• 제목/요약/키워드: Potential theory

검색결과 1,546건 처리시간 0.03초

Does the Gaseous Aniline Cation Isomerize to Methylpyridine Cations Before Dissociation?

  • Choe, Joong Chul
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3249-3252
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    • 2013
  • We have explored the potential energy surface for the isomerization of the aniline (AN) radical cation to the 2-, 3-, and 4-methylpyridine (picoline, MP) radical cations using G3 model calculations. The isomerization may occur through the 1H-azepine (7-aza-cycloheptatriene) radical cation. A quantitative kinetic analysis has been performed using the Rice-Ramsperger-Kassel-Marcus theory, based on the potential energy surface. The result shows that isomerization between $AN^{+\bullet}$ and each $MP^{+\bullet}$ hardly occurs before their dissociations.

천수에서 2차원 수치파 수조에 대한 계산 (A Numerical Study on 2-Dimensuional Tank with Shallow Draft)

  • 임춘규
    • 한국해양공학회지
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    • 제14권1호
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    • pp.1-5
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    • 2000
  • A numerical analysis for wave motion in the shallow water is presented. The method is based on potential theory. The fully nonlinear free surface boundary condition is assumed in an inner domain and this solution is matched along an assumed common boundary to a linear solution in outer domain. In two-dimensional problem Cauchy's integral theorem is applied to calculate the complex potential and its time derivative along boundary.

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진동삼축시험에 기초한 액상화 평가 (Assessment of Liquefaction Potential based on the Cyclic Triaxial Test)

  • 최재순
    • 한국지진공학회:학술대회논문집
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    • 한국지진공학회 1999년도 춘계 학술발표회 논문집 Proceedings of EESK Conference-Spring
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    • pp.77-84
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    • 1999
  • An assessment of liquefaction potential is made in principle by comparing earthquake induced shear stress to the liquefaction strength of the soil. In this research a modified method based on Seed and Idriss theory is developed for evaluating liquefaction strength of Jumunjon sand(Korean standard sand). Also the factors affecting liquefaction strenght such as cyclic shear stress amplitude and relative density are investigated and verified by using cyclic triaxial test. From the result the new relationships between cyclic shear stress ratio and number of load cycles are proposed for evaluating liquefaction strength under moderated magnitude(M=6.5) of earthquake.

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Temperature Dependence of Galvanomagnetic Properties in Thin Bi Film

  • Nam, S.W.
    • Journal of Magnetics
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    • 제4권4호
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    • pp.111-114
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    • 1999
  • Numerical calculation for temperature dependence of galvanomagnetic properties of thin bismuth films is pursued. The quasi-two dimensional system is treated in the perturbation formalism of previous study, where realistic screened potential due to impurity is assumed to be the only scattering channel. The potential is separated into pure two dimensional part and the remaining presumed perturbation part. Relaxation time and mobilities for both electron and hole are evaluated, then temperature dependence of the Hall coefficient and magnetoresistance is obtained. The broad minimum of magnetoresistnace is manifested, and the interpretation under the kinetic theory is made. Thickness dependence of the quantities are also shown, which are in good agreement with the expected quantum size effect.

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Cylindrical bending of multilayered composite laminates and sandwiches

  • Sayyad, Atteshamuddin S.;Ghugal, Yuwaraj M.
    • Advances in aircraft and spacecraft science
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    • 제3권2호
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    • pp.113-148
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    • 2016
  • In a whole variety of higher order plate theories existing in the literature no consideration is given to the transverse normal strain / deformation effects on flexural response when these higher order theories are applied to shear flexible composite plates in view of minimizing the number of unknown variables. The objective of this study is to carry out cylindrical bending of simply supported laminated composite and sandwich plates using sinusoidal shear and normal deformation plate theory. The most important feature of the present theory is that it includes the effects of transverse normal strain/deformation. The displacement field of the presented theory is built upon classical plate theory and uses sine and cosine functions in terms of thickness coordinate to include the effects of shear deformation and transverse normal strain. The theory accounts for realistic variation of the transverse shear stress through the thickness and satisfies the shear stress free conditions at the top and bottom surfaces of the plate without using the problem dependent shear correction factor. Governing equations and boundary conditions of the theory are obtained using the principle of minimum potential energy. The accuracy of the proposed theory is examined for several configurations of laminates under various static loadings. Some problems are presented for the first time in this paper which can become the base for future research. For the comparison purpose, the numerical results are also generated by using higher order shear deformation theory of Reddy, first-order shear deformation plate theory of Mindlin and classical plate theory. The numerical results show that the present theory provides displacements and stresses very accurately as compared to those obtained by using other theories.

탄성지반위에 놓인 비국소 자기-전기-탄성 나노 판의 구조안정해석 (Structural stability analysis of nonlocal Megneto-Electro-Elastic(MEE) nano plates on elastic foundation)

