• Title/Summary/Keyword: Porous Network

검색결과 104건 처리시간 0.04초

Composite Materials with MWCNTs and Conducting Polymer Nanorods and their Application as Supercapacitors

  • Liua, Lichun;Yoo, Sang-Hoon;Park, Sung-Ho
    • Journal of Electrochemical Science and Technology
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    • 제1권1호
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    • pp.25-30
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    • 2010
  • This study demonstrated the synthesis of high-surface-area metal-free carbonaceous electrodes (CE) from anodic aluminum oxide (AAO) templates, and their application as supercapacitors. Multi-walled Carbon nanotubes (MWCNTs) were interwoven into a porous network sheet that was attached to one side of AAO template through a vacuum filtration of the homogeneously dispersed MWCNT toluene solution. Subsequently, the conducting polymer was electrochemically grown into the porous MWCNT network and nanochannels of AAO, leading to the formation of a carbonaceous metal-free film electrode with a high surface area in the given geometrical surface area. Typical conducting polymers such as polypyrrole (PPY) and poly(3,4-ethylenedioxythiophene) (PEDOT) were examined as model systems, and the resulting electrodes were investigated as supercapacitors (SCs). These SCs exhibited stable, high capacitances, with values as high as 554 F/g, 1.08 F/$cm^2$ for PPY and 237 F/g, 0.98 F/$cm^2$ for PEDOT, that were normalized by both the mass and geometric area.

통계적 확산이론에 기초한 다공질체의 유동관망 유동해석 기법 개발 (Development of a Pipe Network Fluid-Flow Modelling Technique for Porous Media based on Statistical Percolation Theory)

  • 신휴성
    • 지질공학
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    • 제23권4호
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    • pp.447-455
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    • 2013
  • 본 연구에서는 다공질 지반체내의 투수계수를 계산하기 위하여 정방형의 배열형태를 갖는 유동관망(pipe network) 유동해석 모델을 개발하였다. 본 유동관망을 통한 유체의 흐름 메커니즘은 통계적 침투이론(percolation theory)에 기초하여 정의된다(Stauffer and Aharony, 1994). 여기서, 개별 유동관의 직경들이 주어진 다공질 매질의 공극률과 공극크기 분포특성을 기초로 하여 통계적으로 지정됨으로 계산된 유체흐름은 불균일한 채널 유동 형태로 나타난다. 본 유동해석에서는 유동관망 모델의 한쪽 경계면에 가압된 유체가 투입되고 다른 측면 경계면들은 흐름을 억제하는 경계조건을 두어 한 방향으로 유동관망을 통해 유체의 흐름을 유도하여 모델링된다. 이때, 흐름을 허용할지를 정의하는 확산조건(percolation condition)이 각 유동관에 부여되며, 이는 각 유동 경로의 직경과 재료면 특성을 기초로 계산된 삼투압(capillary pressure) 수준에 의해 정의된다. 유체가 유입되는 면의 수압에 대해 전체 유동관망 모델 내의 수압 분포가 평형을 이루면 유출되는 면의 수압이 일정해 지며, 유입면의 수압과 계산된 유출면의 수압 및 유동량을 Darcy 방정식에 적용하면 유동관망 모델로 모사된 다공질 매질의 투수계수를 얻어 낼 수 있다. 본 연구에서는, 민감할 것으로 예상된 유동 격자망의 규모의 투수계수 결과값에 대한 민감도를 검토하였으며, 실제 석유개발 현장에서 수집된 시추코어에 대해 측정된 투수계수값과 제안 네트워크 모델을 이용한 계산값과 비교하여 합리적인 범위 내에서 잘 부합됨을 보였다.

