• Journal of Electrochemical Science and Technology
• /
• v.12 no.2
• /
• pp.257-265
• /
• 2021

In this study, we report niobium (Nb) with hierarchical porous structure produced by a one-pot, HF-free electrochemical etching process. It is proved experimentally that a well-defined hierarchical porous structure is produced from the combination of a limited repetition of pulse etching and high concentration of aggressive anion (i.e., SO₄^2-), which results in hierarchical pores with high order over 3. A formula is derived for the surface area of porous Nb as a function of the hierarchical order of pores while the experimental surface area is estimated on the basis of the electrochemical gas evolution rate on porous Nb. From the comparison of the theoretical and experimental surface areas, an in-depth understanding was gained about porous structure produced in this work in terms of the actual pore shape and hierarchical pore order.

• Korean Journal of Materials Research
• /
• v.28 no.1
• /
• pp.62-67
• /
• 2018

Active clay, bentonite and zeolite were used as porous materials for humidity controlling ceramic boards. The specific area and the pore volume of active clay were higher than bentonite and zeolite. The flexible strength of the gypsum board decreased with an increasing amount of porous material, and the flexible strength was lowest when active clay with a higher specific surface area than others porous materials was added. The specific surface area and total pore volume of ceramic boards containing porous material were highest at $102.25m^2/g$, $0.142cm^3/g$, respectively, when the active clay was added. In addition, as the amount of added porous materials increased, the specific surface area and total pore volume of the ceramic board increased, but the average pore diameter decreased. The addition of s porous materials with a high specific area and a large pore volume improved the moisture absorptive and desorptive performance of the ceramic board. Therefore, in this experiment, the moisture absorptive and desorptive properties were the best when active clay was added. Furthermore, as the amount of added porous materials increased, the moisture absorptive and desorptive properties improved. When 70 mass% of active clay was added to ${\alpha}$-type gypsum, the hygroscopicity was the highest, about $300g/m^2$, in this experiment.

• Journal of the Korean Ceramic Society
• /
• v.41 no.7
• /
• pp.503-507
• /
• 2004

The importance of porous ceramics has been increasingly recognized and adequate strength of porous ceramics is now required for structural applications. Porosities of porous ceramics act as flaws in inner volume and outer surface which result in severe strength degradation. The effect of pore structure, however, on strength and reliability of porous ceramics has not been clearly understood. We investigate the relationship between pore structure and mechanical properties using a sphere indentation on bilayer structure, porous ceramic top layer with soft polymer substrate. Porous alumina and silica were prepared to characterize the isolated pore structure and interconnected pore structure, respectively. The porous ceramic with 1mm thickness were bonded to soft polycarbonate substrate and then fracture strengths were estimated from critical loads for radial cracking of porous ceramics during sphere indentation from top surface. This simple and reproducible technique provides Weibull modulus of strength of porous ceramics with different pore structure. It shows that the porous ceramics with isolated pore structure have higher strength and higher Weibull modulus as well, than those with interconnected pore structure even with the same porosity.

• Steel and Composite Structures
• /
• v.45 no.3
• /
• pp.349-367
• /
• 2022

In this research, an approach combining a semi-analytical method and an analytical method is presented to investigate the static and dynamic post-buckling behavior of the sandwich functionally graded (FG) porous cylindrical shells exposed to external pressure. The sandwich cylindrical shell considered is composed of a viscoelastic core and two FG porous (FGP) face layers. The viscoelastic core is made of Kelvin-Voigt-type material. The material properties of the FG porous face layer are considered continuous through each face thickness according to a porosity coefficient and a volume fraction index. Two types of sandwich FG porous viscoelastic cylindrical shells named Type A and Type B are considered in the research. Type A shell has the porosity evenly distributed across the thickness direction, and Type B has the porosity unevenly distributes across the thickness direction. The FG face layers are considered in two cases: outside metal surface, inside ceramic surface (OMS-ICS), and inside metal surface, outside ceramic surface (IMS-OCS). According to Donnell shell theory, von-Karman equation, and Galerkin's method, a discretized nonlinear governing equation is derived for analyzing the behavior of the shells. The explicit expressions for static and dynamic critical buckling loading are thus developed. To study the dynamic buckling of the shells, the governing equation is examined via a numerical approach implementing the fourth-order Runge-Kutta method. With a procedure presented by Budiansky-Roth, the critical load for dynamic post-buckling is obtained. The effects of various parameters, such as material and geometrical parameters, on the post-buckling behaviors are investigated.