  • 한성천;박원태
    • 한국산학기술학회논문지
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    • 제18권9호
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    • pp.52-60
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    • 2017
  • 본 논문은 탄성지반위에 놓인 비국소 자기-전기-탄성 나노 판의 구조안정에 관하여 1차 전단변형이론을 이용하여 분석하였다. 4변이 단순지지된 자기-전기-탄성 나노 판의 좌굴하중을 구하기 위하여 Navier 방법을 적용하였다. 기존의 연구들에서는 2방향 좌굴해석은 거의 연구되지 않았다. Maxwell 방정식과 자기-전기 경계조건에 따라 자기-전기-탄성 나노 판의 두께 방향에 따른 자위 및 전위의 변화가 결정된다. 자기-전기-탄성 나노 판의 탄성이론을 재 공식화하기 위하여 Eringen의 비국소 미분 구성 관계식을 사용하였고 변분이론을 이용하여 비국소 탄성이론의 지배방정식을 연구하였다. 탄성지반의 효과는 Pasternak의 가정을 적용하였다. 비국소 이론과 국소 이론의 관계를 계산 결과를 통하여 분석하였다. 또한, 전위 및 자위의 크기, 비국소 매개변수, 탄성지반 매개변수 그리고 폭-두께 비에 따른 구조적 안정문제를 연구하였다. 분석 결과들은 전위 및 자위의 효과를 나타내었다. 이러한 계산 결과들은 자기-전기-탄성 재료로 구성된 신소재 구조물에 관한 향후 연구의 비교자료가 될 수 있을 것이다.

직류급전계통에서 레일전위상승제한장치의 동작제어기법 (A Control Technique for the Rail Potential Limit Device in DC Feeding System)

  • 민명환;정호성;박영;창상훈;신명철
    • 전기학회논문지
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    • 제61권3호
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    • pp.485-490
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    • 2012
  • Nowadays, in metropolitan railroad, DC feeding system is being generally applied. In order to reduce damage of electro-chemical corrosion caused by stray current and leakage current, in DC feeding system, rail is used as negative-polarity return conductor for traction load current. However, it has problem of rail potential increase and there are no adequate measures to prevent it in domestic. The rise of rail potential leads to damage for human and equipments. To solve the problems, this paper presents fundamental theory and related standards about rail potential increase. And then, we analyzed field testing data and simulated a variety of operations by using PSCAD/EMTDC as an analysis program of power system. In addition, this paper suggests rail potential limit device and addresses how to the device. To verify the effect, simulation of DC feeding system before and after the application of the device is carried out in various cases.

규칙파(規則波)에 놓인 구(球)의 수평운동(水平運動)에 대(對)한 해석(解析) (On the Surge Motion of a Freely-Floating Sphere in a Plane Progressive Wave)

  • 박찬욱;최항순
    • 대한조선학회지
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    • 제18권1호
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    • pp.19-27
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    • 1981
  • The surge motion of a freely-floating sphere in a regular wave is studied within the framework of a linear potential theory. The fluid is assumed to be perfect and only the steady-state harmonic motion in a water of infinite depth is considered. A velocity potential describing the fluid motion is decomposed into three parts; the incident wave potential, the diffraction potential and the radiation potential. In this paper the diffraction potential and the radiation potential are analysed by using multipole expansion method. Upon calculating pressures over the immersed surface of the sphere, the hydrodynamic forces are evaluated in terms of Froude-Krylov, diffraction, added mass and damping forces as functions of the frequency of the incident wave. Finally the frequency dependence of two pertinent parameters, the amplitude ratio and the phase lag between the motion of the sphere and that of the incident wave is derived from the equation of motion. As for numerical results the general tendency of the present calculation shows good agreement with Kim's work who also treated this problem utilizing the Green's function method.

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INTERPARTICLE POTENTIAL OF 10 NANOMETER TITANIUM NANOPARTICLES IN LIQUID SODIUM: THEORETICAL APPROACH

  • KIM, SOO JAE;PARK, GUNYEOP;PARK, HYUN SUN;KIM, MOO HWAN;BAEK, JEHYUN
    • Nuclear Engineering and Technology
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    • 제47권6호
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    • pp.662-668
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    • 2015
  • A suspension of titanium nanoparticles (Ti NPs) in liquid sodium (Na) has been proposed as a method to mitigate the violent sodium-water reaction (SWR). The interparticle potential between Ti NPs in liquid Na may play a significant role in the agglomeration of NPs on the reaction surface and in the bulk liquid Na, since the potential contributes to a reduction in the long-term dispersion stability. For the effective control of the SWR with NPs, a physical understanding of the molecular dynamics of NPs in liquid Na is key. Therefore in this study, the nonretarded Van der Waals model and the solvation potential model are employed to analyze the interparticle potential. The ab initio calculation reveals that a strong repulsive force driven by the solvation potential exceeds the interparticle attraction and predicts the agglomeration energy required for two 10-nm Ti NPs to be $4{\times}10^{-17}J$. The collision theory suggests that Ti NPs can be effective suppressors of the SWR due to the high energy barrier that prevents significant agglomeration of Ti NPs in quiescent liquid Na.

기존의 액상화 평가기법 밀 그 적용성에 관한 연구 (A Study on the Conventional Liquefaction Analysis and Application to Korean Liquefaction Hazard Zones)

  • 박인준;신윤섭;최재순;김수일
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 1999년도 봄 학술발표회 논문집
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    • pp.431-438
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    • 1999
  • An assessment of liquefaction potential is made in principle by comparing the shear stress induced by earthquake to the liquefaction strength of the soil. In this study, a modified method based on Seed and Idriss theory is developed for evaluating liquefaction potential. The shear stress in the ground can be evaluated with seismic response analysis and the liquefaction strength of the soil can be investigated by using cyclic triaxial tests. The cyclic triaxial tests are conducted in two different conditions in order to investigate the factors affecting liquefaction strength such as cyclic shear stress amplitude and relative density. And performance of the modified method in practical examples is demonstrated by applying it to liquefaction analysis of artificial zones with dimensions and material properties similar to those in a typical field. From the result, the modified method for assessing liquefaction potential can successfully evaluate the safety factor under moderate magnitude(M=6.5) of earthquake.

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