셀 다공구조를 갖는 Al2O3세라믹스의 제조 (Processing of Al2O3 Ceramics with a Porous Cellular Structure)

  • 임병구;이락형;하정수
    • 한국세라믹학회지
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    • 제44권10호
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    • pp.574-579
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    • 2007
  • Porous $Al_2O_3$ ceramics were prepared by the gelcasting foams method (a slurry foaming process) with acrylamide monomer. The foaming and gelation behavior was investigated with the parameters such as the type and concentration of surfactant, solid loading of slurry, and the concentrations of initiator and catalyst. Density, porosity, microstructure, and strength of the green and sintered samples were characterized. Of the four kinds of surfactants tested, Triton X-114 showed the highest foaming ability for the solid loading of 55-30 vol%. The gelation condition giving the idle time off min was found to set the foamed structure without significant bubble enlargement and liquid lamella thinning. The green samples were fairly strong and machinable and showed maximum strength of 2.4 MPa in diametral compression. The sintered samples showed densities of 10-36% theoretical (i.e. porosity 90-64%) with a highly interconnected network of spherical pores with sizes ranging from 30 to $600{\mu}m$. The pore size and connectivity increased but the cell strut thickness decreased with decreasing the solid loading. Flexural strength of 37.8-1.7 MPa was obtained for the sintered samples.

Thermal-hydraulic modeling of CAREM-25 advanced small modular reactor using the porous media approach and COBRA-EN modified code

  • Saeed Zare Ganjaroodi;Maryam Fani;Ehsan Zarifi;Salaheddine Bentridi
    • Nuclear Engineering and Technology
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    • 제56권5호
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    • pp.1574-1583
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    • 2024
  • Small Modular Reactors (SMRs) are compact nuclear reactors designed to generate electric power up to 300 MWe. They could be assembled in factory, and then transported to be directly installed on-stie. CAREM (Central Argentina de Elementos Modulares) is a national SMR development project, based on light water reactor technology supervised by Argentina's National Atomic Energy Commission (CNEA). It is a natural circulation-based SMR with an indirect-cycle, including specific items and parts that simplify the design and improve safety performance. In this paper, the thermal-hydraulic study of CAREM-25 advanced small modular reactor is conducted by using COBRA-EN modified code and the Porous Media Approach (PMA) for the first time. According to PMA approach, each fuel assembly is modeled and divided into a network of lumped regions. While complex geometries are defined, the thermal-hydraulic parameters such as temperature and density are calculated for coolant and fuel rods. The obtained results show that the temperature in the fuel center may reach a peak around 1280 K in the hottest fuel assembly. Finally, the comparison of results from both methods (modified COBRA-EN and PMA) presented an appropriate consistency.

Analysis of flow through dam foundation by FEM and ANN models Case study: Shahid Abbaspour Dam

  • Shahrbanouzadeh, Mehrdad;Barani, Gholam Abbas;Shojaee, Saeed
    • Geomechanics and Engineering
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    • 제9권4호
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    • pp.465-481
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    • 2015
  • Three-dimensional simulation of flow through dam foundation is performed using finite element (Seep3D model) and artificial neural network (ANN) models. The governing and discretized equation for seepage is obtained using the Galerkin method in heterogeneous and anisotropic porous media. The ANN is a feedforward four layer network employing the sigmoid function as an activator and the back-propagation algorithm for the network learning, using the water level elevations of the upstream and downstream of the dam, as input variables and the piezometric heads as the target outputs. The obtained results are compared with the piezometric data of Shahid Abbaspour's Dam. Both calculated data show a good agreement with available measurements that demonstrate the effectiveness and accuracy of purposed methods.

