, and currency, and the peripheral route is composed of streamer credibility, streamer reputation, social presence, and system quality. An online survey of female customers aged 20 to 49 who have purchased beauty products through live commerce within the past three months was conducted. The results demonstrate that information completeness and information currency exert significant impact on perceived usefulness and enjoyment. Social presence and system quality also exert significant impact on perceived usefulness and enjoyment. Moreover, perceived usefulness and enjoyment had significant impact on behavioral intention. The effect of information completeness on perceived usefulness and enjoyment was much stronger for high product involvement groups. Furthermore, the effect of streamer reputation on perceived enjoyment was much stronger for high product involvement groups. In contrast, the effect of social presence on perceived usefulness and enjoyment was much stronger for low product involvement groups. This study suggests theoretical implications for applying ELM to live commerce and practical implications for differentiated live commerce marketing strategies.

• The Research Journal of the Costume Culture
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• v.31 no.1
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• pp.1-17
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• 2023

This study analyzed requirements for medical masks and difference in satisfaction based on demographic characteristics and side effects experience caused by wearing medical masks. Three factors related to requirements for medical masks were identified: wearing comfort and usability, blocking function for harmfulness, and design. As a result of the difference analysis for requirements of medical masks based on demographic characteristics, all three factors showed a significant difference in gender and occupation. Design did in age and monthly income. As a result of the presence or absence of breathing difficulties experience, design factor was significant. As a result of the presence or absence of skin trouble experience, wearing comfort and usability showed a significant difference. As a result of the difference in satisfaction with medical masks based on demographic characteristics and side effect experience caused by wearing medical masks, breathing, ear string tightness, blocking harmful substances, price, and over all wearing comfort showed a significant difference by gender, marital status, age, occupation, and monthly income, and the presence of absence of breathing difficulty experience and skin trouble experience, respectively. As a result of the interaction effect analysis between demographic characteristics and side effects experience caused by wearing medical masks, it showed a significant interaction effect between gender and monthly income, between marital status and monthly income, between monthly income and breathing difficulties experience, and between monthly income and skin trouble experience.