• Title/Summary/Keyword: Precursor approach

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An Observer-Theoretic Approach to Estimating Neutron Flux and Precursor Spatial Distributions (중성자속과 프리커서의 공간분포 추정을 위한 옵저버 이론 방법)

  • Park, Young-Ho;Cho, Nam-Zin
    • Nuclear Engineering and Technology
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    • v.22 no.2
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    • pp.139-150
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    • 1990
  • This paper describes a method for estimating the flux and precursor spatial distributions using only limited flux measurements. It is based on the Luenberger observer in control theory, extended to the distributed parameter systems such as the space-time reactor dynamics equation. The results of the application of the method to simple reactor models showed that the flux distribution could be estimated by the observer very efficiently using information from only a few sensors.

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Effect of Grain Growth Inhibitor on Sintering of Nanophase WC-10wt%Co (초미립 WC-l0wt%Co 초경 분말의 소결시 입자 성장 억제제 첨가 효과 연구)

  • 김병기
    • Journal of Powder Materials
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    • v.1 no.2
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    • pp.208-216
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    • 1994
  • A radically new approach to the in situ synthesis of the consituent phases of a composite structure has enabled the production of a new WC/Co materials with an ultrafine microstructure. The process for synthesizing nanophase WC/Co powders consists of spray drying from solution to form a homogeneous precursor powder, and thermochemical conversion of the precursor powder to the nanophase WC/Co powder. Near theoretical density of pure nanophase WC-10 wt%Co has been obtained in only 30 sec at 140$0^{\circ}C$. But WC particles were grown up very rapidly with longer sintering time to get full density. To overcome coarsening of WC particle during sintering, VC, TaC and VC/TaC were used as the grain growth inhibitor with different amount respectively. VC/TaC doped WC-10 wt%Co was shown superior hardness and TRS and microstructure was maintained ultrafine scale (average WC size is less than 0.1 ${\mu}{\textrm}{m}$).

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Experimental Study of the Growth of the SiC Rod using Nd-Yag Laser Chemical Vapor Deposition (Nd-Yag 레이저 화학증착을 이용한 SiC 로드 성장에 관한 실험적 연구)

  • Lim, Young;Ryu, Jae-Eun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.4
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    • pp.481-488
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    • 2004
  • Laser chemical vapor deposition can be used as a new approach for a rapid prototyping technique. The purpose of the study is to fabricate several 3-dimensional objects that are relatively simple as well as to find the characteristics of SiC rod growth that is the first step in developing a new rapid prototyping technique with laser chemical vapor deposition. In the study, SiC rods were generated with varying precursor pressure for 5 minutes. Deposition rates with varying precursor pressure, shapes of rods, surface roughness and component organization were investigated, in particular. Finally, several simple objects like a branch or a propeller were successfully fabricated using laser chemical vapor deposition.

Effect of Encapsulation Ratio on the Phase Transition Kinetics of the SiO2 Encapsulated Paraffin Phase Change Materials (SiO2 캡슐화 파라핀 상변화 물질의 상전이 역학에 대한 캡슐화 비율의 영향)

  • Soumen, Mandal;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.99-100
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    • 2023
  • In this study, an approach has been made to understand the effect of encapsulation thickness of the nanoencapsulated PCMs on the phase transition kinetics. Paraffin is encapsulated by silica via single pot polycondensation reaction. Different ratios of silica precursor are chosen to encapsulate paraffin. The obtained encapsulated PCMs are identified as nano sized, as well as with increasing silica precursor, thicker silica encapsulations have been manifested with shrinking core diameter. The synthesized PCMs are characterized using various characterization techniques. Isochronal kinetic studies are done in differential scanning calorimeter (DSC) to understand about their phase transformation behaviors. This study can appreciate the cognition of the large-scale applications of PCMs into the building constructions as well as the fundamental conception on the phase transition kinetics of PCMs can also be amended.

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Introducing an Efficient and Eco-Friendly Spray-Drying Process for the Synthesis of NCM Precursor for Lithium-ion Batteries

  • Hye-Jin Park;Seong-Ju Sim;Bong-Soo Jin;Hyun-Soo Kim
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.168-177
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    • 2024
  • Ni-rich cathode is one of the promising candidates for high-energy lithium-ion battery applications. Due to its specific capacity, easy industrialization, and good circulation ability, Ni-rich cathode materials have been widely used for lithium-ion batteries. However, due to the limitation of the co-precipitation method, including sewage pollution, and the instability of the long production cycles, developing a new efficient and environmentally friendly synthetic approach is critical. In this study, the Ni0.91Co0.06Mn0.03CO3 precursor powder was successfully synthesized by an efficient spray-drying method using carbonate compounds as a raw material. This Ni0.91Co0.06Mn0.03CO3 precursor was calcined by mixing with LiOH·H2O (5 wt% excess) at 480℃ for 5 hours and then sintered at two different temperatures (780℃/800℃) for 15 hours under an oxygen atmosphere to complete the cathode active material preparation, which is a key component of lithium-ion batteries. As a result, LiNi0.91Co0.06Mn0.03O2 cathode active material powders were obtained successfully via a simple sintering process on the Ni0.91Co0.06Mn0.03CO3 precursor powder. Furthermore, the obtained LiNi0.91Co0.06Mn0.03O2 cathode active material powders were characterized. Overall, the material sintered at 780℃ shows superior electrochemical performance by delivering a discharge capacity of 190.76 mAh/g at 1st cycle (0.1 C) and excellent capacity retention of 66.80% even after 50 cycles.