• 연구논문집
• /
• s.23
• /
• pp.5-13
• /
• 1993

The present work deals with the theoretical prediction of static & dynamic characteristic of annular type externally pressurized thrust air bearings with metal-sintered porous media. For the evaluation of surface loading effect by machining, it is assumed that the flow at the porous surface is dominant and which is equivalent to the flow through orifice. Finite different method with over-relaxation method is used to solve the numerical problems. The influences of radius ratio, supply pressure and squeeze number on performances are investigated, as the results. The results of this study can be used to predict the optimal running condition and stable realm of porous bearings.

• Journal of the Korean Society for Precision Engineering
• /
• v.20 no.1
• /
• pp.91-98
• /
• 2003

Removal of gas in a mold has been a big problem in pressing mold or in injection mold. Air vent has been used to solve the problem, but it has weak points such as the increased cost, the increased number of process, and vent marks on the surface of a product. In this study, the sintering method and rapid tooling method are used for making porous metal mold. Porous metal mold has many open pores, which are very small. When porous metal mold is used for pressing mold or injection mold, all process would be made short, produce cost would be down, and vent marks would be not leaved on the surface of a product. Characteristic of porous material varies from sintering conditions, which are the length of sintering time, sintering temperature and sintering atmosphere etc. This study will find optimized sintering condition for the porous metal mold.

• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2002.10a
• /
• pp.308-311
• /
• 2002

Removal of gas in a mold has been a big problem in pressing mold or in injection mold. Air vent has been used to solve the problem, but it has weak points such as the Increased cost, the increased number of process. and vent marks on the surface of a product. In this study, the sintering method and rapid tooling method are used for making porous metal mold. Porous metal mold has many open pores, which are very small. When porous metal mold is used for pressing mold or injection mold, all process would be made short, produce cost would be down, and vent marks would be not leaved on the surface of a product. Characteristic of Porous material varies from sintering conditions, which are the length of sintering time, sintering temperature and sintering atmosphere etc. This study will find optimized sintering condition for the porous metal mold.

• Journal of Integrative Natural Science
• /
• v.3 no.4
• /
• pp.202-205
• /
• 2010

Nanocrystalline porous silicon surfaces have been used to detect nitroaromatic compounds in vapor phase. The mode of photoluminescence is emphasized as a sensing attitude or detection technique. Quenching of photoluminescence from nanocrystalline porous surfaces as a transduction mode is measured upon the exposure of nitroaromatic compounds. Reversible detection mode for nitroaromatics is, too, observed. To verify the detection afore-mentioned, photoluminescent freshly prepared porous silicons are functionalized with different groups. The mechanism of quenching of photoluminescence is attributed to the electron transfer behaviors of quantum-sized nano-crystallites in the porous silicon matrix to the analytes(nitroaromatics). An attempt has been done to prove that the surface-derivatized photoluminescent porous silicone surfaces can act as versatile substrates for sensing behaviors due to having a large surface area and highly sensitive transduction mode.

• Journal of Integrative Natural Science
• /
• v.7 no.4
• /
• pp.221-226
• /
• 2014

Optically encoded porous silicon smart particles were successfully fabricated from the free-standing porous silicon thin films using ultrasono-method. DBR PSi was prepared by an electrochemical etch of heavily doped $p^{{+}{+}}$-type silicon wafer. DBR PSi was prepared by using a periodic pseudo-square wave current. The surface-modified DBR PSi was prepared by either thermal oxidation or thermal hydrosilylation. Free-standing DBR PSi films were generated by lift-off from the silicon wafer substrate using an electropolishing current. Free-standing DBR PSi films were ultrasonicated to create DBR-structured porous smart particles. Optical characteristics of porous smart particles were measured by FT-IR spectroscopy. The surface morphology of porous smart particles was determined by FE-SEM.

• Journal of Integrative Natural Science
• /
• v.7 no.1
• /
• pp.1-4
• /
• 2014

Distributed Bragg reflector porous silicon of different characteristics were formed to determine their optical constants in the visible wavelength range using a periodic square wave current between low and high current densities. The surface and cross-sectional SEM images of distributed Bragg reflector porous silicon were obtained using a cold field emission scanning electron microscope. The surface image of distributed Bragg reflector porous silicon indicates that the distributions of pores are even. The cross-sectional image illustrates that the multilayer of distributed Bragg reflector porous silicon exhibits a depth of few microns and applying of square current density during the etching process results two distinct refractive indices in the contrast. Distributed Bragg reflector porous silicon exhibited a porosity depth profile that related directly to the current-time profile used in etch. Its free-standing film was obtained by applying an electro-polishing current.