유전율법을 이용한 다공질 매질의 공극률 및 유효공극률의 측정에 관한 연구 (Determination of porosity and effective porosity of saturated porous media using a permittivity method in the laboratory)

  • 김만일;니시가끼마코토
    • 지질공학
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    • 제13권4호
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    • pp.419-428
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    • 2003
  • 지반을 대상으로 지하수의 이동 및 오염물질 침투에 대한 평가를 위해, 지반을 구성하고 있는 매질의 공극률과 유효공극률을 파악하는 것은 매우 중요하다. 이들은 물질 이동을 결정하는 중요한 물리적 파라메터이다. 본 연구에서는 새로운 유전율 시스템인 FOR-V (Frequency domain reflectometry with vector network analyzer)를 적용하여 표준사 (Standard sand)와 강모래 (River sand)에 대한 공극률 및 유효공극률을 측정하기 위한 실험적 연구를 실시하였다. 또한, 이들을 측정하기 위해, 다공질 매질에 대한 유전율상수의 특성을 고려한 유전율 믹싱모델 (dielectric FDR-V 시스템을 적용한 주입실험 (Injection test)과 주입물질의 농도를 측정하는 치환실험 (Replacement test)을 수행하였다. 두 종류의 실험 결과치를 비교한 결과, 측정된 유효공극률을 공극률과 비교해 보면, 약 85 - 92 %의 범위 내에 존재하는 것으로 측정되었다. 일반적인 흙의 유효공극률은 공극률에 대해 약 90 % 범위 내에 분포하고 있는 것으로 알려져 있으나, 본 연구에서는 다소 낮은 결과치를 보이고 있다. 이러한 현상은 시스템의 측정 프로브의 측정 범위가 직경 0.36 cm의 동축측정프로브 끝부분에서 이루어져 비교적 작기 때문에 제작된 흙 시료전 체적에 대한 유효공극률의 결과치이기 보다는 프로브가 위치한 지점에 대한 측정치로 판단된다. 이러한 측정 프로브의 특성을 고려해 볼 때, FDR-V 시스템은 연구자가 의도한 연구에 따라 특정 지점에 대한 지반의 정밀한 물리적 특성을 파악할 수 있을 것으로 사료된다.

알루미나-지르코니아 복합체의 제조공정 및 미세구조에 미치는 폴리머 첨가의 영향 (Effect of Polymer Content on Synthesis Process and Microstructure of Alumina-Zirconia Composite)

  • 이상진;권명도;이충효;조경식
    • 한국분말재료학회지
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    • 제10권5호
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    • pp.310-317
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    • 2003
  • Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

Electro-osmotic pump in osteo-articular tissue engineering: A feasibility study

  • Lemonnier, Sarah;Naili, Salah;Lemaire, Thibault
    • Advances in biomechanics and applications
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    • 제1권4호
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    • pp.227-237
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    • 2014
  • The in vitro construction of osteo-articular large implants combining biomaterials and cells is of great interest since these tissues have limited regeneration capability. But the development of such organoids is particularly challenging, especially in the later time of the culture, when the extracellular matrix has almost filled the initial porous network. The fluid flow needed to efficiently perfuse the sample can then not be achieved using only the hydraulic driving force. In this paper, we investigate the interest of using an electric field to promote mass transport through the scaffold at the late stage of the culture. Based on the resolution of the electrokinetics equations, this study provides an estimation of the necessary electric driving force to reach a sufficient oxygen perfusion through the sample, thus analyzing the feasibility of this concept. The possible consequences of such electric fields on cellular activities are then discussed.

Fabrication of Nano-sized Titanate Powder via a Polymeric Steric Entrapment Route and Planetary Milling Process

  • Lee, Sang-Jin;Lee, Chung-Hyo
    • 한국세라믹학회지
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    • 제39권4호
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    • pp.336-340
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    • 2002
  • Pure and nano-sized $TiO_2$ and $CaTiO_3$ powders were fabricated by a polymeric steric entrapment route and planetary milling process. An ethylene glycol was used as a polymeric carrier for the preparation of organic-inorganic precursors. Titanium isopropoxide and calcium nitrate were dissolved in liquid-type ethylene glycol without any precipitation. At the optimum amount of the polymer, the metal cations were dispersed in solution and a homogeneous polymeric network was formed. The dried precursor ceramic gels were turned to porous powders through calcination process. The porous powders were crystallized at low temperatures and the crystalline powders were planetary milled to nano size.