Gas Chromatography-High Resolution Tandem Mass Spectrometry Using a GC-APPI-LIT Orbitrap for Complex Volatile Compounds Analysis

  • Lee, Young-Jin;Smith, Erica A.;Jun, Ji-Hyun
    • Mass Spectrometry Letters
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    • v.3 no.2
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    • pp.29-38
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    • 2012
  • A new approach of volatile compounds analysis is proposed using a linear ion trap Orbitrap mass spectrometer coupled with gas chromatography through an atmospheric pressure photoionization interface. In the proposed GC-HRMS/MS approach, direct chemical composition analysis is made for the precursor ions in high resolution MS spectra and the structural identifications were made through the database search of high quality MS/MS spectra. Successful analysis of a complex perfume sample was demonstrated and compared with GC-EI-Q and GC-EI-TOF. The current approach is complementary to conventional GC-EI-MS analysis and can identify low abundance co-eluting compounds. Toluene co-sprayed as a dopant through API probe significantly enhanced ionization of certain compounds and reduced oxidation during the ionization.

Prediction of Ozone Concentration in Suwon by Empirical Kinetic Modeling Approach (EKMA를 이용한 수원시의 장래 오존농도 예측)

  • 서정배;장영기
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.368-370
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    • 1999
  • 고농도의 오존 농도를 예측ㆍ평가하기 위해서는 대상지역의 기상조건과 풍상쪽(up wind)으로부터의 오존ㆍ오존전구물질(precursor)의 중ㆍ장거리이동, VOCs 및 NOx의 배경농도 및 배출량과 관련된 VOC/NOx의 농도 특성을 파악하는 것이 필수적이다. 따라서 대상지역의 VOCs/NOx의 농도 특성에 따라 차후 고농도의 오존 생성을 예방하기 위한 오존전구물질의 저감대책이 결정되어지므로 대상지역의 광화학특성을 파악하는 것이 선행되어져야 한다.(중략)

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Fabrication of YBCO films on metal tapes by the TFA-MOD process (TFA-MOD법에 의한 금속기판 위 YBCO 박막 제조)

  • Shin Geo-Myung;Song Kyu-Jung;Park Chan;Moon Seung-Hyun;Yoo Sang-Im
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.92-96
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    • 2005
  • YBCO thin films on metal substrates were prepared by the metal-organic deposition using trifluoroacetates (TFA-MOD). To compensate the loss of Ba element from the precursor films due to the reaction with $CeO_2$ cap layer, we have employed Ba-excessive precursor solutions of $YBa_{2+x}Cu_{3}O_{7-{\delta}}$ ($0{\le}x{\le}0.1$). The precursor solutions were dip-coated on the metal substrates with $CeO_2$ cap layer, initially heated up to $400^{\circ}C$, and finally fired at the various high temperatures for 2 h in a reduced oxygen atmosphere. With this approach, YBCO films possessing critical temperature over 85 K could be successfully prepared on the metal substrates. The highest $T_{c,zero}$ value of 86 K was obtained from the Ba-excessive YBCO film of x=0.005 in $YBa_{2+x}Cu_{3}O_{7-{\delta}}$ fired at $750^{\circ}C$ for 2 h. However, unexpected $T_c$ suppression even in Ba-excessive YBCO samples requires further identification.

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Interobserver Variation in the Diagnosis of Gastric Epithelial Dysplasia and Carcinoma between Two Pathologists in Japan and Korea

  • Kushima, Ryoji;Kim, Kyoung-Mee
    • Journal of Gastric Cancer
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    • v.11 no.3
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    • pp.141-145
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    • 2011
  • Although the biological potential of gastric epithelial dysplasia (GED) as a precursor of gastric cancer has never been in doubt, the classification of these lesions has been controversial and fraught with marked variations in approach to diagnosis across the world. The complexity of cyto-architectural features has been considered to be of paramount importance for the diagnosis of carcinoma in Japan, while breach of the basement membrane and invasion into the lamina propria has been considered the sine qua non of malignancy and hence a pre-requisite for the diagnosis of cancer in the West. In Korea, although the incidence of gastric cancer is similar to Japan, the diagnostic approach to GED or cancer seems to lie midway between Western and Japanese criteria. In this review, we will discuss the difference in the diagnosis of GED and cancer between two pathologists working in the comprehensive cancer center located in Japan and Korea, one of the most prevalent areas in the world for gastric cancer.

Numerical Study of Sound Generation Mechanism by a Blast Wave (폭발파에 의한 음향파 생성 메커니즘의 수치적 연구)

  • Bin, Jong-Hoon
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.10
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    • pp.1053-1061
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    • 2009
  • The goal of this paper is to investigate the generation characteristics of the main impulsive noise sources generated by the supersonic flow discharging from a muzzle. For this, this paper investigates two fundamental mechanisms to sound generation in shocked flows: shock motion and shock deformation. Shock motion is modeled numerically by examining the interaction of a sound wave with a shock. The numerical approach is validated by comparison with results obtained by linear theory for a small disturbance case. Shock deformations are modeled numerically by examining the interaction of a vortex ring with a blast wave. A numerical approach of a dispersion-relation-preserving(DRP) scheme is used to investigate the sound generation and propagation by their interactions in near-field.